Sulfamic acid
H3NO3S
sulfamic acid
Consulting for Sulfamic acid
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Identification
- CAS Number
- 5329-14-6
- EC Number
- 226-218-8
- UN Number
- 2967
- Index Number
- 016-026-00-0
- PubChem CID
- 5987
Physical-chemical properties
- Molecular Formula
- H3NO3S
- Molar Mass
- 97.10 g/mol
- IUPAC Name
- sulfamic acid
Chemical Identifiers
- InChI
- InChI=1S/H3NO3S/c1-5(2,3)4/h(H3,1,2,3,4)
- InChI Key
- IIACRCGMVDHOTQ-UHFFFAOYSA-N
Overview
Sulfamic acid (CAS 5329-14-6) is a crystalline inorganic acid with strong acidic properties and excellent descaling capabilities. This versatile chemical compound, with the molecular formula H3NO3S and molecular weight of 97.1 g/mol, serves as an essential industrial chemical across multiple sectors. Also known by its IUPAC designation sulfamic acid, this white crystalline solid exhibits unique properties that distinguish it from other mineral acids. Unlike traditional acids such as hydrochloric or sulfuric acid, sulfamic acid offers controlled reactivity while maintaining excellent solubility in water. The compound demonstrates notable safety characteristics with a GHS07 pictogram and "Warning" signal word, classified primarily for skin and eye irritation (Skin Irrit. 2; Eye Irrit. 2) and chronic aquatic toxicity (Aquatic Chronic 3). Its ADR Class 8 designation reflects its corrosive nature, requiring appropriate handling protocols and protective equipment during transport and use. These safety properties make it more manageable than stronger mineral acids while retaining effective performance. Sulfamic acid finds extensive application in industrial cleaning formulations, particularly for descaling equipment in power plants, boilers, and heat exchangers. The chemical industry utilizes it as an intermediate in synthesis processes and as a catalyst in certain reactions. Additionally, it serves in electroplating applications for surface preparation and metal finishing operations. While structurally different from organic acids like nonanoic acid or specialty chemicals such as tetrachlorosilane, sulfamic acid complements various industrial chemical portfolios. OYSI provides reliable access to high-quality sulfamic acid for European industrial customers, ensuring consistent supply for critical manufacturing and maintenance operations.
Safety & Classification
Skin Irrit. 2; Eye Irrit. 2; Aquatic Chronic 3
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2967 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Sulfaminsäure |
| Marine Pollutant | No |
Frequently Asked Questions
What is sulfamic acid?
Sulfamic acid is an inorganic compound with the molecular formula H3NO3S and a molecular weight of 97.1 g/mol. It appears as white, odorless crystals that are highly soluble in water. This non-volatile acid is stable under normal conditions and serves as both an acid and a source of nitrogen. Its unique chemical structure makes it particularly useful in various industrial applications where controlled acidic conditions are required.
What are the physicochemical properties of sulfamic acid?
Sulfamic acid exists as white crystalline powder or crystals at room temperature with no characteristic odor. It demonstrates excellent water solubility, making it easy to prepare aqueous solutions of various concentrations. The compound is non-volatile and thermally stable under normal storage conditions. It exhibits strong acidic properties while remaining relatively safe to handle compared to other mineral acids, making it suitable for numerous industrial processes.
What is sulfamic acid used for?
Sulfamic acid serves multiple industrial purposes, primarily as a descaling agent for removing calcium and lime deposits from equipment, boilers, and heat exchangers. It functions as a cleaning agent in metal treatment processes and acts as a catalyst in various chemical syntheses. Additionally, it finds applications in electroplating, herbicide formulations, and as a stabilizing agent in chlorine-based disinfectants, making it valuable across diverse industrial sectors.
How to handle sulfamic acid safely?
Sulfamic acid requires careful handling due to its skin and eye irritation properties (Skin Irrit. 2; Eye Irrit. 2). Wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation in work areas and avoid generating dust. Handle containers carefully to prevent spillage, and always add the acid to water, never the reverse, when preparing solutions to prevent violent reactions.
How to store sulfamic acid correctly?
Sulfamic acid should be stored in a cool, dry, well-ventilated area away from incompatible materials such as strong bases, oxidizing agents, and metals. Keep containers tightly sealed to prevent moisture absorption and contamination. Store in original labeled containers made of compatible materials. Maintain storage temperatures within recommended ranges and ensure storage areas are equipped with appropriate spill containment measures and emergency equipment.
What to do in case of contact with sulfamic acid?
Immediate first aid is essential following sulfamic acid contact. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek medical attention if irritation persists or if large amounts have been ingested.
How to dispose of sulfamic acid properly?
Sulfamic acid disposal must comply with local environmental regulations and waste management guidelines. Small quantities can often be neutralized carefully with appropriate bases under controlled conditions before disposal. Larger quantities should be collected as hazardous chemical waste and disposed of through licensed waste management facilities. Never dispose of sulfamic acid through regular drainage systems or municipal waste streams without proper treatment and authorization.
How to transport sulfamic acid?
Sulfamic acid is classified under ADR Class 8 (corrosive substances), Group III, requiring specific transport regulations compliance. Use appropriate UN-approved packaging designed for corrosive materials and ensure proper labeling with hazard identification. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers require hazardous materials training certification, and shipments must follow designated routing restrictions where applicable.
Is sulfamic acid subject to specific regulations?
Sulfamic acid is regulated under various European chemical legislation frameworks including REACH and CLP regulations. It is not classified as a Substance of Very High Concern (SVHC), simplifying its regulatory status. However, users must comply with standard chemical safety requirements including proper labeling, safety data sheet provision, and workplace exposure controls. Import, storage, and use must follow national chemical safety regulations in respective European countries.
Where to buy sulfamic acid in Europe?
Sulfamic acid is available through OYSI, a trusted European chemical distributor specializing in technical-grade chemicals for industrial applications. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. As an established distributor, OYSI ensures product quality and maintains appropriate logistics capabilities for safe delivery of corrosive materials like sulfamic acid to industrial customers throughout European markets.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.