Zinc bis(1-oxidopyridin-1-ium-2-thiolate)
C10H8N2O2S2Zn
zinc bis(1-oxidopyridin-1-ium-2-thiolate)
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Identification
- CAS Number
- 13463-41-7
- EC Number
- 236-671-3
- UN Number
- 2811
- Index Number
- 613-333-00-7
- PubChem CID
- 26041
Physical-chemical properties
- Molecular Formula
- C10H8N2O2S2Zn
- Molar Mass
- 317.70 g/mol
- IUPAC Name
- zinc bis(1-oxidopyridin-1-ium-2-thiolate)
Chemical Identifiers
- InChI
- InChI=1S/2C5H5NOS.Zn/c2*7-6-4-2-1-3-5(6)8;/h2*1-4,8H;/q;;+2/p-2
- InChI Key
- OTPSWLRZXRHDNX-UHFFFAOYSA-L
Overview
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) (CAS 13463-41-7) is an organometallic zinc complex with antimicrobial and biocidal properties. This specialized zinc-based compound, also identified by its EC number 236-671-3, represents a sophisticated organometallic complex where zinc coordinates with two 1-oxidopyridin-1-ium-2-thiolate ligands. With a molecular formula of C10H8N2O2S2Zn and molecular weight of 317.7 g/mol, this substance demonstrates unique chemical characteristics that make it valuable in various industrial applications requiring antimicrobial activity. The compound exhibits significant biological activity, which is reflected in its comprehensive hazard classification. It carries multiple serious health warnings including reproductive toxicity (Repr. 1B), acute toxicity (Acute Tox. 2 and 3), and specific target organ toxicity with repeated exposure (STOT RE 1). The substance also presents severe eye damage potential (Eye Dam. 1) and poses considerable environmental risks with both acute and chronic aquatic toxicity classifications. These properties necessitate careful handling protocols and appropriate safety measures during storage, transport, and application. Unlike simpler biocidal agents such as 2,2-dibromo-2-cyanoacetamide, this zinc complex offers specific coordination chemistry advantages that can provide sustained antimicrobial action. The compound finds primary applications in specialized biocidal formulations, antimicrobial coatings for industrial surfaces, and as an active ingredient in certain preservative systems where zinc-based antimicrobial activity is specifically required. Transportation regulations classify this material under ADR Class 6.1, requiring compliance with toxic substance handling protocols. OYSI maintains technical-grade zinc bis(1-oxidopyridin-1-ium-2-thiolate) inventory to support European industrial customers requiring this specialized organometallic antimicrobial compound.
Safety & Classification
Repr. 1B; Acute Tox. 2; Acute Tox. 3; STOT RE 1; Eye Dam. 1; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
Health Hazard
GHS08
Serious health hazard. May cause cancer, organ damage, or genetic defects.
Skull and Crossbones
GHS06
Acute toxicity. Fatal if swallowed, in contact with skin, or if inhaled.
Corrosion
GHS05
Corrosive. Causes severe skin burns and eye damage.
Environment
GHS09
Environmental hazard. Toxic to aquatic life with long lasting effects.
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2811 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Zink-Pyrithion |
| Marine Pollutant | No |
Frequently Asked Questions
What is zinc bis(1-oxidopyridin-1-ium-2-thiolate)?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is an organometallic compound with the molecular formula C10H8N2O2S2Zn and CAS number 13463-41-7. This zinc complex contains pyridine-based ligands with thiolate groups, forming a coordination compound with a molecular weight of 317.7 g/mol. It is classified as a highly hazardous substance with multiple toxicity concerns including reproductive toxicity, acute toxicity, and environmental hazards.
What are the physicochemical properties of zinc bis(1-oxidopyridin-1-ium-2-thiolate)?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is a solid organometallic compound with a molecular weight of 317.7 g/mol and the molecular formula C10H8N2O2S2Zn. As a zinc coordination complex containing sulfur and nitrogen heteroatoms, it typically exhibits limited water solubility. The compound's specific physical appearance, odor characteristics, and detailed solubility data require consultation of the safety data sheet for precise handling information.
What is zinc bis(1-oxidopyridin-1-ium-2-thiolate) used for?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is primarily used as an antimicrobial agent and preservative in industrial applications. Its biocidal properties make it valuable in formulations requiring microbial control, particularly in coatings, paints, and polymer preservation systems. Due to its high toxicity classification and reproductive hazards, its use is restricted to professional and industrial applications where proper safety measures can be implemented.
How to handle zinc bis(1-oxidopyridin-1-ium-2-thiolate) safely?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) requires maximum safety precautions due to its Danger signal word and multiple hazard classifications. Essential protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection to prevent inhalation. Work must be conducted in well-ventilated areas or under fume extraction systems. Avoid skin and eye contact completely, as the substance causes serious eye damage and acute toxicity.
How to store zinc bis(1-oxidopyridin-1-ium-2-thiolate) correctly?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) must be stored in a cool, dry, well-ventilated area away from incompatible materials. Keep containers tightly sealed and protected from moisture and heat sources. Due to its aquatic toxicity classification, storage areas must prevent environmental release. Store separately from food, feed, and drinking water supplies. Access should be restricted to trained personnel only, with appropriate safety equipment readily available.
What to do in case of contact with zinc bis(1-oxidopyridin-1-ium-2-thiolate)?
Immediate medical attention is required for any exposure to zinc bis(1-oxidopyridin-1-ium-2-thiolate) due to its acute toxicity. For skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes and seek urgent medical care due to serious eye damage potential. If inhaled, move to fresh air immediately and get medical attention.
How to dispose of zinc bis(1-oxidopyridin-1-ium-2-thiolate) appropriately?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) disposal must comply with hazardous waste regulations due to its multiple danger classifications and environmental toxicity. The substance cannot be disposed of in normal waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies familiar with toxic and environmentally hazardous materials. Prevent release to waterways or soil due to its aquatic toxicity classification.
How to transport zinc bis(1-oxidopyridin-1-ium-2-thiolate)?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is classified under ADR Class 6.1 (Toxic substances), Packing Group II, indicating significant transport hazards. Transportation requires appropriate UN-approved packaging, proper labeling with GHS pictogrammes (GHS08, GHS06, GHS05, GHS09), and shipping documentation indicating its toxic nature. Only certified carriers experienced in dangerous goods transportation should handle shipments, following all ADR regulatory requirements.
Is zinc bis(1-oxidopyridin-1-ium-2-thiolate) subject to specific regulations?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is subject to extensive regulatory control under REACH and CLP regulations due to its multiple hazard classifications including reproductive toxicity (Repr. 1B) and acute toxicity. While not currently listed as an SVHC substance, its use may be restricted in consumer applications due to safety concerns. Professional users must comply with occupational exposure limits, risk assessment requirements, and appropriate risk management measures.
Where to buy zinc bis(1-oxidopyridin-1-ium-2-thiolate) in Europe?
Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is available through OYSI, a specialized European distributor of technical chemicals. As a highly regulated substance with multiple hazard classifications, purchase is typically restricted to qualified industrial and professional users who can demonstrate appropriate safety measures and regulatory compliance. Contact OYSI directly for availability, technical specifications, and regulatory documentation required for safe handling and use.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.