1,2,3,4,5,6-hexachlorobenzene
C6Cl6
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Identification
- CAS Number
- 118-74-1
- EC Number
- 204-273-9
- UN Number
- 2729
- Index Number
- 602-065-00-6
- PubChem CID
- 8370
Physical-chemical properties
- Molecular Formula
- C6Cl6
- Molar Mass
- 284.80 g/mol
- IUPAC Name
- 1,2,3,4,5,6-hexachlorobenzene
Chemical Identifiers
- InChI
- InChI=1S/C6Cl6/c7-1-2(8)4(10)6(12)5(11)3(1)9
- InChI Key
- CKAPSXZOOQJIBF-UHFFFAOYSA-N
Overview
1,2,3,4,5,6-hexachlorobenzene (CAS 118-74-1) is a fully chlorinated benzene compound with exceptional chemical stability and persistent environmental characteristics. This organochlorine compound represents the highest degree of chlorination possible on a benzene ring, containing six chlorine atoms substituted at all available positions. With the molecular formula C6Cl6 and a molecular weight of 284.8 g/mol, hexachlorobenzene exhibits remarkable thermal and chemical resistance due to its fully saturated aromatic structure. The compound appears as white crystalline solid under standard conditions and demonstrates very low solubility in water while showing greater solubility in organic solvents. From a safety perspective, 1,2,3,4,5,6-hexachlorobenzene requires careful handling protocols due to its classification as a Category 1B carcinogen and specific target organ toxicant. The substance carries GHS08 health hazard and GHS09 environmental hazard pictograms, reflecting its potential for serious health effects and environmental persistence. Its ADR classification as Class 6.1 indicates toxic properties requiring appropriate transportation precautions. Unlike simpler aromatic compounds such as N-methylaniline, hexachlorobenzene's extensive halogenation significantly increases its bioaccumulation potential and environmental persistence. Industrial applications include use as an intermediate in specialty chemical synthesis and as a component in certain high-temperature resistant materials. The compound also finds application in research settings for environmental fate studies and as an analytical standard. Due to its persistent nature, many traditional uses have been restricted, with current applications focusing on controlled industrial processes where containment is ensured. OYSI maintains availability of 1,2,3,4,5,6-hexachlorobenzene for qualified industrial customers with appropriate handling capabilities and regulatory compliance requirements.
Safety & Classification
Carc. 1B; STOT RE 1; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Transport (ADR)
| UN Number | 2729 |
| ADR Class | 6.1 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Hexachlorbenzen |
| Marine Pollutant | No |
Frequently Asked Questions
What is 1,2,3,4,5,6-hexachlorobenzene?
1,2,3,4,5,6-hexachlorobenzene is a synthetic organochlorine compound with the molecular formula C6Cl6 and CAS number 118-74-1. This substance consists of a benzene ring where all six hydrogen atoms have been replaced by chlorine atoms, resulting in a highly chlorinated aromatic compound with a molecular weight of 284.8 g/mol. It is classified as a hazardous substance with carcinogenic properties and environmental toxicity concerns.
What are the physicochemical properties of 1,2,3,4,5,6-hexachlorobenzene?
1,2,3,4,5,6-hexachlorobenzene is a white crystalline solid at room temperature with very low water solubility due to its highly chlorinated structure. The compound exhibits high chemical stability and persistence in the environment. It has low volatility and tends to bioaccumulate in fatty tissues. The substance is lipophilic, making it soluble in organic solvents and fats but practically insoluble in water.
What is 1,2,3,4,5,6-hexachlorobenzene used for?
1,2,3,4,5,6-hexachlorobenzene is primarily used as an intermediate in chemical synthesis and research applications. Historically, it was used in the production of other chlorinated compounds and as a fungicide, though many uses have been restricted due to environmental and health concerns. Currently, its applications are mainly limited to specialized industrial processes and analytical chemistry as a reference standard or research chemical.
How to handle 1,2,3,4,5,6-hexachlorobenzene safely?
Safe handling of 1,2,3,4,5,6-hexachlorobenzene requires comprehensive personal protective equipment including chemical-resistant gloves, protective clothing, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Given its carcinogenic classification (Carc. 1B), minimize skin contact and avoid dust generation. Implement strict hygiene measures, including thorough handwashing and contaminated clothing removal before leaving work areas.
How to store 1,2,3,4,5,6-hexachlorobenzene correctly?
1,2,3,4,5,6-hexachlorobenzene should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers tightly closed and properly labeled in a secure chemical storage area with restricted access. Store separately from oxidizing agents, strong bases, and food products. Ensure storage areas have appropriate spill containment measures and maintain inventory records due to the substance's hazardous classification.
What to do in case of contact with 1,2,3,4,5,6-hexachlorobenzene?
In case of skin contact with 1,2,3,4,5,6-hexachlorobenzene, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately. For eye contact, rinse with clean water for at least 15 minutes. Seek immediate medical attention in all cases of exposure, informing healthcare providers of the substance identity and providing the safety data sheet.
How to dispose of 1,2,3,4,5,6-hexachlorobenzene appropriately?
Disposal of 1,2,3,4,5,6-hexachlorobenzene must be conducted through licensed hazardous waste disposal facilities due to its environmental persistence and toxicity. The substance requires high-temperature incineration under controlled conditions to ensure complete destruction. Never dispose of this material in regular waste streams, sewers, or the environment. Consult local environmental regulations and use certified waste disposal contractors specialized in handling persistent organic pollutants.
How to transport 1,2,3,4,5,6-hexachlorobenzene?
Transportation of 1,2,3,4,5,6-hexachlorobenzene is regulated under ADR classification 6.1 (toxic substances), packing group III. The substance must be packaged in UN-approved containers with proper hazardous material labels and documentation. Transport vehicles require appropriate placarding and drivers need hazmat certification. Shipping documentation must include proper shipping names, hazard classes, and emergency contact information for regulatory compliance.
Is 1,2,3,4,5,6-hexachlorobenzene subject to specific regulations?
1,2,3,4,5,6-hexachlorobenzene is subject to strict regulations under REACH, CLP, and various international conventions including the Stockholm Convention on Persistent Organic Pollutants. Its carcinogenic classification requires special handling procedures and exposure monitoring. The substance may face import/export restrictions and requires detailed safety data sheets. Users must comply with occupational exposure limits and environmental protection measures as mandated by European and national legislation.
Where to buy 1,2,3,4,5,6-hexachlorobenzene in Europe?
1,2,3,4,5,6-hexachlorobenzene is available through specialized chemical distributors like OYSI, which serves the European market with technical-grade chemicals. Due to its hazardous classification and regulatory restrictions, procurement requires proper documentation, end-use declarations, and compliance with safety regulations. OYSI provides technical support and ensures proper packaging and documentation for safe delivery to qualified industrial and research customers across Europe.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.