1,1-dichloroethene

C2H2Cl2

CAS75-35-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
Danger

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Identification

CAS Number
75-35-4
EC Number
200-864-0
UN Number
1303
Index Number
602-025-00-8
PubChem CID
6366

Physical-chemical properties

Molecular Formula
C2H2Cl2
Molar Mass
96.94 g/mol
IUPAC Name
1,1-dichloroethene

Chemical Identifiers

InChI
InChI=1S/C2H2Cl2/c1-2(3)4/h1H2
InChI Key
LGXVIGDEPROXKC-UHFFFAOYSA-N

Overview

1,1-dichloroethene (CAS 75-35-4) is a chlorinated alkene compound characterized by its high flammability and significant toxicity profile. This organochlorine compound, with the molecular formula C2H2Cl2 and a molecular weight of 96.94 g/mol, represents an important industrial chemical intermediate despite its hazardous classification. The substance exists as a volatile liquid under standard conditions and exhibits exceptional reactivity due to its unsaturated carbon-carbon double bond combined with two chlorine substituents on the same carbon atom. The safety profile of 1,1-dichloroethene requires careful consideration, as it carries multiple serious health and environmental hazard classifications. It is classified as a Category 1B carcinogen and Category 2 mutagen, indicating strong evidence of cancer-causing potential and genetic damage risks. The compound also presents acute toxicity concerns through multiple exposure routes and can cause specific target organ toxicity following repeated exposure. Its flammable liquid classification (Category 1) combined with its volatility creates significant fire and explosion risks in industrial settings. From an industrial perspective, 1,1-dichloroethene serves primarily as a chemical intermediate in polymer synthesis and as a precursor for various chlorinated compounds. The chemical industry utilizes this compound in specialized applications where its unique reactivity profile provides advantages over related substances such as 1,3-dichloroprop-1-ene, though both require similar stringent handling protocols due to their hazardous nature. OYSI maintains availability of 1,1-dichloroethene for qualified industrial customers requiring this specialized chemical intermediate, ensuring compliance with all relevant European chemical regulations and safety requirements.

Safety & Classification

Danger
Classification:

Flam. Liq. 1; Carc. 1B; Muta. 2; Acute Tox. 1; Acute Tox. 3; STOT RE 1; Aquatic Chronic 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H224

Extremely flammable liquid and vapour.

H350

May cause cancer.

H341

Suspected of causing genetic defects.

H330

Fatal if inhaled.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H412

Harmful to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1303
ADR Class3
Packing GroupI
Tunnel CodeD/E
Proper Shipping NameVinylidenchlorid, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is 1,1-dichloroethene?

1,1-dichloroethene is an organochlorine compound with the molecular formula C2H2Cl2 and CAS number 75-35-4. This chemical substance has a molecular weight of 96.94 g/mol and belongs to the dichloroethene family. It is classified as an extremely hazardous substance due to its carcinogenic, mutagenic, and highly toxic properties. The compound requires strict handling protocols and is subject to extensive regulatory oversight in industrial applications.

What are the physicochemical properties of 1,1-dichloroethene?

1,1-dichloroethene is a volatile liquid at room temperature with characteristic properties typical of chlorinated hydrocarbons. The substance exhibits high volatility and flammability, classified as Flammable Liquid Category 1. It has limited water solubility but dissolves readily in organic solvents. The compound's high vapor pressure contributes to its volatility, making proper ventilation essential during handling and storage operations.

What is 1,1-dichloroethene used for?

1,1-dichloroethene serves primarily as an intermediate in chemical synthesis and manufacturing processes. The compound is utilized in the production of specialized polymers and as a building block for other chemical compounds. Due to its extremely hazardous classification including carcinogenic and mutagenic properties, its industrial applications are heavily regulated and limited to controlled professional environments with strict safety protocols.

How to handle 1,1-dichloroethene safely?

1,1-dichloroethene requires maximum safety precautions due to its Acute Toxicity Category 1 classification. Personnel must wear full chemical-resistant protective equipment including supplied-air respirators, chemical-resistant gloves, and full body protection. Work must be conducted in well-ventilated areas or fume hoods, away from ignition sources due to its high flammability. Only trained professionals should handle this extremely hazardous substance.

How to store 1,1-dichloroethene correctly?

1,1-dichloroethene must be stored in specially designed facilities meeting ADR Class 3, Packing Group I requirements. Storage areas require explosion-proof electrical equipment, excellent ventilation, and temperature control to prevent vapor accumulation. Containers should be kept tightly sealed, away from heat sources, oxidizing agents, and incompatible materials. Storage facilities must comply with regulations for carcinogenic substances and include appropriate containment systems.

What to do in case of contact with 1,1-dichloroethene?

Immediate action is critical due to the substance's Acute Toxicity Category 1 classification. For skin contact, remove contaminated clothing and flush with water for at least 15 minutes. In case of inhalation, move to fresh air immediately and seek emergency medical attention. Eye contact requires immediate irrigation with water. Due to the substance's extreme toxicity and carcinogenic properties, all exposures require immediate professional medical evaluation.

How to dispose of 1,1-dichloroethene appropriately?

1,1-dichloroethene disposal requires specialized hazardous waste treatment due to its carcinogenic and highly toxic properties. The substance must be handled by licensed hazardous waste disposal companies equipped for treating chlorinated organic compounds. Incineration at high temperatures in approved facilities is typically required. All disposal activities must comply with local and European waste regulations, including proper documentation and tracking throughout the disposal process.

How to transport 1,1-dichloroethene?

1,1-dichloroethene transport falls under ADR Class 3 (Flammable Liquids), Packing Group I, indicating maximum danger level. Transportation requires specialized vehicles with appropriate safety equipment, trained drivers with hazardous materials certification, and proper shipping documentation. Packages must meet stringent packing requirements for highly flammable and toxic substances. Emergency response information must accompany all shipments per ADR regulations.

Is 1,1-dichloroethene subject to specific regulations?

1,1-dichloroethene is subject to extensive European regulations under REACH and CLP due to its classification as Carcinogenic Category 1B, Mutagenic Category 2, and Acute Toxic Category 1. The substance requires registration, detailed safety data sheets, and restricted handling procedures. Industrial users must implement strict occupational exposure controls and comply with worker protection regulations. Import, distribution, and use may require special authorizations.

Where to buy 1,1-dichloroethene in Europe?

1,1-dichloroethene is available through specialized chemical distributors like OYSI, which serves the European market with high-purity industrial chemicals. Due to the substance's extremely hazardous classification and regulatory requirements, purchases are restricted to qualified industrial users with appropriate safety infrastructure and regulatory compliance. OYSI provides technical support and ensures proper documentation for this highly regulated chemical substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.