Dichloro(dimethyl)silane

C2H6Cl2Si

dichloro(dimethyl)silane

CAS75-78-5
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
75-78-5
EC Number
200-901-0
UN Number
1162
Index Number
014-003-00-X
PubChem CID
6398

Physical-chemical properties

Molecular Formula
C2H6Cl2Si
Molar Mass
129.06 g/mol
IUPAC Name
dichloro(dimethyl)silane

Chemical Identifiers

InChI
InChI=1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3
InChI Key
LIKFHECYJZWXFJ-UHFFFAOYSA-N

Overview

Dichloro(dimethyl)silane (CAS 75-78-5) is an organosilicon compound with two chlorine atoms and two methyl groups bonded to a central silicon atom. This colorless liquid represents a crucial intermediate in organosilicon chemistry, serving as a fundamental building block for numerous silicon-based materials and compounds. With the molecular formula C2H6Cl2Si and a molecular weight of 129.06 g/mol, dichloro(dimethyl)silane exhibits the characteristic reactivity of chlorosilanes, particularly its susceptibility to hydrolysis in the presence of moisture. The compound belongs to the same chemical family as trichloro(methyl)silane, though it features two methyl groups instead of one, resulting in different reactivity patterns and applications. The substance presents significant safety considerations due to its flammable nature, classified as Flammable Liquid Category 2 under the GHS system. It requires careful handling as it can cause skin and eye irritation, and may cause respiratory tract irritation upon inhalation. The compound's reactivity with water generates hydrogen chloride, necessitating storage in dry conditions and appropriate containment measures. Transportation falls under ADR Class 3, reflecting its flammable liquid classification. Industrial applications of dichloro(dimethyl)silane primarily center on its role as a precursor in silicone polymer synthesis, where it serves as a chain terminator or branching agent. The compound finds extensive use in the production of specialized silicone fluids and resins, particularly those requiring specific viscosity and thermal properties. Additionally, it functions as a key intermediate in the manufacture of various organosilicon compounds used in surface treatment applications and as coupling agents. OYSI maintains reliable supplies of dichloro(dimethyl)silane to support European industrial operations requiring this essential organosilicon building block.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1162
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameDimethyldichlorsilan
Marine PollutantNo

Frequently Asked Questions

What is dichloro(dimethyl)silane?

Dichloro(dimethyl)silane is an organosilicon compound with the molecular formula C2H6Cl2Si and CAS number 75-78-5. This chemical substance has a molecular weight of 129.06 g/mol and belongs to the family of chlorosilanes. It is classified as a flammable liquid with irritating properties, requiring careful handling due to its hazardous nature. The compound is widely used in industrial applications as a chemical intermediate and reagent in various synthesis processes.

What are the physicochemical properties of dichloro(dimethyl)silane?

Dichloro(dimethyl)silane is a colorless liquid at room temperature with a pungent, irritating odor characteristic of chlorosilanes. The compound is highly reactive with water, undergoing hydrolysis to form silanol compounds and hydrogen chloride. It has a relatively low boiling point and is volatile under normal conditions. Due to its chemical structure containing both silicon-chlorine and silicon-carbon bonds, it exhibits typical organosilicon reactivity patterns and serves as an important building block in silicon chemistry.

What is dichloro(dimethyl)silane used for?

Dichloro(dimethyl)silane is primarily used as a chemical intermediate in the production of silicone polymers, resins, and other organosilicon compounds. It serves as a key building block in the synthesis of dimethylsilicone materials used in sealants, adhesives, and coatings. The compound is also employed in surface modification treatments, as a coupling agent, and in the manufacture of specialty chemicals. Its reactive chlorine atoms make it valuable for creating silicon-based materials with specific properties.

How to handle dichloro(dimethyl)silane safely?

Dichloro(dimethyl)silane requires careful handling using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods due to its irritating vapors. Avoid contact with skin, eyes, and respiratory system. Keep away from heat sources, sparks, and open flames as it is classified as Flam. Liq. 2. Ensure emergency eyewash stations and safety showers are readily accessible when handling this substance.

How to store dichloro(dimethyl)silane correctly?

Dichloro(dimethyl)silane must be stored in a cool, dry, well-ventilated area away from heat sources and ignition sources due to its flammable nature. Keep containers tightly sealed to prevent moisture contact, as the compound reacts with water. Store separately from incompatible materials such as strong bases, alcohols, and oxidizing agents. Use appropriate secondary containment and ensure storage areas comply with local fire safety regulations for flammable liquids classified under ADR Class 3, Packing Group II.

What to do in case of contact with dichloro(dimethyl)silane?

Dichloro(dimethyl)silane contact requires immediate action due to its irritating properties. For skin contact, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water for several minutes and remove contact lenses if present. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician after any significant exposure.

How to dispose of dichloro(dimethyl)silane properly?

Dichloro(dimethyl)silane disposal must comply with local, national, and European waste regulations as it is classified as hazardous waste. The substance should never be poured down drains or disposed of in regular waste streams. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized under controlled conditions by trained personnel, but this should only be done following established safety protocols and regulatory guidelines for chemical waste management.

How to transport dichloro(dimethyl)silane?

Dichloro(dimethyl)silane is classified under ADR Class 3 (flammable liquids) with Packing Group II, requiring specific transport regulations compliance. The substance must be packaged in UN-approved containers with proper labeling including GHS02 and GHS07 pictograms and 'Danger' signal word. Transport vehicles must carry appropriate emergency equipment and documentation. Only authorized carriers trained in hazardous materials transport should handle shipments, following all applicable dangerous goods regulations for road, rail, sea, or air transport within Europe.

Is dichloro(dimethyl)silane subject to specific regulations?

Dichloro(dimethyl)silane is subject to various European regulations including REACH registration requirements and CLP classification as Flam. Liq. 2, STOT SE 3, Skin Irrit. 2, and Eye Irrit. 2. The substance is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with occupational safety regulations, environmental protection laws, and transport regulations. Safety data sheets must be provided following CLP requirements, and workplace exposure limits should be observed where applicable.

Where to buy dichloro(dimethyl)silane in Europe?

Dichloro(dimethyl)silane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides high-quality chemical products with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures reliable supply chains and technical expertise for industrial applications. Contact OYSI directly for availability, specifications, packaging options, and delivery arrangements tailored to your specific requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.