Chloro(methyl)mercury
CH3ClHg
chloro(methyl)mercury
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Identification
- CAS Number
- 115-09-3
- EC Number
- 204-064-2
- UN Number
- 3467
- Index Number
- 080-012-00-0
- PubChem CID
- 409301
Physical-chemical properties
- Molecular Formula
- CH3ClHg
- Molar Mass
- 251.08 g/mol
- IUPAC Name
- chloro(methyl)mercury
Chemical Identifiers
- InChI
- InChI=1S/CH3.ClH.Hg/h1H3;1H;/q;;+1/p-1
- InChI Key
- BABMCXWQNSQAOC-UHFFFAOYSA-M
Overview
Chloro(methyl)mercury (CAS 115-09-3) is an organomercury compound with high toxicity and carcinogenic properties. This chemical substance represents one of the most hazardous organometallic compounds encountered in industrial chemistry, requiring extreme caution in handling and storage due to its severe health implications. With the molecular formula CH3ClHg and a molecular weight of 251.08 g/mol, chloro(methyl)mercury belongs to the family of methylmercury compounds that have gained significant attention due to their environmental persistence and bioaccumulation potential. The compound is classified under multiple hazard categories including carcinogenicity (Category 2), reproductive toxicity (Category 1A), acute toxicity (Category 2), and specific target organ toxicity (Category 1). The GHS pictograms GHS08, GHS06, and GHS09 clearly indicate its health hazards, acute toxicity, and environmental dangers respectively. The substance's classification under ADR Class 6.1 reflects its status as a toxic material requiring specialized transportation protocols. Unlike other toxic organic compounds such as N-methylaniline or phenylhydrazine, chloro(methyl)mercury poses additional environmental risks due to mercury's persistence and biomagnification in ecosystems. The compound exhibits particular concern for aquatic environments, as indicated by its Aquatic Acute 1 classification. Industrial applications of chloro(methyl)mercury are highly restricted and primarily limited to specialized research purposes, analytical chemistry standards, and specific catalytic processes under controlled laboratory conditions. Due to increasing regulatory restrictions, many industrial processes have transitioned to safer alternatives. OYSI maintains strict compliance with all European regulations regarding the distribution of this highly controlled substance, ensuring proper documentation and safety protocols for qualified industrial customers.
Safety & Classification
Carc. 2; Repr. 1A; Lact.; Acute Tox. 2; Acute Tox. 2; Acute Tox. 2; STOT RE 1; Aquatic Acute 1; A...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing cancer.
May cause harm to breast-fed children.
Fatal if inhaled.
Fatal in contact with skin.
Fatal if swallowed.
Causes damage to organs through prolonged or repeated exposure.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3467 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Methylquecksilberchlorid |
| Marine Pollutant | No |
Frequently Asked Questions
What is chloro(methyl)mercury?
Chloro(methyl)mercury is an organomercury compound with the chemical formula CH3ClHg and CAS number 115-09-3. This substance has a molecular weight of 251.08 g/mol and belongs to the family of methylmercury compounds. It is classified as extremely hazardous, carrying multiple danger classifications including carcinogenic, reproductive toxic, and acutely toxic properties. The compound poses significant risks to human health and the environment, requiring strict handling protocols and regulatory oversight.
What are the physicochemical properties of chloro(methyl)mercury?
Chloro(methyl)mercury is an organometallic compound that typically appears as a crystalline solid at room temperature. Like other organomercury compounds, it exhibits high toxicity and bioaccumulation potential. The substance has limited solubility in water but may dissolve in organic solvents. Its molecular structure consists of a methyl group bonded to mercury, which is also bonded to a chlorine atom, creating a linear molecular geometry characteristic of organomercury compounds.
What is chloro(methyl)mercury used for?
Chloro(methyl)mercury is primarily used in specialized research applications and as a laboratory reagent for analytical chemistry purposes. Due to its extreme toxicity and environmental persistence, its industrial applications are severely restricted. It may be used in very limited quantities for scientific research involving organomercury chemistry studies, toxicological research, or as a reference standard in analytical laboratories. Most commercial uses have been phased out due to health and environmental concerns.
How to handle chloro(methyl)mercury safely?
Chloro(methyl)mercury requires extreme safety precautions due to its high toxicity. Personal protective equipment must include chemical-resistant gloves, full face protection, and respiratory protection in well-ventilated areas or fume hoods. Work should be conducted in designated areas with restricted access. Avoid any skin contact, ingestion, or inhalation. Emergency procedures and decontamination protocols must be established before handling. Only trained personnel should work with this substance under strict supervision.
How to store chloro(methyl)mercury correctly?
Chloro(methyl)mercury must be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Storage should occur in tightly sealed, chemically resistant containers within secondary containment systems. Access must be restricted to authorized personnel only, with clear labeling indicating the extreme hazards. Storage areas should be equipped with appropriate ventilation and spill containment measures. Regular inspection of containers and storage conditions is essential to prevent leaks or degradation.
What to do in case of contact with chloro(methyl)mercury?
Chloro(methyl)mercury exposure requires immediate emergency response. For skin contact, remove contaminated clothing and wash affected area with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately. For eye contact, flush with water for 15 minutes. Seek immediate medical attention in all cases of exposure, informing medical personnel of the specific substance involved. Do not induce vomiting if ingested. Contact poison control centers and follow their guidance.
How to dispose of chloro(methyl)mercury appropriately?
Chloro(methyl)mercury disposal requires specialized hazardous waste treatment due to its extreme toxicity and environmental persistence. The substance must be collected by licensed hazardous waste disposal companies equipped to handle mercury-containing compounds. It cannot be disposed of in regular waste streams, sewers, or landfills. All containers and contaminated materials must be treated as hazardous waste. Disposal must comply with local, national, and international regulations governing mercury and toxic substance waste management.
How to transport chloro(methyl)mercury?
Chloro(methyl)mercury is classified under ADR Class 6.1 (toxic substances) Packing Group II, indicating high toxicity requiring strict transport regulations. Transportation must comply with dangerous goods regulations, using appropriate packaging, labeling, and documentation. Only certified carriers authorized to transport toxic materials may handle shipments. Packages must display proper hazard labels and placards. Transport vehicles require specific safety equipment, and drivers must have hazardous materials training and certification.
Is chloro(methyl)mercury subject to specific regulations?
Chloro(methyl)mercury is subject to extensive regulatory oversight under multiple frameworks including REACH, CLP, and mercury-specific regulations. It carries classification as Carcinogenic Category 2, Reproductive Toxicity Category 1A, and multiple acute toxicity classifications. The substance requires safety data sheets, exposure assessments, and risk management measures. Its manufacture, import, use, and disposal are heavily restricted due to its extreme hazards to human health and the environment. Compliance with mercury conventions is mandatory.
Where to buy chloro(methyl)mercury in Europe?
Chloro(methyl)mercury is available through specialized chemical distributors in Europe, including OYSI, which supplies laboratory and research-grade chemicals to qualified customers. Due to its extreme toxicity and regulatory restrictions, purchases are limited to authorized research institutions, analytical laboratories, and qualified industrial users. Buyers must demonstrate legitimate use, provide appropriate safety protocols, and comply with all regulatory requirements. Availability may be restricted based on local regulations and end-use applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.