Dichloro(dimethyl)silane

C2H6Cl2Si

dichloro(dimethyl)silane

CAS75-78-5
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
75-78-5
EC Number
200-901-0
UN Number
1162
Index Number
014-003-00-X
PubChem CID
6398

Physical-chemical properties

Molecular Formula
C2H6Cl2Si
Molar Mass
129.06 g/mol
IUPAC Name
dichloro(dimethyl)silane

Chemical Identifiers

InChI
InChI=1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3
InChI Key
LIKFHECYJZWXFJ-UHFFFAOYSA-N

Overview

Dichloro(dimethyl)silane (CAS 75-78-5) is an organosilicon compound with reactive chlorine groups used primarily as a silane coupling agent and chemical intermediate. This colorless liquid represents a fundamental building block in organosilicon chemistry, featuring two methyl groups and two chlorine atoms bonded to a central silicon atom. With its molecular formula C2H6Cl2Si and molecular weight of 129.06 g/mol, dichloro(dimethyl)silane exhibits high reactivity due to the presence of silicon-chlorine bonds, which readily undergo hydrolysis and substitution reactions. The compound belongs to the broader family of chlorosilanes, sharing chemical similarities with related compounds such as trichloro(methyl)silane, though it offers different reactivity patterns due to its specific substitution pattern. From a safety perspective, dichloro(dimethyl)silane requires careful handling as it is classified as a flammable liquid (Category 2) and poses risks including skin and eye irritation, as well as specific target organ toxicity. The compound carries the danger signal word and is associated with GHS pictograms GHS02 and GHS07, reflecting its fire hazard and health risks. During transport, it falls under ADR Class 3, requiring appropriate hazardous materials protocols. Industrial applications of dichloro(dimethyl)silane include its use as a precursor in silicone polymer synthesis, where it serves as a key intermediate for producing dimethylsiloxane units. It also functions as a surface modification agent in the treatment of glass and mineral substrates, and plays a role in the manufacture of specialty silicone materials for electronics and automotive industries. OYSI provides dichloro(dimethyl)silane to European industrial customers, ensuring reliable supply chains for demanding technical applications across various manufacturing sectors.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1162
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameDimethyldichlorsilan
Marine PollutantNo

Frequently Asked Questions

What is dichloro(dimethyl)silane?

Dichloro(dimethyl)silane is an organosilicon compound with the molecular formula C2H6Cl2Si and CAS number 75-78-5. This chemical substance has a molecular weight of 129.06 g/mol and belongs to the family of chlorosilanes. It is classified as a flammable liquid and presents several health hazards including skin and eye irritation, as well as specific target organ toxicity. The compound is widely used in industrial applications for silicon-based chemical synthesis and surface modification processes.

What are the physicochemical properties of dichloro(dimethyl)silane?

Dichloro(dimethyl)silane is a colorless liquid at room temperature with a characteristic pungent odor typical of chlorosilanes. The compound is highly reactive with water and moisture, undergoing hydrolysis to form hydrogen chloride gas and corresponding silanols. It has low viscosity and is soluble in most organic solvents but reacts violently with water. The substance exhibits flammable properties and can form explosive vapor-air mixtures under certain conditions.

What is dichloro(dimethyl)silane used for?

Dichloro(dimethyl)silane is primarily used as an intermediate in the production of silicone polymers and resins. It serves as a key building block for manufacturing dimethylsilicone compounds and cross-linking agents. The substance is also employed in surface treatment applications, particularly for creating hydrophobic coatings and improving adhesion properties. Additionally, it finds use in the semiconductor industry for specialized chemical vapor deposition processes and in the production of specialty silicone materials.

How to handle dichloro(dimethyl)silane safely?

Dichloro(dimethyl)silane requires careful handling using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid contact with skin and eyes, and ensure no ignition sources are present due to its flammable nature. Use non-sparking tools and equipment, and always have appropriate fire extinguishing media readily available during handling operations.

How to store dichloro(dimethyl)silane correctly?

Dichloro(dimethyl)silane must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and ignition points. The storage area should be protected from moisture and water to prevent hydrolysis reactions. Keep containers away from incompatible materials such as strong bases, alcohols, and oxidizing agents. Store in original containers with proper labeling and ensure compliance with local flammable liquid storage regulations including appropriate fire suppression systems.

What to do in case of contact with dichloro(dimethyl)silane?

Dichloro(dimethyl)silane contact requires immediate first aid measures depending on the exposure route. For skin contact, immediately remove contaminated clothing and flush affected areas with plenty of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water and seek medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. For ingestion, do not induce vomiting and seek immediate medical attention while providing supportive care.

How to dispose of dichloro(dimethyl)silane properly?

Dichloro(dimethyl)silane disposal must comply with local and national hazardous waste regulations due to its flammable and corrosive properties. The substance should be collected in appropriate containers and delivered to licensed hazardous waste disposal facilities. Small quantities may be carefully hydrolyzed under controlled conditions by qualified personnel, neutralizing the resulting hydrogen chloride. Never dispose of this chemical through regular drainage systems or municipal waste streams, and always consult local environmental authorities for specific disposal requirements.

How to transport dichloro(dimethyl)silane?

Dichloro(dimethyl)silane is classified under ADR Class 3 (flammable liquids), Packing Group II for transportation purposes. The substance must be packaged in UN-approved containers with appropriate labeling including flammable liquid hazard labels. Transport vehicles must comply with ADR regulations for Class 3 substances, including proper ventilation, fire extinguishing equipment, and driver certification. Shipping documentation must include proper shipping names, hazard classes, and emergency response information according to dangerous goods transportation regulations.

Is dichloro(dimethyl)silane subject to specific regulations?

Dichloro(dimethyl)silane is subject to various chemical regulations including REACH registration requirements in the European Union and CLP classification and labeling obligations. The substance is not currently listed as a Substance of Very High Concern (SVHC). It must be handled according to occupational health and safety regulations due to its flammable and irritating properties. Users must comply with local chemical safety legislation, maintain safety data sheets, and implement appropriate risk management measures in industrial applications.

Where to buy dichloro(dimethyl)silane in Europe?

Dichloro(dimethyl)silane is available through OYSI, a European distributor specializing in technical chemicals and industrial raw materials. OYSI provides reliable supply chains across European markets with proper regulatory compliance and technical support. As a specialized chemical distributor, OYSI ensures product quality, appropriate packaging, and complete documentation including safety data sheets and certificates of analysis. Contact OYSI directly for availability, specifications, and delivery options tailored to your specific industrial requirements and geographic location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.