Trichloro(methyl)silane

CH3Cl3Si

trichloro(methyl)silane

CAS75-79-6
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
75-79-6
EC Number
200-902-6
UN Number
1250
Index Number
014-004-00-5
PubChem CID
6399

Physical-chemical properties

Molecular Formula
CH3Cl3Si
Molar Mass
149.47 g/mol
IUPAC Name
trichloro(methyl)silane

Chemical Identifiers

InChI
InChI=1S/CH3Cl3Si/c1-5(2,3)4/h1H3
InChI Key
JLUFWMXJHAVVNN-UHFFFAOYSA-N

Overview

Trichloro(methyl)silane (CAS 75-79-6) is an organosilicon compound with highly reactive chlorosilane functionality used in chemical synthesis and surface modification applications. This versatile organosilicon compound serves as a crucial intermediate in silicone chemistry and surface treatment technologies. With its molecular formula CH3Cl3Si and molecular weight of 149.47 g/mol, trichloro(methyl)silane belongs to the chlorosilane family, which are known for their exceptional reactivity with water and alcohols to form siloxane bonds. The compound features three highly reactive chlorine atoms attached to a silicon center, along with one methyl group, making it an ideal building block for creating methylsiloxane polymers and specialized surface coatings. The substance presents significant safety considerations due to its flammable liquid classification (Flam. Liq. 2) and potential for causing skin and eye irritation. It requires careful handling under controlled conditions, as it readily hydrolyzes in the presence of moisture to release hydrogen chloride gas. Like other reactive organosilicon compounds such as dichloro(dimethyl)silane, proper storage in anhydrous conditions is essential to maintain product integrity and ensure safe handling. Primary industrial applications include the production of methylsilicone resins, hydrophobic surface treatments for glass and ceramics, and as a coupling agent in composite materials. The compound is particularly valuable in electronics manufacturing for creating protective coatings and in the automotive industry for glass treatment applications. Its reactivity profile makes it suitable for crosslinking reactions and the formation of durable siloxane networks. OYSI provides trichloro(methyl)silane to European industrial customers requiring reliable access to high-quality organosilicon intermediates for specialized chemical manufacturing processes.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1250
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameMethyltrichlorsilan
Marine PollutantNo

Frequently Asked Questions

What is trichloro(methyl)silane?

Trichloro(methyl)silane is an organosilicon compound with the chemical formula CH3Cl3Si and CAS number 75-79-6. This colorless liquid has a molecular weight of 149.47 g/mol and belongs to the chlorosilane family. It is classified as a flammable liquid with irritating properties to skin and eyes, and can cause specific target organ toxicity. The compound is widely used in chemical synthesis and surface modification applications due to its reactive silane functionality.

What are the physicochemical properties of trichloro(methyl)silane?

Trichloro(methyl)silane is a colorless liquid at room temperature with a pungent, acrid odor characteristic of chlorosilanes. It has a molecular weight of 149.47 g/mol and reacts vigorously with water, releasing hydrogen chloride gas. The compound is soluble in organic solvents but hydrolyzes rapidly in moisture. It exhibits flammable properties (Flam. Liq. 2) and can cause skin and eye irritation upon contact.

What is trichloro(methyl)silane used for?

Trichloro(methyl)silane serves as a key intermediate in silicone polymer production and surface modification applications. It is commonly used as a coupling agent to improve adhesion between organic and inorganic materials, particularly in glass fiber treatment and composite manufacturing. The compound also finds applications in the synthesis of methylsilicone resins, sealants, and coatings. Additionally, it is utilized in semiconductor manufacturing and as a precursor for specialized organosilicon compounds in various industrial processes.

How to handle trichloro(methyl)silane safely?

Trichloro(methyl)silane requires careful handling due to its flammable and irritating properties. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation of vapors. Keep away from heat sources, sparks, and open flames. Use non-sparking tools and ensure proper grounding of equipment. Avoid contact with water or moisture as this generates corrosive hydrogen chloride gas.

How to store trichloro(methyl)silane correctly?

Trichloro(methyl)silane must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and ignition sources. Keep containers away from incompatible materials such as water, alcohols, and strong bases. Store in original containers made of suitable materials that resist corrosion. Maintain storage temperatures below recommended limits and ensure proper labeling. Implement appropriate fire prevention measures and have suitable fire extinguishing equipment nearby due to its flammable nature.

What to do in case of contact with trichloro(methyl)silane?

Trichloro(methyl)silane contact requires immediate first aid measures. For skin contact, immediately remove contaminated clothing and wash the affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and seek medical help if breathing difficulties occur. For ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of trichloro(methyl)silane properly?

Trichloro(methyl)silane disposal must comply with local and national hazardous waste regulations. The compound cannot be disposed of through regular waste streams due to its hazardous classification. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized carefully by trained personnel using appropriate methods, but this should only be done following established safety procedures. Empty containers should also be treated as hazardous waste and disposed of accordingly.

How to transport trichloro(methyl)silane?

Trichloro(methyl)silane is classified as ADR Class 3 (flammable liquids), Packing Group II for transport purposes. It must be transported in approved containers and packaging that meet UN specifications. Vehicles must carry appropriate hazard placards and emergency response information. Drivers require ADR certification for dangerous goods transport. The shipment must be accompanied by proper transport documents and safety data sheets. Loading and unloading operations should follow strict safety protocols to prevent spills or exposure.

Is trichloro(methyl)silane subject to specific regulations?

Trichloro(methyl)silane is subject to various European chemical regulations including REACH registration requirements and CLP classification obligations. It is not currently listed as a Substance of Very High Concern (SVHC) under REACH. Suppliers must provide safety data sheets and ensure proper labeling with danger pictograms GHS02 and GHS07. The substance must be handled according to occupational health and safety regulations, and its use may be restricted in certain consumer applications under applicable chemical safety legislation.

Where to buy trichloro(methyl)silane in Europe?

Trichloro(methyl)silane is available through OYSI, a trusted European distributor of specialty chemicals. OYSI provides high-quality trichloro(methyl)silane with complete regulatory documentation including safety data sheets and certificates of analysis. As an established chemical distributor, OYSI ensures compliance with European regulations and offers reliable supply chain solutions. Contact OYSI directly for pricing, availability, and technical support for your trichloro(methyl)silane requirements across European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.