Tert-butyl prop-2-enoate
C7H12O2
tert-butyl prop-2-enoate
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Identification
- CAS Number
- 1663-39-4
- EC Number
- 216-768-7
- UN Number
- 3272
- Index Number
- 607-245-00-8
- PubChem CID
- 15458
Physical-chemical properties
- Molecular Formula
- C7H12O2
- Molar Mass
- 128.17 g/mol
- IUPAC Name
- tert-butyl prop-2-enoate
Chemical Identifiers
- InChI
- InChI=1S/C7H12O2/c1-5-6(8)9-7(2,3)4/h5H,1H2,2-4H3
- InChI Key
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N
Overview
Tert-butyl prop-2-enoate (CAS 1663-39-4) is an acrylic ester monomer with reactive vinyl functionality and enhanced thermal stability from its bulky tert-butyl group. This specialized acrylic monomer represents an important building block in polymer chemistry, combining the reactivity of acrylic acid derivatives with the steric properties of tertiary butyl substituents. The compound's molecular structure features a prop-2-enoate backbone with a tert-butyl ester group, providing unique polymerization characteristics that distinguish it from conventional acrylates. With its molecular formula C7H12O2 and molecular weight of 128.17 g/mol, tert-butyl prop-2-enoate exhibits properties that make it valuable for creating polymers with specific thermal and mechanical properties. The substance is classified as a flammable liquid requiring careful handling protocols due to its Class 3 ADR classification and associated safety hazards including acute toxicity and skin sensitization potential. Its vapor can form explosive mixtures with air, necessitating appropriate fire prevention measures and proper ventilation systems during processing. Like other acrylic compounds in this chemical family, including ethyl N-(2-methylpropoxycarbothioyl)carbamate, proper personal protective equipment and engineering controls are essential for safe handling. Primary industrial applications include specialty polymer synthesis, where the tert-butyl group provides enhanced thermal stability and altered glass transition temperatures in the resulting polymers. The monomer is particularly valuable in producing high-performance coatings and adhesives where temperature resistance is critical. Additionally, it serves as a reactive intermediate in pharmaceutical synthesis and specialty chemical manufacturing, where its unique steric properties enable selective chemical transformations. OYSI maintains reliable supplies of tert-butyl prop-2-enoate for European industrial customers, ensuring consistent quality and regulatory compliance for demanding applications.
Safety & Classification
Flam. Liq. 2; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Skin Sens...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
Skin Contact
Measures if substance contacts the skin
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3272 |
| ADR Class | 3 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | tert-Butylacrylat, stabilisiert |
| Marine Pollutant | No |
Frequently Asked Questions
What is tert-butyl prop-2-enoate?
Tert-butyl prop-2-enoate is an organic chemical compound with the molecular formula C7H12O2 and CAS number 1663-39-4. This ester has a molecular weight of 128.17 g/mol and belongs to the acrylate family. It is classified as a flammable liquid with multiple hazard properties including acute toxicity, skin irritation, and skin sensitization. The compound requires careful handling due to its danger classification and associated safety risks in industrial applications.
What are the physicochemical properties of tert-butyl prop-2-enoate?
Tert-butyl prop-2-enoate is a liquid organic compound at room temperature with the molecular formula C7H12O2. It has a molecular weight of 128.17 g/mol and exhibits flammable properties. As an acrylate ester, it typically has a characteristic acrylic odor and limited water solubility. The compound's physical state and chemical structure make it suitable for polymerization reactions and industrial synthesis applications requiring ester functionality.
What is tert-butyl prop-2-enoate used for?
Tert-butyl prop-2-enoate is primarily used as a monomer in polymer synthesis and as an intermediate in organic chemical manufacturing. Its acrylate structure makes it valuable for producing specialty polymers, coatings, and adhesives. The compound serves as a building block in the synthesis of various chemical products where the tert-butyl ester group provides specific properties such as steric hindrance and controlled reactivity in polymerization processes.
How to handle tert-butyl prop-2-enoate safely?
Tert-butyl prop-2-enoate requires careful handling due to its flammable nature and multiple health hazards. Essential safety measures include wearing appropriate personal protective equipment such as chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas away from ignition sources, heat, and open flames. Avoid skin contact and inhalation as the compound can cause skin irritation, sensitization, and acute toxicity effects.
How to store tert-butyl prop-2-enoate correctly?
Tert-butyl prop-2-enoate must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames due to its flammable classification. Use appropriate containers compatible with acrylate esters and ensure proper labeling with hazard information. Store away from incompatible materials such as strong oxidizers and bases. Maintain storage temperatures below recommended limits and implement proper inventory rotation to prevent degradation or polymerization.
What to do in case of contact with tert-butyl prop-2-enoate?
Immediate action is required in case of contact with tert-butyl prop-2-enoate due to its irritant and toxic properties. For skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately. For eye contact, flush with clean water for 15 minutes. Seek medical attention if irritation persists or if ingestion occurs. Always consult safety data sheets for complete first aid procedures.
How to dispose of tert-butyl prop-2-enoate appropriately?
Tert-butyl prop-2-enoate disposal must comply with local and national hazardous waste regulations due to its classification as a flammable and toxic substance. The compound cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies for proper collection and treatment. Small quantities may require neutralization or incineration under controlled conditions following regulatory guidelines and environmental protection standards.
How to transport tert-butyl prop-2-enoate?
Tert-butyl prop-2-enoate is classified under ADR Class 3 (flammable liquids), Packing Group II, requiring specific transport regulations compliance. The substance must be packaged in approved containers with proper hazard labeling including GHS pictograms GHS02, GHS07, and GHS09. Transportation requires appropriate documentation, vehicle placarding, and driver training for hazardous materials. Ensure compliance with international dangerous goods regulations for road, rail, sea, or air transport.
Is tert-butyl prop-2-enoate subject to particular regulations?
Tert-butyl prop-2-enoate is subject to various chemical regulations including REACH registration requirements in Europe and CLP classification for hazard communication. The compound is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with workplace safety regulations, environmental protection laws, and chemical inventory reporting requirements. Industrial users should maintain safety data sheets and implement appropriate risk management measures according to regulatory guidelines.
Where to buy tert-butyl prop-2-enoate in Europe?
Tert-butyl prop-2-enoate is available through OYSI, a European distributor specializing in technical chemical products. OYSI provides reliable supply chains for industrial customers requiring this acrylate monomer for manufacturing applications. As a professional chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for European markets. Contact OYSI directly for availability, technical specifications, and delivery options suited to your specific industrial requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.