Trichloro(methyl)silane
CH3Cl3Si
trichloro(methyl)silane
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Identification
- CAS Number
- 75-79-6
- EC Number
- 200-902-6
- UN Number
- 1250
- Index Number
- 014-004-00-5
- PubChem CID
- 6399
Physical-chemical properties
- Molecular Formula
- CH3Cl3Si
- Molar Mass
- 149.47 g/mol
- IUPAC Name
- trichloro(methyl)silane
Chemical Identifiers
- InChI
- InChI=1S/CH3Cl3Si/c1-5(2,3)4/h1H3
- InChI Key
- JLUFWMXJHAVVNN-UHFFFAOYSA-N
Overview
Trichloro(methyl)silane (CAS 75-79-6) is an organosilicon compound with highly reactive chlorosilane properties and flammable characteristics. This organosilicon compound represents a crucial intermediate in silicone chemistry and surface modification applications. With its molecular formula CH3Cl3Si and molecular weight of 149.47 g/mol, trichloro(methyl)silane belongs to the chlorosilane family, which serves as fundamental building blocks for various silicon-based materials. The compound features three highly reactive chlorine atoms bonded to a silicon center, along with a methyl group, making it an essential precursor for methylsiloxane polymers and surface treatment agents. From a safety perspective, trichloro(methyl)silane requires careful handling due to its classification as a flammable liquid (Category 2) and its potential to cause skin and eye irritation. The substance also presents specific target organ toxicity concerns, necessitating appropriate protective equipment and ventilation systems during industrial use. Its ADR Class 3 classification reflects the fire hazards associated with this volatile compound, requiring specialized storage and transportation protocols. Industrial applications primarily focus on silicone polymer synthesis, where trichloro(methyl)silane serves as a key monomer for producing methylpolysiloxanes and various silicone resins. The compound also finds extensive use in surface modification treatments, particularly for glass, metals, and other substrates requiring hydrophobic properties. Additionally, it functions as an intermediate in the production of specialty chemicals and advanced materials in electronics and automotive industries. Unlike simpler compounds such as propanal, trichloro(methyl)silane offers unique silicon-carbon bonding capabilities essential for creating durable, temperature-resistant materials. OYSI provides trichloro(methyl)silane to European industrial customers, ensuring reliable supply chain support for silicone manufacturing and specialty chemical applications.
Safety & Classification
Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1250 |
| ADR Class | 3 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Methyltrichlorsilan |
| Marine Pollutant | No |
Frequently Asked Questions
What is trichloro(methyl)silane?
Trichloro(methyl)silane is an organosilicon compound with the molecular formula CH3Cl3Si and CAS number 75-79-6. This chemical substance has a molecular weight of 149.47 g/mol and belongs to the family of chlorosilanes. It is classified as a flammable liquid and presents multiple hazards including skin and eye irritation, as well as specific target organ toxicity. The compound is widely used in industrial applications for silicon-based chemical synthesis and surface modification processes.
What are the physicochemical properties of trichloro(methyl)silane?
Trichloro(methyl)silane is a colorless liquid with a pungent, acrid odor characteristic of chlorosilanes. It has a molecular weight of 149.47 g/mol and reacts violently with water, producing hydrogen chloride gas and silanols. The compound is highly flammable and volatile at room temperature. It is soluble in most organic solvents but must be kept strictly away from moisture due to its hydrolytic instability, which makes it corrosive to metals in the presence of water.
What is trichloro(methyl)silane used for?
Trichloro(methyl)silane is primarily used as a precursor in the synthesis of silicone polymers and resins. It serves as a coupling agent for surface modification of glass, metals, and other substrates to improve adhesion properties. The compound is also employed in the production of specialty silicones, protective coatings, and sealants. In the semiconductor industry, it can be used for chemical vapor deposition processes to create thin silicon-containing films on electronic components.
How to handle trichloro(methyl)silane safely?
Trichloro(methyl)silane must be handled wearing appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in a well-ventilated area or under a fume hood to avoid inhalation of vapors. Keep the substance away from heat sources, sparks, and open flames due to its flammable nature. Ensure no water or moisture contact occurs during handling, as this will cause violent reactions and release of corrosive hydrogen chloride gas.
How to store trichloro(methyl)silane correctly?
Trichloro(methyl)silane must be stored in tightly sealed, moisture-proof containers in a cool, dry, well-ventilated area away from heat sources and ignition sources. The storage area should be equipped with appropriate fire suppression systems and be separated from incompatible materials such as water, alcohols, and strong bases. Containers should be made of compatible materials and regularly inspected for integrity. Storage temperatures should be kept below 25°C to minimize vapor pressure and decomposition risks.
What to do in case of contact with trichloro(methyl)silane?
In case of skin contact with trichloro(methyl)silane, immediately remove contaminated clothing and wash the affected area thoroughly with plenty of water for at least 15 minutes. For eye contact, rinse immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. In case of ingestion, do not induce vomiting and rinse mouth with water. Seek immediate medical attention in all cases and provide the safety data sheet to medical personnel.
How to dispose of trichloro(methyl)silane properly?
Trichloro(methyl)silane must be disposed of as hazardous waste in accordance with local, national, and European waste regulations. The substance should never be poured down drains or released into the environment. Waste disposal must be carried out by licensed hazardous waste contractors who can handle flammable and corrosive materials. Empty containers may still contain residues and should also be treated as hazardous waste. Always consult local authorities for specific disposal requirements and authorized waste treatment facilities.
How to transport trichloro(methyl)silane?
Trichloro(methyl)silane is classified under ADR Class 3 (flammable liquids), Packing Group II, indicating moderate danger level for transportation. It must be transported in approved packaging that meets UN specification requirements and properly labeled with appropriate hazard placards. Vehicles must carry appropriate firefighting equipment and emergency response information. Drivers require ADR certification for dangerous goods transport. The substance must be segregated from incompatible materials during transport and protected from moisture and heat sources.
Is trichloro(methyl)silane subject to specific regulations?
Trichloro(methyl)silane is subject to REACH regulation requiring registration for manufacture or import above 1 tonne per year in the EU. It is classified under CLP regulation with hazard classes including Flam. Liq. 2, STOT SE 3, Skin Irrit. 2, and Eye Irrit. 2, requiring appropriate labeling with danger signal word and GHS02/GHS07 pictograms. The substance is not currently listed as a SVHC under REACH. Users must comply with occupational safety regulations and may need to prepare safety assessments for workplace use.
Where to buy trichloro(methyl)silane in Europe?
Trichloro(methyl)silane is available through OYSI, a European distributor of technical chemicals serving industrial customers across Europe. As a specialized chemical requiring proper handling and regulatory compliance, it is typically sold to qualified industrial users with appropriate safety infrastructure. Purchases require verification of end-use applications and compliance with chemical safety regulations. OYSI provides technical support and documentation including safety data sheets and certificates of analysis to ensure proper product handling and regulatory compliance.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.