Tribromoarsane

AsBr3

tribromoarsane

CAS7784-33-0

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Identification

CAS Number
7784-33-0
EC Number
232-057-4
UN Number
1555
Index Number
033-002-00-5
PubChem CID
24569

Physical-chemical properties

Molecular Formula
AsBr3
Molar Mass
314.63 g/mol
IUPAC Name
tribromoarsane

Chemical Identifiers

InChI
InChI=1S/AsBr3/c2-1(3)4
InChI Key
JMBNQWNFNACVCB-UHFFFAOYSA-N

Overview

Tribromoarsane (CAS 7784-33-0) is an inorganic arsenic compound with three bromine atoms bonded to a central arsenic atom, forming a highly reactive halide. This arsenic tribromide represents a significant chemical intermediate in organoarsenic synthesis and specialized industrial applications. The compound exhibits the characteristic properties of arsenic halides, displaying high reactivity toward moisture and organic substrates. With its molecular formula AsBr3 and molecular weight of 314.63 g/mol, tribromoarsane serves as a versatile building block in chemical manufacturing processes requiring precise arsenic incorporation. The substance falls under ADR class 6.1, indicating its toxic nature and requiring appropriate handling protocols during transportation and storage. Like other arsenic compounds, tribromoarsane demands strict safety measures including proper ventilation, personal protective equipment, and secure containment systems. Its reactivity with water produces hydrobromic acid and arsenic compounds, necessitating dry storage conditions and inert atmosphere handling when required. Primary industrial applications include semiconductor manufacturing processes, where tribromoarsane functions as a precursor for specialized arsenic-containing materials. The compound also finds use in organic synthesis as a brominating agent and in the production of organoarsenic compounds for research applications. Unlike simpler aromatic compounds such as 4-nitroaniline or 4-nitrophenol used in dye chemistry, tribromoarsane serves more specialized roles in advanced materials science and electronic applications. OYSI maintains technical-grade tribromoarsane inventory to support European industrial customers requiring this specialized arsenic compound, backed by comprehensive documentation and regulatory compliance support.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1555
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameArsenbromid, fest
Marine PollutantNo

Frequently Asked Questions

What is tribromoarsane?

Tribromoarsane is an inorganic arsenic compound with the chemical formula AsBr3 and CAS number 7784-33-0. This substance has a molecular weight of 314.63 g/mol and belongs to the family of arsenic halides. Tribromoarsane is formed by the combination of arsenic with three bromine atoms, creating a covalent compound that exhibits typical properties of arsenic-bromine complexes used in specialized chemical applications.

What are the physicochemical properties of tribromoarsane?

Tribromoarsane appears as a crystalline solid at room temperature with a characteristic yellowish to orange color. The compound is sensitive to moisture and can decompose in the presence of water, releasing hydrogen bromide vapors. It has limited solubility in polar solvents but dissolves readily in organic solvents such as carbon disulfide and benzene. The compound exhibits a pungent, irritating odor typical of bromine-containing substances.

What is tribromoarsane used for?

Tribromoarsane serves primarily as a chemical intermediate in organic synthesis and semiconductor manufacturing processes. It is utilized in the production of organoarsenic compounds and as a brominating agent in specialized chemical reactions. The compound finds applications in research laboratories for analytical chemistry purposes and in the electronics industry for the preparation of high-purity arsenic compounds used in semiconductor doping processes.

How to handle tribromoarsane safely?

Tribromoarsane requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in a well-ventilated area or under a fume hood to prevent inhalation exposure. Avoid contact with skin, eyes, and clothing, as the compound can cause irritation and potential health hazards. Always use proper laboratory techniques and ensure emergency shower and eyewash stations are readily accessible.

How to store tribromoarsane correctly?

Tribromoarsane should be stored in a cool, dry, well-ventilated area away from moisture and incompatible materials. Keep containers tightly sealed and protected from light and heat sources. The compound should be stored separately from strong oxidizing agents, alkalis, and water-reactive substances. Use appropriate secondary containment and ensure storage areas are equipped with adequate ventilation systems to prevent vapor accumulation.

What to do in case of contact with tribromoarsane?

Immediate action is required upon contact with tribromoarsane. For skin contact, remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. Seek immediate medical attention in all cases and provide safety data sheet information to medical personnel.

How to dispose of tribromoarsane appropriately?

Tribromoarsane disposal must comply with local, national, and international hazardous waste regulations due to its arsenic content. The compound should never be disposed of in regular waste streams or sewage systems. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small laboratory quantities may require neutralization or chemical treatment before disposal, following institutional waste management protocols and regulatory guidelines.

How to transport tribromoarsane?

Tribromoarsane is classified under ADR regulations as Class 6.1 (toxic substances) with Packing Group II, indicating moderate toxicity levels. Transportation requires appropriate UN-specification packaging and proper hazardous material documentation. Vehicles must display appropriate hazard placards and drivers need hazardous materials training certification. Shipments should include emergency response information and comply with international dangerous goods transportation regulations for road, rail, and air transport.

Is tribromoarsane subject to specific regulations?

Tribromoarsane falls under various chemical regulations including REACH registration requirements in Europe due to its commercial use. The compound is subject to workplace safety regulations and occupational exposure limits due to its arsenic content. It is not currently listed as a Substance of Very High Concern (SVHC) under REACH, but users must comply with CLP classification and labeling requirements and maintain appropriate safety documentation.

Where to buy tribromoarsane in Europe?

Tribromoarsane is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers across Europe. OYSI provides high-quality tribromoarsane with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures reliable supply chain management and technical support for customers requiring this specialized arsenic compound for their applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.