Chloro(2-methoxyethyl)mercury

C3H7ClHgO

chloro(2-methoxyethyl)mercury

CAS123-88-6
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
123-88-6
EC Number
204-659-7
UN Number
2777
Index Number
080-009-00-4
PubChem CID
12521357

Physical-chemical properties

Molecular Formula
C3H7ClHgO
Molar Mass
295.13 g/mol
IUPAC Name
chloro(2-methoxyethyl)mercury

Chemical Identifiers

InChI
InChI=1S/C3H7O.ClH.Hg/c1-3-4-2;;/h1,3H2,2H3;1H;/q;;+1/p-1
InChI Key
VJTAZCKMHINUKO-UHFFFAOYSA-M

Overview

Chloro(2-methoxyethyl)mercury (CAS 123-88-6) is an organomercury compound with high toxicity and corrosive properties. This organometallic substance represents a specialized mercury derivative featuring a chloro substituent and a 2-methoxyethyl functional group. With the molecular formula C3H7ClHgO and a molecular weight of 295.13 g/mol, chloro(2-methoxyethyl)mercury exhibits the characteristic properties of organomercury compounds while presenting unique reactivity patterns due to its specific structural configuration. The compound carries severe safety classifications, including acute toxicity category 3, specific target organ toxicity following repeated exposure category 1, and skin corrosion category 1B. Its GHS pictograms (GHS06, GHS08, GHS05, GHS09) reflect its dangerous nature, requiring stringent handling protocols and specialized storage conditions. The substance poses significant environmental risks, classified as both acutely and chronically hazardous to aquatic life. Transport classification under ADR class 6.1 emphasizes its toxic properties during logistics operations. Industrial applications for chloro(2-methoxyethyl)mercury primarily include specialized chemical synthesis processes where organomercury compounds serve as catalysts or intermediates. The compound finds use in certain pharmaceutical synthesis pathways and in the production of specialized organic compounds. Additionally, it serves applications in analytical chemistry as a reagent for specific mercury-based analytical procedures. Like other organomercury derivatives such as nitrooxy(phenyl)mercury and acetyloxy(phenyl)mercury, this compound requires expert handling and comprehensive safety protocols due to mercury's bioaccumulative properties and severe toxicological profile. OYSI maintains availability of chloro(2-methoxyethyl)mercury for qualified industrial customers requiring specialized organometallic compounds for technical applications.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; STOT RE 1; Skin Corr. 1B; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2777
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name2-Methoxyethylquecksilberchlorid
Marine PollutantNo

Frequently Asked Questions

What is chloro(2-methoxyethyl)mercury?

Chloro(2-methoxyethyl)mercury is an organomercury compound with the molecular formula C3H7ClHgO and CAS number 123-88-6. This chemical substance has a molecular weight of 295.13 g/mol and contains mercury bonded to an organic group consisting of a 2-methoxyethyl chain and a chlorine atom. It is classified as a highly toxic substance with multiple hazard classifications including acute toxicity, skin corrosion, and environmental toxicity, requiring careful handling and specialized safety measures.

What are the physicochemical properties of chloro(2-methoxyethyl)mercury?

Chloro(2-methoxyethyl)mercury is an organomercury compound with a molecular mass of 295.13 g/mol and molecular formula C3H7ClHgO. As a mercury-containing organic compound, it typically exists as a liquid or solid at room temperature, depending on specific conditions. The compound contains both polar (methoxy) and nonpolar components, affecting its solubility characteristics. Due to its organometallic nature and mercury content, it exhibits specific reactivity patterns and stability concerns that must be considered during handling and storage.

What is chloro(2-methoxyethyl)mercury used for?

Chloro(2-methoxyethyl)mercury is primarily used in specialized research applications and as a reagent in organometallic chemistry. Its applications are typically limited to laboratory settings for analytical chemistry, research into mercury compounds, and specific synthetic processes requiring organomercury reagents. Due to its high toxicity and environmental concerns, its use is heavily restricted and regulated. Industrial applications are extremely limited, with most uses confined to specialized chemical research and development under controlled conditions with appropriate safety measures.

