Silicon

Si

silicon

CAS7440-21-3

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Identification

CAS Number
7440-21-3
EC Number
231-130-8
UN Number
1346
PubChem CID
5461123

Physical-chemical properties

Molecular Formula
Si
Molar Mass
28.09 g/mol
IUPAC Name
silicon

Chemical Identifiers

InChI
InChI=1S/Si
InChI Key
XUIMIQQOPSSXEZ-UHFFFAOYSA-N

Overview

Silicon (CAS 7440-21-3) is a metalloid chemical element with semiconducting properties and exceptional chemical stability in crystalline form. Silicon stands as one of the most abundant elements in Earth's crust and serves as a cornerstone material in modern technology and industrial applications. This tetravalent metalloid exhibits unique properties that bridge the gap between metals and non-metals, making it invaluable across diverse sectors from electronics to construction materials. In its pure crystalline form, silicon displays a diamond-like structure that contributes to its remarkable mechanical strength and thermal stability. The element's versatility stems from its ability to form strong covalent bonds with oxygen, carbon, and other elements, creating an extensive range of silicon-based compounds. Unlike reactive substances such as 3,7-dinitroso-1,3,5,7-tetrazabicyclo[3.3.1]nonane, silicon in its elemental form remains chemically inert under normal conditions, though it can react vigorously when finely divided and exposed to oxidizing agents. This characteristic places it under ADR Class 4.1 classification when in powder form due to potential flammability risks. Silicon's primary industrial applications include semiconductor manufacturing for electronic devices, where ultra-pure silicon wafers form the foundation of computer chips and solar cells. The construction industry extensively utilizes silicon in silicone polymers and sealants, while the metallurgical sector employs it as an alloying agent to enhance steel and aluminum properties. Additionally, silicon serves as a reducing agent in various chemical processes. As a leading European distributor of technical chemicals, OYSI maintains reliable supplies of silicon in various grades and specifications to meet the demanding requirements of industrial customers across multiple sectors.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1346
ADR Class4.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameSilicium-Pulver, amorph
Marine PollutantNo

Frequently Asked Questions

What is silicon?

Silicon is a chemical element with the symbol Si and atomic number 14, classified as a metalloid or semi-metal. It is the second most abundant element in Earth's crust after oxygen and forms the basis of silicate minerals. Silicon appears as a dark gray, crystalline solid with metallic luster in its pure form. With a molecular weight of 28.085 g/mol, silicon is essential in semiconductor technology and serves as the foundation for modern electronics and computer chips.

What are the physicochemical properties of silicon?

Silicon is a hard, brittle crystalline solid with a dark gray to black metallic appearance at room temperature. It has a high melting point of 1414°C and boiling point of 3265°C, making it thermally stable. Silicon is insoluble in water and most acids but dissolves in alkali solutions and hydrofluoric acid. It exhibits semiconductor properties, with electrical conductivity between metals and insulators. Silicon is odorless and chemically relatively inert under normal conditions.

What is silicon used for?

Silicon is primarily used in semiconductor manufacturing for computer chips, solar panels, and electronic devices. It serves as a key component in the production of silicones, which are used in sealants, adhesives, and rubber products. Silicon is essential in metallurgy as an alloying agent to improve steel and aluminum properties. Additionally, it finds applications in glass manufacturing, ceramics, and as a deoxidizer in steel production, making it crucial for numerous industrial processes.

How to handle silicon safely?

Silicon requires standard industrial hygiene practices during handling to prevent dust inhalation and skin irritation. Wear appropriate personal protective equipment including safety glasses, dust masks, and protective clothing when working with silicon powder. Ensure adequate ventilation in work areas to minimize dust exposure. Use proper lifting techniques for heavy silicon ingots and avoid generating excessive dust during processing. Implement good housekeeping practices to prevent dust accumulation in work areas.

How to store silicon correctly?

Silicon should be stored in a dry, well-ventilated area away from strong oxidizing agents and alkali materials. Keep containers tightly closed to prevent moisture absorption and contamination. Store silicon away from acids like hydrofluoric acid and strong bases that can react with it. Maintain storage temperatures within normal ambient ranges and protect from direct sunlight. Ensure storage areas are equipped with appropriate fire safety measures, as silicon powder can present combustible dust hazards.

What to do in case of contact with silicon?

Silicon contact typically causes minimal immediate health effects, but proper first aid measures should be followed. For skin contact, wash the affected area thoroughly with soap and water to remove particles. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention if irritation persists. If silicon dust is inhaled, move to fresh air immediately. For ingestion, rinse mouth with water and seek medical advice if necessary.

How to dispose of silicon properly?

Silicon disposal should comply with local environmental regulations and waste management guidelines. Pure silicon can often be recycled through specialized metal recovery facilities due to its value in electronics manufacturing. Contaminated silicon waste must be classified and disposed of according to the nature of contaminants present. Consult local waste management authorities for specific disposal requirements. Avoid disposing of silicon in regular municipal waste streams and consider recovery options when economically viable.

How to transport silicon?

Silicon is classified under ADR Class 4.1 (flammable solids) Packing Group III for transportation purposes. This classification applies primarily to silicon powder forms that may present combustible dust hazards. Proper packaging must meet UN specifications for Class 4.1 materials, typically using appropriate containers that prevent dust release. Transport vehicles should carry required safety equipment and documentation. Drivers must hold ADR certification for Class 4.1 materials when transporting commercial quantities.

Is silicon subject to specific regulations?

Silicon is subject to standard REACH registration requirements in Europe as a chemical substance manufactured or imported above one tonne per year. It is not classified as a Substance of Very High Concern (SVHC) under REACH regulation. Silicon falls under general industrial chemical regulations and workplace safety standards. Specific applications in electronics may be subject to additional quality and purity standards. Companies handling silicon must comply with occupational health regulations regarding dust exposure limits.

Where to buy silicon in Europe?

Silicon is available through OYSI, a leading European distributor of technical chemicals serving industrial customers across the continent. OYSI offers various grades of silicon suitable for different applications, from semiconductor-grade to metallurgical-grade materials. European customers can access silicon through established chemical distribution networks and specialized metal suppliers. Industrial users should specify purity requirements and particle size specifications when requesting quotes. Contact OYSI directly for availability, technical specifications, and pricing information for your specific silicon requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.