Zinc bis(1-oxidopyridin-1-ium-2-thiolate)

C10H8N2O2S2Zn

zinc bis(1-oxidopyridin-1-ium-2-thiolate)

CAS13463-41-7
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
13463-41-7
EC Number
236-671-3
UN Number
2811
Index Number
613-333-00-7
PubChem CID
26041

Physical-chemical properties

Molecular Formula
C10H8N2O2S2Zn
Molar Mass
317.70 g/mol
IUPAC Name
zinc bis(1-oxidopyridin-1-ium-2-thiolate)

Chemical Identifiers

InChI
InChI=1S/2C5H5NOS.Zn/c2*7-6-4-2-1-3-5(6)8;/h2*1-4,8H;/q;;+2/p-2
InChI Key
OTPSWLRZXRHDNX-UHFFFAOYSA-L

Overview

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) (CAS 13463-41-7) is an organometallic zinc complex with antimicrobial and biocidal properties. This specialized zinc-based compound, also identified by its EC number 236-671-3, represents a sophisticated organometallic complex where zinc coordinates with two 1-oxidopyridin-1-ium-2-thiolate ligands. With a molecular formula of C10H8N2O2S2Zn and molecular weight of 317.7 g/mol, this substance demonstrates unique chemical characteristics that make it valuable in various industrial applications requiring antimicrobial activity. The compound exhibits significant biological activity, which is reflected in its comprehensive hazard classification. It carries multiple serious health warnings including reproductive toxicity (Repr. 1B), acute toxicity (Acute Tox. 2 and 3), and specific target organ toxicity with repeated exposure (STOT RE 1). The substance also presents severe eye damage potential (Eye Dam. 1) and poses considerable environmental risks with both acute and chronic aquatic toxicity classifications. These properties necessitate careful handling protocols and appropriate safety measures during storage, transport, and application. Unlike simpler biocidal agents such as 2,2-dibromo-2-cyanoacetamide, this zinc complex offers specific coordination chemistry advantages that can provide sustained antimicrobial action. The compound finds primary applications in specialized biocidal formulations, antimicrobial coatings for industrial surfaces, and as an active ingredient in certain preservative systems where zinc-based antimicrobial activity is specifically required. Transportation regulations classify this material under ADR Class 6.1, requiring compliance with toxic substance handling protocols. OYSI maintains technical-grade zinc bis(1-oxidopyridin-1-ium-2-thiolate) inventory to support European industrial customers requiring this specialized organometallic antimicrobial compound.

Safety & Classification

Danger
Classification:

Repr. 1B; Acute Tox. 2; Acute Tox. 3; STOT RE 1; Eye Dam. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H318

Causes serious eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2811
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameZink-Pyrithion
Marine PollutantNo

Frequently Asked Questions

What is zinc bis(1-oxidopyridin-1-ium-2-thiolate)?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is an organometallic compound with the molecular formula C10H8N2O2S2Zn and CAS number 13463-41-7. This zinc complex contains pyridine-based ligands with thiolate groups, forming a coordination compound with a molecular weight of 317.7 g/mol. It is classified as a highly hazardous substance with multiple toxicity concerns including reproductive toxicity, acute toxicity, and environmental hazards.

What are the physicochemical properties of zinc bis(1-oxidopyridin-1-ium-2-thiolate)?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is a solid organometallic compound with a molecular weight of 317.7 g/mol and the molecular formula C10H8N2O2S2Zn. As a zinc coordination complex containing sulfur and nitrogen heteroatoms, it typically exhibits limited water solubility. The compound's specific physical appearance, odor characteristics, and detailed solubility data require consultation of the safety data sheet for precise handling information.

What is zinc bis(1-oxidopyridin-1-ium-2-thiolate) used for?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is primarily used as an antimicrobial agent and preservative in industrial applications. Its biocidal properties make it valuable in formulations requiring microbial control, particularly in coatings, paints, and polymer preservation systems. Due to its high toxicity classification and reproductive hazards, its use is restricted to professional and industrial applications where proper safety measures can be implemented.

How to handle zinc bis(1-oxidopyridin-1-ium-2-thiolate) safely?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) requires maximum safety precautions due to its Danger signal word and multiple hazard classifications. Essential protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection to prevent inhalation. Work must be conducted in well-ventilated areas or under fume extraction systems. Avoid skin and eye contact completely, as the substance causes serious eye damage and acute toxicity.

How to store zinc bis(1-oxidopyridin-1-ium-2-thiolate) correctly?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) must be stored in a cool, dry, well-ventilated area away from incompatible materials. Keep containers tightly sealed and protected from moisture and heat sources. Due to its aquatic toxicity classification, storage areas must prevent environmental release. Store separately from food, feed, and drinking water supplies. Access should be restricted to trained personnel only, with appropriate safety equipment readily available.

What to do in case of contact with zinc bis(1-oxidopyridin-1-ium-2-thiolate)?

Immediate medical attention is required for any exposure to zinc bis(1-oxidopyridin-1-ium-2-thiolate) due to its acute toxicity. For skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes and seek urgent medical care due to serious eye damage potential. If inhaled, move to fresh air immediately and get medical attention.

How to dispose of zinc bis(1-oxidopyridin-1-ium-2-thiolate) appropriately?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) disposal must comply with hazardous waste regulations due to its multiple danger classifications and environmental toxicity. The substance cannot be disposed of in normal waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies familiar with toxic and environmentally hazardous materials. Prevent release to waterways or soil due to its aquatic toxicity classification.

How to transport zinc bis(1-oxidopyridin-1-ium-2-thiolate)?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is classified under ADR Class 6.1 (Toxic substances), Packing Group II, indicating significant transport hazards. Transportation requires appropriate UN-approved packaging, proper labeling with GHS pictogrammes (GHS08, GHS06, GHS05, GHS09), and shipping documentation indicating its toxic nature. Only certified carriers experienced in dangerous goods transportation should handle shipments, following all ADR regulatory requirements.

Is zinc bis(1-oxidopyridin-1-ium-2-thiolate) subject to specific regulations?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is subject to extensive regulatory control under REACH and CLP regulations due to its multiple hazard classifications including reproductive toxicity (Repr. 1B) and acute toxicity. While not currently listed as an SVHC substance, its use may be restricted in consumer applications due to safety concerns. Professional users must comply with occupational exposure limits, risk assessment requirements, and appropriate risk management measures.

Where to buy zinc bis(1-oxidopyridin-1-ium-2-thiolate) in Europe?

Zinc bis(1-oxidopyridin-1-ium-2-thiolate) is available through OYSI, a specialized European distributor of technical chemicals. As a highly regulated substance with multiple hazard classifications, purchase is typically restricted to qualified industrial and professional users who can demonstrate appropriate safety measures and regulatory compliance. Contact OYSI directly for availability, technical specifications, and regulatory documentation required for safe handling and use.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.