Chloro(methyl)mercury
CH3ClHg
chloro(methyl)mercury
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Identification
- CAS Number
- 115-09-3
- EC Number
- 204-064-2
- UN Number
- 3467
- Index Number
- 080-012-00-0
- PubChem CID
- 409301
Physical-chemical properties
- Molecular Formula
- CH3ClHg
- Molar Mass
- 251.08 g/mol
- IUPAC Name
- chloro(methyl)mercury
Chemical Identifiers
- InChI
- InChI=1S/CH3.ClH.Hg/h1H3;1H;/q;;+1/p-1
- InChI Key
- BABMCXWQNSQAOC-UHFFFAOYSA-M
Overview
Chloro(methyl)mercury (CAS 115-09-3) is an organomercury compound with highly toxic properties and severe health hazards. This chemical substance, with the molecular formula CH3ClHg and molecular weight of 251.08 g/mol, represents one of the most dangerous classes of mercury-containing compounds due to its ability to cross biological membranes and accumulate in living tissues. As an organometallic compound, chloro(methyl)mercury exhibits exceptional toxicity characteristics that require extreme caution in handling and storage. The substance is classified under multiple hazard categories including carcinogenicity (Category 2), reproductive toxicity (Category 1A), and acute toxicity (Category 2) for oral, dermal, and inhalation exposure routes. Its GHS pictograms (GHS08, GHS06, GHS09) clearly indicate the health hazards, acute toxicity, and environmental dangers associated with this compound. The ADR classification of 6.1 confirms its status as a toxic substance requiring specialized transportation protocols. The compound's toxicological profile is particularly concerning due to its potential for bioaccumulation and its ability to cause specific target organ toxicity following repeated exposure (STOT RE 1). Unlike other mercury compounds or related toxic substances such as dichlorocadmium, chloro(methyl)mercury demonstrates exceptional mobility in biological systems, making exposure prevention absolutely critical. Industrial applications of chloro(methyl)mercury are highly restricted and primarily limited to specialized research applications, analytical chemistry standards, and specific synthetic processes under controlled laboratory conditions. Some applications include use as a reference material in environmental analysis and as an intermediate in specialized organometallic synthesis reactions. OYSI maintains strict protocols for the handling and distribution of this controlled substance, ensuring compliance with all European chemical safety regulations and providing comprehensive safety documentation to qualified industrial customers.
Safety & Classification
Carc. 2; Repr. 1A; Lact.; Acute Tox. 2; Acute Tox. 2; Acute Tox. 2; STOT RE 1; Aquatic Acute 1; A...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing cancer.
May cause harm to breast-fed children.
Fatal if inhaled.
Fatal in contact with skin.
Fatal if swallowed.
Causes damage to organs through prolonged or repeated exposure.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3467 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Methylquecksilberchlorid |
| Marine Pollutant | No |
Frequently Asked Questions
What is chloro(methyl)mercury?
Chloro(methyl)mercury is an organomercury compound with the chemical formula CH3ClHg and CAS number 115-09-3. This substance has a molecular weight of 251.08 g/mol and represents one of the most hazardous mercury-containing chemicals. It is classified as a carcinogen category 2, reproductive toxicant category 1A, and presents severe acute toxicity through multiple exposure routes. The compound poses significant environmental risks due to its aquatic toxicity and bioaccumulation potential.
What are the physicochemical properties of chloro(methyl)mercury?
Chloro(methyl)mercury is typically a colorless to white crystalline solid at room temperature with high volatility. The compound is moderately soluble in water and highly soluble in organic solvents. It exhibits a characteristic metallic odor and can sublime at relatively low temperatures. Due to its organomercury structure, it demonstrates high lipophilicity, allowing it to easily penetrate biological membranes and accumulate in fatty tissues, contributing to its extreme toxicity profile.
What is chloro(methyl)mercury used for?
Chloro(methyl)mercury is primarily used as a research chemical and analytical standard in laboratory settings. It serves as a precursor in the synthesis of other organomercury compounds and is utilized in specialized analytical procedures for mercury speciation studies. Due to its extreme toxicity and environmental persistence, its commercial applications are severely restricted. The compound may also be used in very limited quantities for academic research related to mercury toxicology and environmental fate studies.
How to handle chloro(methyl)mercury safely?
Chloro(methyl)mercury requires extreme safety precautions including full personal protective equipment with chemical-resistant gloves, safety goggles, and respiratory protection. Work must be conducted in a well-ventilated fume hood or containment system. Avoid any skin contact, inhalation, or ingestion as the compound is extremely toxic through all exposure routes. Emergency procedures should be established before handling, and only trained personnel should work with this substance under strict supervision and documented safety protocols.
How to store chloro(methyl)mercury correctly?
Chloro(methyl)mercury must be stored in tightly sealed, chemically compatible containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Storage areas should be secured with restricted access and appropriate hazard signage. The compound should be kept away from strong oxidizing agents, acids, and reducing agents. Secondary containment is recommended to prevent environmental release. Regular inspection of containers and storage conditions is essential to prevent leaks or degradation.
What to do in case of contact with chloro(methyl)mercury?
Chloro(methyl)mercury exposure requires immediate emergency response and medical attention. For skin contact, immediately remove contaminated clothing and flush with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately and provide oxygen if breathing is difficult. In case of eye contact, flush with water for at least 15 minutes. Never induce vomiting if ingested. Seek immediate medical attention for all exposure routes and provide safety data sheet to medical personnel.
How to dispose of chloro(methyl)mercury appropriately?
Chloro(methyl)mercury disposal must comply with hazardous waste regulations and requires specialized treatment by licensed waste management facilities. The compound cannot be disposed of through normal waste streams due to its extreme toxicity and mercury content. Waste must be properly labeled, contained in appropriate vessels, and handled according to local and international hazardous waste transport regulations. Recovery and recycling of mercury content may be required depending on local environmental regulations and waste management protocols.
How to transport chloro(methyl)mercury?
Chloro(methyl)mercury is classified under ADR Class 6.1 (Toxic substances) Packing Group II, indicating high toxicity requiring specialized transport procedures. Packaging must meet UN specification standards with proper labeling including GHS pictograms GHS06, GHS08, and GHS09. Transport documents must include proper shipping names, hazard classes, and emergency response information. Only authorized carriers trained in dangerous goods transport should handle shipments, and emergency response procedures must be readily available during transport.
Is chloro(methyl)mercury subject to specific regulations?
Chloro(methyl)mercury is subject to extensive regulatory controls under REACH, CLP, and various national chemical safety regulations. As a highly toxic organomercury compound, it requires safety data sheets, exposure assessments, and risk management measures. The substance is classified with multiple hazard categories including carcinogenicity, reproductive toxicity, and environmental hazards. Import, manufacture, and use may require specific authorizations or notifications depending on jurisdiction. Mercury-containing compounds are also subject to international treaties like the Minamata Convention.
Where to buy chloro(methyl)mercury in Europe?
Chloro(methyl)mercury is available through specialized chemical distributors like OYSI, which supplies high-quality research chemicals across Europe. Due to the substance's extreme hazards and regulatory restrictions, procurement requires proper documentation, safety certifications, and compliance with local regulations. Buyers must demonstrate legitimate research purposes, appropriate handling facilities, and trained personnel. OYSI can provide technical support, safety documentation, and regulatory guidance for European customers requiring this specialized organomercury compound for analytical or research applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.