Propanal

C3H6O

propanal

CAS123-38-6
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
123-38-6
EC Number
204-623-0
UN Number
1275
Index Number
605-018-00-8
PubChem CID
527

Physical-chemical properties

Molecular Formula
C3H6O
Molar Mass
58.08 g/mol
IUPAC Name
propanal

Chemical Identifiers

InChI
InChI=1S/C3H6O/c1-2-3-4/h3H,2H2,1H3
InChI Key
NBBJYMSMWIIQGU-UHFFFAOYSA-N

Overview

Propanal (CAS 123-38-6) is an aliphatic aldehyde with a characteristic pungent odor and high reactivity due to its carbonyl group. This three-carbon aldehyde, also known by its IUPAC name propanal, represents one of the simplest saturated aldehydes in organic chemistry. With the molecular formula C3H6O and a molar mass of 58.08 g/mol, propanal exists as a colorless liquid under standard conditions. The compound belongs to the aldehyde family, characterized by the presence of a formyl group (-CHO) that imparts distinctive chemical properties and reactivity patterns. From a safety perspective, propanal requires careful handling due to its classification as a flammable liquid (Category 2) and its potential to cause skin and eye irritation. The substance carries the "Danger" signal word and displays GHS02 and GHS07 pictograms, indicating fire hazard and health concerns respectively. Its ADR Class 3 classification confirms its status as a dangerous good for transportation purposes. The compound may cause specific target organ toxicity following single exposure, particularly affecting the respiratory system. In industrial applications, propanal serves as an important intermediate in organic synthesis, particularly in the production of various chemical compounds including plastics, pharmaceuticals, and agricultural chemicals. The compound finds significant use in the manufacture of propionic acid and its derivatives, as well as in the synthesis of various esters and alcohols. Unlike more complex organosilicon compounds such as trichloro(methyl)silane, propanal offers simpler handling requirements while maintaining high synthetic utility. OYSI provides technical-grade propanal to support diverse industrial applications across Europe, ensuring reliable supply chain management for chemical manufacturing processes.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1275
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NamePropionaldehyd
Marine PollutantNo

Frequently Asked Questions

What is propanal?

Propanal is an organic aldehyde with the chemical formula C3H6O and CAS number 123-38-6. It is the simplest three-carbon aldehyde, featuring a carbonyl group (C=O) at the terminal position. With a molecular weight of 58.08 g/mol, propanal is classified as a flammable liquid and irritant substance, requiring careful handling due to its hazardous properties including flammability and potential for skin and eye irritation.

What are the physicochemical properties of propanal?

Propanal is a colorless liquid with a characteristic pungent, fruity odor at room temperature. It has a boiling point of 48°C and is highly volatile due to its low molecular weight. The substance is miscible with water and most organic solvents including ethanol and ether. Propanal readily undergoes typical aldehyde reactions such as oxidation and condensation, and its high volatility contributes to its flammable nature.

What is propanal used for?

Propanal serves primarily as an intermediate in organic synthesis and chemical manufacturing. It is used in the production of propionic acid, propanol, and various pharmaceutical compounds. The substance finds applications in flavor and fragrance industries due to its characteristic odor profile. Additionally, propanal is utilized in the manufacture of plastics, resins, and as a building block for more complex organic molecules in fine chemical synthesis.

How to handle propanal safely?

Propanal requires strict safety protocols due to its flammable and irritant properties. Personnel must wear appropriate PPE including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent vapor accumulation. All ignition sources must be eliminated from the work area. Emergency eyewash stations and safety showers should be readily accessible when handling this substance.

How to store propanal correctly?

Propanal must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. The substance should be kept in tightly sealed containers made of compatible materials, preferably in a flammable liquids storage cabinet. Storage temperatures should remain below 25°C to minimize vapor generation. Keep away from strong oxidizing agents and bases, as these materials are incompatible and may cause dangerous reactions.

What to do in case of contact with propanal?

Propanal exposure requires immediate action due to its irritant properties. For skin contact, remove contaminated clothing and wash the affected area with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with water for 15-20 minutes and remove contact lenses if present. If inhaled, move the person to fresh air immediately. Seek medical attention if irritation persists or if large amounts were involved.

How to dispose of propanal properly?

Propanal disposal must comply with local, national, and EU waste regulations as a hazardous chemical waste. The substance cannot be disposed of down drains or with regular waste due to its flammable and irritant properties. Arrange disposal through licensed hazardous waste contractors who can handle flammable liquids appropriately. Small quantities may be neutralized or treated according to approved laboratory waste procedures before disposal through authorized channels.

How to transport propanal?

Propanal is classified under ADR as Class 3 (Flammable Liquids), Packing Group II, indicating moderate danger level for transport. Packages must bear appropriate hazard labels including flammable liquid warnings and limited quantity markings where applicable. Transport vehicles require proper placarding and emergency equipment. Drivers must hold valid ADR certification for dangerous goods transport, and shipping documentation must include proper shipping names and hazard information.

Is propanal subject to particular regulations?

Propanal is regulated under EU CLP Regulation with mandatory hazard classification as Flam. Liq. 2, STOT SE 3, Skin Irrit. 2, and Eye Irrit. 2, requiring danger signal word and GHS02/GHS07 pictograms. Under REACH regulation, suppliers must provide safety data sheets and ensure proper registration. The substance is not currently listed as SVHC (Substance of Very High Concern), but users must comply with occupational exposure limits and workplace safety requirements.

Where to buy propanal in Europe?

Propanal is available through OYSI, a specialized European distributor of technical chemicals serving industrial and professional customers. OYSI ensures regulatory compliance including proper CLP labeling, safety data sheets, and transport documentation. As an established chemical distributor, OYSI provides reliable supply chains across Europe with appropriate packaging and handling for this flammable substance. Contact OYSI directly for availability, specifications, and technical support for your propanal requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.