Tetrabromomethane

CBr4

tetrabromomethane

CAS558-13-4

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Identification

CAS Number
558-13-4
EC Number
209-189-6
UN Number
2516
PubChem CID
11205

Physical-chemical properties

Molecular Formula
CBr4
Molar Mass
331.63 g/mol
IUPAC Name
tetrabromomethane

Chemical Identifiers

InChI
InChI=1S/CBr4/c2-1(3,4)5
InChI Key
HJUGFYREWKUQJT-UHFFFAOYSA-N

Overview

Tetrabromomethane (CAS 558-13-4) is a halogenated organic compound with high density and excellent solvent properties for specialized industrial applications. This brominated methane derivative, with the molecular formula CBr4, represents one of the most heavily halogenated single-carbon compounds available for technical applications. With a molecular weight of 331.63 g/mol, tetrabromomethane exhibits unique physical and chemical characteristics that distinguish it from other halogenated solvents. The compound's structure, featuring four bromine atoms bonded to a central carbon atom, results in exceptional density and specific solubility properties that make it valuable in specialized industrial processes. As a member of the tetrahalomethane family, tetrabromomethane shares certain characteristics with related halogenated compounds while offering distinct advantages in specific applications. Unlike lighter halogenated solvents, its high bromine content provides superior density separation capabilities. The compound's classification under ADR Class 6.1 requires appropriate handling procedures and storage conditions to ensure safe industrial use. Tetrabromomethane finds primary applications in density separation processes, particularly in mineral processing and geological sample preparation where its high specific gravity enables effective separation of materials with different densities. The compound also serves as a specialized solvent in certain analytical procedures and as an intermediate in organic synthesis reactions. Additionally, it functions as a component in some fire suppression systems, though this application has become more restricted due to environmental considerations. Industrial users often compare tetrabromomethane with other halogenated compounds such as 4-nitroaniline derivatives when selecting appropriate solvents for specific separation or analytical procedures, as the choice depends on the particular density and solubility requirements of each application. OYSI maintains reliable supplies of high-purity tetrabromomethane to support European industrial operations requiring this specialized halogenated compound.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2516
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameTetrabromkohlenstoff, fest
Marine PollutantNo

Frequently Asked Questions

What is tetrabromomethane?

Tetrabromomethane is a halogenated organic compound with the chemical formula CBr4, consisting of a carbon atom bonded to four bromine atoms. This colorless crystalline solid has a molecular weight of 331.63 g/mol and is also known as carbon tetrabromide. It belongs to the family of tetrahalomethanes and serves as an important chemical intermediate in various industrial processes.

What are the physicochemical properties of tetrabromomethane?

Tetrabromomethane is a colorless to pale yellow crystalline solid at room temperature with a characteristic sweet odor. It has a high density due to the presence of four bromine atoms and exhibits low solubility in water but dissolves well in organic solvents like chloroform and benzene. The compound sublimes readily and has a relatively low melting point around 90°C.

What is tetrabromomethane used for?

Tetrabromomethane is primarily used as a chemical intermediate in organic synthesis and as a source of bromine in various chemical reactions. It serves as a reagent in laboratory applications, particularly in analytical chemistry and research. The compound is also utilized in specialized industrial processes where controlled bromine release is required, though its applications are more limited compared to other halogenated compounds.

How to handle tetrabromomethane safely?

Tetrabromomethane should be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation of vapors. Although not classified under standard GHS pictograms, the compound requires careful handling due to its bromine content and potential toxicity, following standard laboratory safety protocols.

How to store tetrabromomethane correctly?

Tetrabromomethane should be stored in a cool, dry place away from direct sunlight in tightly sealed containers to prevent sublimation and contamination. The storage area must be well-ventilated and the compound should be kept away from incompatible materials such as strong bases and reducing agents. Temperature control is important to maintain the solid state and prevent vapor formation.

What to do in case of contact with tetrabromomethane?

In case of skin contact with tetrabromomethane, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention if respiratory irritation occurs. For eye contact, flush with clean water for at least 15 minutes and consult a physician if irritation persists.

How to dispose of tetrabromomethane appropriately?

Tetrabromomethane must be disposed of as hazardous chemical waste through authorized waste management companies specializing in halogenated compounds. The material cannot be disposed of in regular waste streams due to its bromine content and potential environmental impact. Collection, transport, and treatment must comply with local and European waste regulations including proper documentation and manifest requirements.

How to transport tetrabromomethane?

Tetrabromomethane is classified under ADR as Class 6.1 (Toxic substances), Packing Group III, requiring specific packaging and labeling for transport. Shipments must use UN-approved packaging with appropriate hazard labels and documentation. Transport vehicles must comply with ADR regulations for toxic substances, including proper placarding, driver certification, and emergency response information during transit across European borders.

Is tetrabromomethane subject to particular regulations?

Tetrabromomethane is subject to standard European chemical regulations under REACH and CLP, requiring registration and classification data from suppliers. While not currently listed as an SVHC (Substance of Very High Concern), it must comply with standard chemical safety requirements including proper labeling, safety data sheets, and exposure assessments for professional use within the European market.

Where to buy tetrabromomethane in Europe?

Tetrabromomethane is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers across the continent. OYSI provides reliable supply chains, proper documentation, and regulatory compliance for professional users requiring this specialized brominated compound. Contact OYSI directly for availability, specifications, and delivery options to your location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.