Butyl 2-methylprop-2-enoate

C8H14O2

butyl 2-methylprop-2-enoate

CAS97-88-1
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
97-88-1
EC Number
202-615-1
UN Number
2227
Index Number
607-033-00-5
PubChem CID
7354

Physical-chemical properties

Molecular Formula
C8H14O2
Molar Mass
142.20 g/mol
IUPAC Name
butyl 2-methylprop-2-enoate

Chemical Identifiers

InChI
InChI=1S/C8H14O2/c1-4-5-6-10-8(9)7(2)3/h2,4-6H2,1,3H3
InChI Key
SOGAXMICEFXMKE-UHFFFAOYSA-N

Overview

Butyl 2-methylprop-2-enoate (CAS 97-88-1) is a methacrylate ester monomer with polymerizable vinyl functionality and moderate volatility characteristics. This colorless liquid chemical compound, also known by its EC number 202-615-1, belongs to the family of acrylic monomers widely utilized in polymer chemistry and industrial manufacturing processes. With a molecular formula of C8H14O2 and molecular weight of 142.2 g/mol, butyl 2-methylprop-2-enoate exhibits typical methacrylate properties including the ability to undergo free radical polymerization to form high-performance polymeric materials. The substance presents several safety considerations that require proper handling protocols. Classified as a flammable liquid (Category 3) under ADR Class 3 transportation regulations, it carries GHS02 and GHS07 pictograms with a "Warning" signal word. The compound can cause skin and eye irritation, skin sensitization, and may cause drowsiness or dizziness through respiratory exposure. Its flammable nature necessitates appropriate storage conditions away from ignition sources and adequate ventilation during use. Industrial applications of butyl 2-methylprop-2-enoate span multiple sectors, particularly in the production of acrylic resins, adhesives, and surface coatings where its excellent film-forming properties and durability are valued. The automotive and construction industries utilize polymers derived from this monomer for protective coatings and sealants. Similar to related compounds like butyl prop-2-enoate, it serves as a key building block in specialty polymer formulations requiring specific mechanical and chemical resistance properties. OYSI maintains reliable supply chains for butyl 2-methylprop-2-enoate, ensuring consistent availability for European industrial customers requiring this essential methacrylate monomer for their manufacturing operations.

Safety & Classification

Warning
Classification:

Flam. Liq. 3; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2227
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping Namen-Butylmethacrylat, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is butyl 2-methylprop-2-enoate?

Butyl 2-methylprop-2-enoate is an organic chemical compound with the molecular formula C8H14O2 and CAS number 97-88-1. It belongs to the family of methacrylate esters, specifically butyl methacrylate, with a molecular weight of 142.2 g/mol. This compound is classified as a flammable liquid and presents moderate health hazards including skin and eye irritation, skin sensitization, and specific target organ toxicity. It requires careful handling due to its irritant and sensitizing properties.

What are the physicochemical properties of butyl 2-methylprop-2-enoate?

Butyl 2-methylprop-2-enoate is a clear, colorless liquid at room temperature with a characteristic acrylic odor. It has a molecular weight of 142.2 g/mol and the molecular formula C8H14O2. The compound is classified as a flammable liquid (Category 3) under GHS classification. It exhibits limited water solubility due to its organic ester structure but is soluble in most organic solvents. The substance polymerizes readily under appropriate conditions, making it valuable for various chemical applications.

What is butyl 2-methylprop-2-enoate used for?

Butyl 2-methylprop-2-enoate serves primarily as a monomer in the production of acrylic polymers and copolymers. It is widely used in the manufacture of paints, coatings, adhesives, and sealants where flexibility and weather resistance are required. The compound also finds applications in the production of textiles, leather finishing, and paper coatings. Additionally, it serves as an intermediate in organic synthesis and is utilized in the formulation of various industrial chemical products.

How to handle butyl 2-methylprop-2-enoate safely?

Butyl 2-methylprop-2-enoate requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or use local exhaust ventilation to prevent vapor accumulation. Avoid skin and eye contact as the substance causes irritation and skin sensitization. Keep away from heat sources, sparks, and open flames due to its flammable nature. Use non-sparking tools and ensure proper grounding of equipment during transfer operations.

How to store butyl 2-methylprop-2-enoate correctly?

Butyl 2-methylprop-2-enoate must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Keep containers tightly closed and store below 25°C to prevent polymerization. The substance should be separated from strong oxidizing agents, acids, and bases. Use original containers or compatible materials for storage. Implement appropriate fire prevention measures in storage areas and ensure containers are properly labeled according to GHS requirements.

What to do in case of contact with butyl 2-methylprop-2-enoate?

Skin contact with butyl 2-methylprop-2-enoate requires immediate removal of contaminated clothing and thorough washing with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and keep at rest. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms of irritation or sensitization develop.

How to dispose of butyl 2-methylprop-2-enoate properly?

Butyl 2-methylprop-2-enoate disposal must comply with local, national, and European waste regulations including the Waste Framework Directive. The substance should be treated as hazardous waste and disposed of through licensed waste management facilities. Incineration at high temperatures in approved facilities is typically the preferred method. Do not discharge into sewers, water bodies, or soil. Small quantities may be absorbed on inert material and disposed of according to local hazardous waste regulations.

How to transport butyl 2-methylprop-2-enoate?

Butyl 2-methylprop-2-enoate is classified under ADR as Class 3 (flammable liquids), Packing Group III for transportation purposes. It requires appropriate packaging, labeling, and documentation according to dangerous goods regulations. Vehicles must carry appropriate fire extinguishing equipment and emergency cards. Drivers need ADR training certification for transporting this substance. Ensure proper segregation from incompatible materials during transport and follow all applicable national and international dangerous goods regulations.

Is butyl 2-methylprop-2-enoate subject to specific regulations?

Butyl 2-methylprop-2-enoate is subject to European REACH regulation requiring registration for manufacture or import above one tonne per year. The substance must be classified and labeled according to CLP regulation with Warning signal word and GHS02/GHS07 pictograms. It is not currently listed as a Substance of Very High Concern (SVHC). Industrial users must implement appropriate risk management measures and provide safety data sheets. Workplace exposure limits may apply depending on national regulations.

Where to buy butyl 2-methylprop-2-enoate in Europe?

Butyl 2-methylprop-2-enoate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides this substance with complete regulatory compliance including safety data sheets, certificates of analysis, and proper dangerous goods documentation. The company ensures reliable supply chain management and technical support for industrial applications. Contact OYSI directly for specific quantities, packaging options, and delivery arrangements to your European location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.