4-methylbenzenesulfonic acid
C7H8O3S
Consulting for 4-methylbenzenesulfonic acid
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Identification
- CAS Number
- 104-15-4
- EC Number
- 203-180-0
- UN Number
- 2585
- Index Number
- 016-030-00-2
- PubChem CID
- 6101
Physical-chemical properties
- Molecular Formula
- C7H8O3S
- Molar Mass
- 172.20 g/mol
- IUPAC Name
- 4-methylbenzenesulfonic acid
Chemical Identifiers
- InChI
- InChI=1S/C7H8O3S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H,8,9,10)
- InChI Key
- JOXIMZWYDAKGHI-UHFFFAOYSA-N
Overview
4-methylbenzenesulfonic acid (CAS 104-15-4) is an aromatic sulfonic acid with strong acidic properties and excellent water solubility. This organic compound, with molecular formula C7H8O3S and molecular weight 172.2 g/mol, represents a key intermediate in various chemical synthesis processes and industrial applications. As a derivative of benzenesulfonic acid with a methyl substituent at the para position, 4-methylbenzenesulfonic acid exhibits characteristic properties of sulfonic acids including high thermal stability and strong protonic acidity. The compound appears as a white to off-white crystalline solid that readily dissolves in water and polar solvents, making it particularly valuable in aqueous reaction systems. From a safety perspective, this substance requires careful handling due to its classification under GHS07 pictogram with warning signal word. It presents skin and eye irritation hazards (Skin Irrit. 2; Eye Irrit. 2) and specific target organ toxicity (STOT SE 3). Its ADR class 8 classification indicates corrosive properties, necessitating appropriate personal protective equipment and storage conditions to prevent exposure. Industrial applications of 4-methylbenzenesulfonic acid include its use as a catalyst in esterification and polymerization reactions, particularly in the production of alkyd resins and polyester materials. The compound serves as an important building block in pharmaceutical synthesis and acts as a sulfonating agent in organic chemistry. Unlike simpler compounds such as nonanoic acid which primarily functions in different applications, 4-methylbenzenesulfonic acid's aromatic structure provides unique reactivity patterns essential for specialized chemical transformations. OYSI supplies high-quality 4-methylbenzenesulfonic acid to meet diverse industrial requirements across European markets.
Safety & Classification
STOT SE 3; Skin Irrit. 2; Eye Irrit. 2
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2585 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | 4-Methylbenzensulfonsäure, freie Schwefelsäure <= 5 %, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is 4-methylbenzenesulfonic acid?
4-methylbenzenesulfonic acid is an organic sulfonic acid compound with the molecular formula C7H8O3S and CAS number 104-15-4. This aromatic sulfonic acid features a methyl group attached to the benzene ring at the para position relative to the sulfonic acid group. With a molecular weight of 172.2 g/mol, it appears as a white crystalline solid that is highly soluble in water and polar solvents due to its ionic nature.
What are the physicochemical properties of 4-methylbenzenesulfonic acid?
4-methylbenzenesulfonic acid is a white to off-white crystalline solid at room temperature with high water solubility due to its sulfonic acid functional group. The compound is hygroscopic and readily dissolves in polar solvents including alcohols. It exhibits strong acidic properties with a low pKa value, making it a strong organic acid. The substance is stable under normal conditions but should be protected from moisture to prevent caking.
What is 4-methylbenzenesulfonic acid used for?
4-methylbenzenesulfonic acid is primarily used as a catalyst in organic synthesis reactions, particularly in esterification and polymerization processes. It serves as an intermediate in the production of dyes, pharmaceuticals, and specialty chemicals. The compound is also utilized in electroplating applications and as a curing agent for certain resins. Additionally, it finds application in the synthesis of surfactants and as a pH adjustment agent in various industrial processes.
How to handle 4-methylbenzenesulfonic acid safely?
4-methylbenzenesulfonic acid requires careful handling as it can cause skin and eye irritation (GHS07 pictogram). Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing to prevent direct contact. Ensure adequate ventilation in work areas to minimize inhalation exposure. Avoid generating dust and wash hands thoroughly after handling. In case of potential respiratory exposure, use appropriate respiratory protection in poorly ventilated areas.
How to store 4-methylbenzenesulfonic acid correctly?
4-methylbenzenesulfonic acid should be stored in a cool, dry, well-ventilated area away from direct sunlight and moisture sources. Keep containers tightly closed in original packaging to prevent contamination and moisture absorption. Store away from incompatible materials such as strong bases, oxidizing agents, and metals. Maintain storage temperatures below 25°C when possible and ensure proper labeling according to CLP regulation requirements including GHS07 pictogram and warning signal word.
What to do in case of contact with 4-methylbenzenesulfonic acid?
4-methylbenzenesulfonic acid contact requires immediate first aid measures due to its irritating properties. For skin contact, immediately remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes and remove contact lenses if present. If inhaled, move person to fresh air immediately. Seek medical attention if irritation persists or develops after any exposure route.
How to dispose of 4-methylbenzenesulfonic acid appropriately?
4-methylbenzenesulfonic acid disposal must comply with local and national hazardous waste regulations as it is classified as corrosive (ADR Class 8). The substance should never be disposed of down drains or in regular waste streams. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized carefully with appropriate bases under controlled conditions by qualified personnel, but professional disposal is recommended for most situations.
How to transport 4-methylbenzenesulfonic acid?
4-methylbenzenesulfonic acid is classified under ADR Class 8 (corrosive substances), Packing Group III for transportation purposes. This classification requires appropriate packaging, labeling, and documentation for road transport. Containers must meet UN specification requirements and display proper hazard labels. Transport vehicles need appropriate equipment for corrosive materials handling. Drivers require ADR training certification, and transport documents must include proper shipping names and emergency response information.
Is 4-methylbenzenesulfonic acid subject to specific regulations?
4-methylbenzenesulfonic acid is subject to REACH regulation requiring registration for manufacture or import above 1 tonne annually in the EU. The substance must be classified and labeled according to CLP regulation with GHS07 pictogram and warning signal word due to its irritating properties. It is not currently listed as a SVHC (Substance of Very High Concern). Users must comply with ADR transport regulations and maintain safety data sheets for workplace safety compliance.
Where to buy 4-methylbenzenesulfonic acid in Europe?
4-methylbenzenesulfonic acid is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the region. OYSI provides this substance with complete regulatory documentation including safety data sheets and certificates of analysis. As an established chemical distributor, OYSI ensures proper packaging, labeling compliance with European regulations, and reliable supply chains for professional users requiring this specialized organic acid for their industrial applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.