Sulfamic acid
H3NO3S
sulfamic acid
Consulting for Sulfamic acid
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Identification
- CAS Number
- 5329-14-6
- EC Number
- 226-218-8
- UN Number
- 2967
- Index Number
- 016-026-00-0
- PubChem CID
- 5987
Physical-chemical properties
- Molecular Formula
- H3NO3S
- Molar Mass
- 97.10 g/mol
- IUPAC Name
- sulfamic acid
Chemical Identifiers
- InChI
- InChI=1S/H3NO3S/c1-5(2,3)4/h(H3,1,2,3,4)
- InChI Key
- IIACRCGMVDHOTQ-UHFFFAOYSA-N
Overview
Sulfamic acid (CAS 5329-14-6) is a crystalline inorganic acid with strong descaling properties and excellent solubility in water. This versatile chemical compound, with the molecular formula H3NO3S and molecular weight of 97.1 g/mol, serves as an essential industrial cleaning agent and chemical intermediate. Unlike stronger mineral acids, sulfamic acid offers controlled reactivity that makes it particularly valuable for applications requiring precise pH adjustment and selective chemical reactions. The compound appears as white, odorless crystals that dissolve readily in water to form a stable acidic solution. From a safety perspective, sulfamic acid is classified under GHS pictogram GHS07 with a "Warning" signal word, indicating moderate hazard levels. The substance can cause skin and eye irritation (Skin Irrit. 2; Eye Irrit. 2) and presents long-term aquatic toxicity concerns (Aquatic Chronic 3). Its ADR classification as Class 8 identifies it as a corrosive material requiring appropriate handling protocols during transportation and storage. Industrial applications of sulfamic acid span multiple sectors, with prominent use as a descaling agent for boilers, heat exchangers, and cooling systems where its non-volatile nature provides advantages over hydrochloric acid. The compound also functions as a catalyst in esterification reactions and serves as a precursor for sweetener production. In textile processing, it acts as a dye bath additive, while in electroplating operations, it helps maintain optimal bath conditions. Interestingly, while substances like nonanoic acid and decanoic acid find applications in different industrial cleaning formulations, sulfamic acid's unique properties make it irreplaceable for specific descaling applications. OYSI provides technical-grade sulfamic acid to European industrial customers, supporting diverse manufacturing and maintenance operations across multiple industries.
Safety & Classification
Skin Irrit. 2; Eye Irrit. 2; Aquatic Chronic 3
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2967 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Sulfaminsäure |
| Marine Pollutant | No |
Frequently Asked Questions
What is sulfamic acid?
Sulfamic acid is a white crystalline solid chemical compound with the molecular formula H3NO3S and CAS number 5329-14-6. It has a molecular weight of 97.1 g/mol and belongs to the family of amino acids containing sulfur. This inorganic acid is highly soluble in water and exhibits strong acidic properties, making it valuable in various industrial applications requiring controlled acidic conditions.
What are the physicochemical properties of sulfamic acid?
Sulfamic acid appears as white crystalline crystals or powder at room temperature. It is highly soluble in water, forming acidic solutions, and has a molecular weight of 97.1 g/mol. The compound is stable under normal conditions but decomposes at elevated temperatures. It exhibits strong acidic properties with good thermal stability, making it suitable for various industrial processes requiring controlled acidity.
What is sulfamic acid used for?
Sulfamic acid serves primarily as a descaling and cleaning agent in industrial applications. It is widely used for removing scale deposits from boilers, heat exchangers, and cooling systems due to its effective chelating properties. Additionally, it functions as a catalyst in various chemical synthesis processes, a stabilizer in certain formulations, and finds applications in metal cleaning and surface treatment industries.
How to handle sulfamic acid safely?
Sulfamic acid requires careful handling due to its skin and eye irritation potential (Skin Irrit. 2, Eye Irrit. 2). Essential protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas to avoid dust inhalation, and ensure eyewash stations and safety showers are accessible. The substance carries a Warning signal word and GHS07 pictogram, indicating moderate hazard level.
How to store sulfamic acid correctly?
Sulfamic acid should be stored in a cool, dry place away from moisture and incompatible materials. Keep containers tightly closed in original packaging to prevent contamination and moisture absorption. Store away from strong bases and oxidizing agents to avoid unwanted reactions. Ensure adequate ventilation in storage areas and maintain temperatures within recommended ranges to preserve product stability and quality.
What to do in case of contact with sulfamic acid?
Sulfamic acid contact requires immediate first aid measures due to its irritating properties. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. For eye contact, flush immediately with water for 15-20 minutes and seek medical attention. If inhaled, move to fresh air immediately. Always consult safety data sheet for complete emergency procedures.
How to dispose of sulfamic acid appropriately?
Sulfamic acid disposal must comply with local and European waste regulations. The substance should be treated as chemical waste and disposed of through licensed waste management companies. Never discharge into sewers or water bodies due to its Aquatic Chronic 3 classification. Neutralization may be possible under controlled conditions before disposal, but always consult local authorities and waste management specialists for proper procedures.
How to transport sulfamic acid?
Sulfamic acid is classified as ADR Class 8 (corrosive substances), Packing Group III for transport purposes. This classification requires specific packaging, labeling, and documentation for road transport within Europe. Packages must bear appropriate hazard labels and comply with ADR regulations. Transportation should be handled by certified carriers familiar with dangerous goods requirements to ensure safe delivery.
Is sulfamic acid subject to specific regulations?
Sulfamic acid is subject to standard European chemical regulations including REACH and CLP requirements. It is not classified as a Substance of Very High Concern (SVHC). The substance must be properly classified and labeled according to CLP regulation, displaying Warning signal word and GHS07 pictogram. Standard industrial chemical handling and workplace safety regulations apply for professional use.
Where to buy sulfamic acid in Europe?
Sulfamic acid is available through OYSI, a specialized European distributor of technical chemicals. OYSI supplies high-quality sulfamic acid to industrial customers across Europe, ensuring proper packaging, documentation, and regulatory compliance. As an established chemical distributor, OYSI provides reliable supply chain solutions and technical support for sulfamic acid requirements in various industrial applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.