1,1-dichloroethene
C2H2Cl2
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Identification
- CAS Number
- 75-35-4
- EC Number
- 200-864-0
- UN Number
- 1303
- Index Number
- 602-025-00-8
- PubChem CID
- 6366
Physical-chemical properties
- Molecular Formula
- C2H2Cl2
- Molar Mass
- 96.94 g/mol
- IUPAC Name
- 1,1-dichloroethene
Chemical Identifiers
- InChI
- InChI=1S/C2H2Cl2/c1-2(3)4/h1H2
- InChI Key
- LGXVIGDEPROXKC-UHFFFAOYSA-N
Overview
1,1-dichloroethene (CAS 75-35-4) is a chlorinated alkene compound with high volatility and significant industrial reactivity applications. This halogenated organic compound, also known by its IUPAC name 1,1-dichloroethene, represents an important intermediate in chemical manufacturing processes. With the molecular formula C2H2Cl2 and a molecular weight of 96.94 g/mol, this colorless liquid exhibits characteristics typical of chlorinated alkenes, sharing some structural similarities with other halogenated compounds like 1,3-dichloroprop-1-ene in terms of reactivity patterns. The compound presents significant safety considerations due to its hazardous properties profile. Classified under multiple danger categories including Flam. Liq. 1, Carc. 1B, and Acute Tox. 1, it requires careful handling protocols and appropriate safety measures. The substance carries the signal word "Danger" and is associated with GHS pictograms for flammability (GHS02), health hazards (GHS08), and acute toxicity (GHS06). Its ADR classification as Class 3 indicates specific transportation requirements for flammable liquids. Key physical properties include its volatile nature and chemical reactivity, making it valuable in polymerization processes and as a chemical intermediate. Industrial applications primarily focus on polymer production, where it serves as a monomer in manufacturing specialized plastics and copolymers. Additionally, it functions as an intermediate in organic synthesis reactions and finds use in certain chemical manufacturing processes requiring reactive chlorinated compounds. OYSI maintains availability of 1,1-dichloroethene for qualified industrial customers, ensuring proper documentation and compliance with European chemical regulations for this controlled substance.
Safety & Classification
Flam. Liq. 1; Carc. 1B; Muta. 2; Acute Tox. 1; Acute Tox. 3; STOT RE 1; Aquatic Chronic 3
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1303 |
| ADR Class | 3 |
| Packing Group | I |
| Tunnel Code | D/E |
| Proper Shipping Name | Vinylidenchlorid, stabilisiert |
| Marine Pollutant | No |
Frequently Asked Questions
What is 1,1-dichloroethene?
1,1-dichloroethene is an organochlorine compound with the molecular formula C2H2Cl2 and CAS number 75-35-4. This chemical substance has a molecular weight of 96.94 g/mol and belongs to the dichloroethene family. It is classified as extremely hazardous due to its carcinogenic, mutagenic, and acute toxic properties. The compound is highly flammable and poses significant health risks including potential organ damage from repeated exposure.
What are the physicochemical properties of 1,1-dichloroethene?
1,1-dichloroethene is a colorless liquid at room temperature with a characteristic sweet, ether-like odor. The compound has low water solubility but is miscible with most organic solvents including alcohols, ethers, and hydrocarbons. It exhibits high volatility with a low boiling point, making vapor formation readily possible at ambient conditions. The substance demonstrates excellent solvent properties for various organic materials and polymers.
What is 1,1-dichloroethene used for?
1,1-dichloroethene is primarily used as an intermediate in chemical synthesis and as a precursor for producing vinylidene chloride polymers and copolymers. The compound serves as a solvent in specialized industrial applications and plays a role in manufacturing certain plastics and synthetic materials. It is also utilized in laboratory settings for specific analytical procedures and research applications, though its use is strictly controlled due to safety concerns.
How to handle 1,1-dichloroethene safely?
1,1-dichloroethene must be handled with extreme caution using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods to prevent vapor inhalation. Avoid all ignition sources as the substance is highly flammable. Only trained personnel should handle this material, following strict safety protocols and emergency procedures due to its carcinogenic and acute toxic properties.
How to store 1,1-dichloroethene correctly?
1,1-dichloroethene must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat, sparks, and open flames. The storage area should be equipped with appropriate fire suppression systems and maintained below 25°C. Keep containers away from incompatible materials such as strong oxidizers, bases, and metals. Storage facilities must comply with local regulations for flammable and carcinogenic substances, with restricted access for authorized personnel only.
What to do in case of contact with 1,1-dichloroethene?
Immediate medical attention is required for any exposure to 1,1-dichloroethene due to its acute toxicity. For skin contact, remove contaminated clothing and wash affected areas thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and provide oxygen if breathing is difficult. For eye contact, flush with clean water for at least 15 minutes. Never induce vomiting if ingested and seek emergency medical care immediately.
How to dispose of 1,1-dichloroethene appropriately?
1,1-dichloroethene must be disposed of as hazardous waste through licensed waste management companies specializing in halogenated organic compounds. The substance cannot be disposed of in regular waste streams or poured down drains due to its environmental and health hazards. Disposal must comply with local and European waste regulations, including proper classification, documentation, and tracking. Incineration at high temperatures in specialized facilities is typically the preferred disposal method.
How to transport 1,1-dichloroethene?
1,1-dichloroethene is classified under ADR as Class 3 dangerous goods (flammable liquids) in Packing Group I, indicating the highest level of danger. Transportation requires specialized containers meeting UN specification requirements and proper hazard labeling including flammable liquid markings. Vehicles must be equipped with appropriate safety equipment and drivers must hold ADR certification. Transport documentation must include proper shipping names, hazard classes, and emergency response information.
Is 1,1-dichloroethene subject to specific regulations?
1,1-dichloroethene is subject to strict European regulations under REACH and CLP due to its classification as a Category 1B carcinogen and highly toxic substance. The compound requires safety data sheets, hazard communication, and may have use restrictions or authorization requirements. Industrial users must implement risk management measures and report usage under REACH obligations. Additional workplace exposure limits and environmental regulations apply across EU member states.
Where to buy 1,1-dichloroethene in Europe?
1,1-dichloroethene is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. As a controlled substance requiring special handling and documentation, it is only supplied to qualified industrial users with appropriate safety infrastructure and regulatory compliance. OYSI provides comprehensive technical support, safety documentation, and ensures proper packaging and transportation according to European chemical regulations.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.