Oxalic acid

C2H2O4

oxalic acid

CAS144-62-7
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
144-62-7
EC Number
205-634-3
UN Number
3261
Index Number
607-006-00-8
PubChem CID
971

Physical-chemical properties

Molecular Formula
C2H2O4
Molar Mass
90.03 g/mol
IUPAC Name
oxalic acid

Chemical Identifiers

InChI
InChI=1S/C2H2O4/c3-1(4)2(5)6/h(H,3,4)(H,5,6)
InChI Key
MUBZPKHOEPUJKR-UHFFFAOYSA-N

Overview

Oxalic acid (CAS 144-62-7) is a dicarboxylic acid with strong reducing properties and excellent chelating capabilities for metal ions. This organic compound, with the molecular formula C2H2O4, represents one of the simplest dicarboxylic acids found naturally in many plants and vegetables. Oxalic acid appears as colorless, crystalline solid that readily dissolves in water, forming strongly acidic solutions. With a molecular weight of 90.03 g/mol and EC number 205-634-3, this versatile chemical compound plays crucial roles across multiple industrial sectors. The substance exhibits notable chemical reactivity, particularly as a reducing agent and metal chelator, making it valuable for various technical applications. However, oxalic acid requires careful handling due to its classification under Acute Tox. 4 with GHS07 pictogram and Warning signal word, indicating potential health hazards upon exposure. Its ADR classification as Class 8 substance reflects its corrosive properties during transport and storage. Key industrial applications include metal cleaning and rust removal, where oxalic acid effectively dissolves iron oxides and other metal deposits. The textile industry utilizes this compound for bleaching and finishing processes, while the leather industry employs it for tanning operations. Unlike more complex chemical intermediates such as benzonitrile or specialized acetate compounds like 2-butoxyethyl acetate, oxalic acid's straightforward molecular structure enables direct application in cleaning formulations and metal treatment processes. The compound also serves essential functions in analytical chemistry as a primary standard for permanganate titrations and in the pharmaceutical industry for various synthesis processes. Its ability to form stable complexes with metal ions makes it particularly valuable in electroplating and metal surface preparation applications. OYSI maintains reliable supplies of technical-grade oxalic acid to support diverse European industrial requirements.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3261
ADR Class8
Packing GroupIII
Tunnel CodeE
Proper Shipping NameOxalsäure, wasserfrei, fest
Marine PollutantNo

Frequently Asked Questions

What is oxalic acid?

Oxalic acid is an organic compound with the chemical formula C2H2O4 and molecular weight of 90.03 g/mol. It is a naturally occurring dicarboxylic acid found in many plants, vegetables, and fruits. This colorless crystalline solid is one of the simplest organic acids and exists primarily as a dihydrate under normal conditions. Oxalic acid is classified as Acute Tox. 4 under CLP regulation, requiring careful handling in industrial and professional applications.

What are the physicochemical properties of oxalic acid?

Oxalic acid is a white, odorless crystalline solid at room temperature with high water solubility. The compound readily forms a dihydrate (C2H2O4·2H2O) under normal atmospheric conditions. It has a relatively low melting point and decomposes upon heating. The acid is highly polar due to its two carboxyl groups, making it soluble in polar solvents like water and alcohols but poorly soluble in non-polar organic solvents.

What is oxalic acid used for?

Oxalic acid is widely used as a cleaning and bleaching agent, particularly for removing rust, stains, and mineral deposits from surfaces. It serves as a reducing agent in photography and textile industries, and as a mordant in dyeing processes. The compound is also utilized in metal polishing, wood restoration, and as a laboratory reagent for analytical chemistry. Industrial applications include leather tanning, paper manufacturing, and as an intermediate in pharmaceutical synthesis.

How to handle oxalic acid safely?

Oxalic acid requires careful handling due to its Acute Tox. 4 classification and GHS07 pictogram warning. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety glasses, and protective clothing. Ensure adequate ventilation when working with the substance. Avoid inhalation of dust or vapors and prevent skin and eye contact. Work in well-ventilated areas or under fume hoods, and have eyewash stations and safety showers readily available in the workplace.

How to store oxalic acid correctly?

Oxalic acid should be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers tightly closed and protected from moisture to prevent caking. Store separately from incompatible materials such as strong bases, oxidizing agents, and metals. Use appropriate secondary containment and ensure storage areas are equipped with spill control materials. Maintain storage temperatures below 25°C and protect from physical damage to containers.

What to do in case of contact with oxalic acid?

In case of skin contact with oxalic acid, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. For eye contact, rinse continuously with clean water and seek immediate medical attention. If inhaled, move the person to fresh air and monitor breathing. If ingested, do not induce vomiting and seek immediate medical assistance. Always consult safety data sheets for specific first aid measures and contact emergency services if severe symptoms occur.

How to dispose of oxalic acid properly?

Oxalic acid disposal must comply with local and national environmental regulations as it is classified as hazardous waste. Small quantities can be neutralized with calcium hydroxide or sodium bicarbonate under controlled conditions before disposal. Larger amounts require professional hazardous waste disposal services. Never discharge directly into sewers, waterways, or soil. Contact licensed waste management companies for proper collection and treatment. Maintain proper documentation of all disposal activities as required by regulations.

How to transport oxalic acid?

Oxalic acid is classified as ADR Class 8, Packing Group III for transportation, indicating it is a corrosive substance with relatively lower danger. Packages must be properly labeled with appropriate hazard markings and UN identification numbers. Use approved packaging materials resistant to corrosion and ensure containers are securely closed and protected from damage during transit. Transport vehicles must carry appropriate emergency equipment and documentation. Follow ADR regulations for loading, segregation, and driver training requirements.

Is oxalic acid subject to specific regulations?

Oxalic acid is regulated under the CLP Regulation with Acute Tox. 4 classification and requires appropriate labeling with GHS07 pictogram and warning signal word. It is not listed as a Substance of Very High Concern (SVHC) under REACH regulation. However, it must comply with standard REACH registration requirements for chemical substances. Users must follow occupational safety regulations, maintain safety data sheets, and implement appropriate risk management measures. Some applications may have additional sector-specific restrictions.

Where to buy oxalic acid in Europe?

Oxalic acid is available throughout Europe from OYSI, a specialized distributor of technical chemicals. OYSI provides high-quality oxalic acid with full regulatory compliance including proper CLP labeling, safety data sheets, and technical documentation. As a European chemical distributor, OYSI ensures reliable supply chains and professional customer support for industrial and professional users. Contact OYSI directly for specific grades, quantities, and delivery options to meet your technical requirements across European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.