How to handle chloro(2-methoxyethyl)mercury safely?

Chloro(2-methoxyethyl)mercury requires extreme safety precautions due to its Acute Tox. 3, STOT RE 1, and Skin Corr. 1B classifications. Essential protective equipment includes chemical-resistant gloves, full face protection, and protective clothing to prevent skin contact. Work must be conducted in well-ventilated areas or under fume hoods to avoid inhalation. Due to its corrosive and highly toxic nature, only trained personnel should handle this substance, following strict protocols to prevent exposure and environmental contamination.

How to store chloro(2-methoxyethyl)mercury correctly?

Chloro(2-methoxyethyl)mercury must be stored in a cool, dry, well-ventilated area away from incompatible materials and ignition sources. The container should be tightly sealed and made of compatible materials resistant to corrosion. Due to its toxic and corrosive nature, storage requires secondary containment to prevent environmental contamination. Access should be restricted to authorized personnel only, with appropriate labeling displaying GHS pictogrammes (GHS06, GHS08, GHS05, GHS09) and danger warnings. Regular inspection of containers is essential to ensure integrity.

What to do in case of contact with chloro(2-methoxyethyl)mercury?

Immediate action is critical due to the substance's Acute Tox. 3 and Skin Corr. 1B classifications. For skin contact, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. If inhaled, move the person to fresh air immediately. For eye contact, rinse thoroughly with water for at least 15 minutes. Seek immediate medical attention in all cases of exposure, informing medical personnel of the specific mercury compound involved and its toxic properties.

How to dispose of chloro(2-methoxyethyl)mercury appropriately?

Chloro(2-methoxyethyl)mercury requires specialized hazardous waste disposal due to its mercury content and multiple hazard classifications. The substance cannot be disposed of through regular waste streams and must be handled by licensed hazardous waste disposal companies specializing in heavy metal contaminated materials. Disposal must comply with local, national, and EU regulations regarding mercury-containing compounds. All containers, contaminated materials, and PPE must also be treated as hazardous waste and disposed of through appropriate channels to prevent environmental contamination.

How to transport chloro(2-methoxyethyl)mercury?

Chloro(2-methoxyethyl)mercury is classified under ADR Class 6.1 (toxic substances) with Packing Group II, indicating significant transport restrictions. Transportation requires specialized packaging meeting UN specifications, proper labeling with hazard diamonds, and documentation including safety data sheets. Only authorized carriers with appropriate permits and training can transport this substance. Vehicles must carry emergency equipment and follow specific routing requirements. The shipment must comply with ADR regulations for toxic substances and may require additional permits depending on quantities and destinations.

Is chloro(2-methoxyethyl)mercury subject to specific regulations?

Chloro(2-methoxyethyl)mercury is subject to extensive regulation under multiple European frameworks including REACH, CLP, and mercury-specific legislation. While not currently listed as an SVHC, its mercury content subjects it to strict controls under EU Mercury Regulation. Classification under CLP requires appropriate hazard communication with GHS pictogrammes and safety data sheets. Users must comply with occupational exposure limits, environmental discharge restrictions, and waste disposal regulations. Registration or notification requirements may apply depending on quantities and intended uses under REACH.

Where to buy chloro(2-methoxyethyl)mercury in Europe?

Chloro(2-methoxyethyl)mercury is available through specialized chemical distributors like OYSI, which supplies high-quality chemical products across Europe. Due to the substance's high toxicity and regulatory restrictions, purchase typically requires verification of legitimate research or industrial use, appropriate safety measures, and compliance with applicable regulations. OYSI can provide detailed product specifications, safety documentation, and regulatory guidance to ensure proper handling and compliance. Contact OYSI directly for availability, technical specifications, and specific requirements for this controlled substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.