Oxalic acid

C2H2O4

oxalic acid

CAS144-62-7
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
144-62-7
EC Number
205-634-3
UN Number
3261
Index Number
607-006-00-8
PubChem CID
971

Physical-chemical properties

Molecular Formula
C2H2O4
Molar Mass
90.03 g/mol
IUPAC Name
oxalic acid

Chemical Identifiers

InChI
InChI=1S/C2H2O4/c3-1(4)2(5)6/h(H,3,4)(H,5,6)
InChI Key
MUBZPKHOEPUJKR-UHFFFAOYSA-N

Overview

Oxalic acid (CAS 144-62-7) is a dicarboxylic acid with strong reducing properties and excellent metal-chelating capabilities. This naturally occurring organic compound, with the molecular formula C2H2O4, represents one of the simplest dicarboxylic acids found in nature. Also known by its IUPAC designation as oxalic acid, this crystalline substance plays a significant role in various industrial applications due to its unique chemical properties. The compound occurs naturally in many plants, including spinach, rhubarb, and other leafy vegetables, where it often forms calcium oxalate crystals. From a safety perspective, oxalic acid carries specific hazard classifications that require careful handling. The substance is classified under Acute Toxicity Category 4, displaying the GHS07 pictogram with a "Warning" signal word. These classifications reflect the compound's potential health impacts, particularly its corrosive nature and toxicity when ingested or improperly handled. The ADR Class 8 designation further emphasizes its corrosive properties during transportation and storage. The industrial applications of oxalic acid are diverse and well-established. In metal processing industries, it serves as an effective rust remover and metal cleaner, leveraging its ability to form stable complexes with metal ions. The textile industry utilizes oxalic acid as a bleaching agent and for removing iron stains from fabrics. Additionally, it finds application in wood restoration and cleaning processes, where it effectively removes tannin stains and brightens aged wood surfaces. Unlike substances such as benzonitrile, which serves primarily as a solvent intermediate, oxalic acid's chelating properties make it particularly valuable in cleaning and restoration applications. OYSI provides high-quality oxalic acid to European industrial customers, ensuring reliable supply for diverse technical applications.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3261
ADR Class8
Packing GroupIII
Tunnel CodeE
Proper Shipping NameOxalsäure, wasserfrei, fest
Marine PollutantNo

Frequently Asked Questions

What is oxalic acid?

Oxalic acid is a naturally occurring dicarboxylic acid with the chemical formula C2H2O4 and CAS number 144-62-7. It has a molecular weight of 90.03 g/mol and appears as colorless crystals. This organic compound is found naturally in many plants including spinach, rhubarb, and sorrel. Industrially, it serves as an important chemical intermediate and cleaning agent due to its strong reducing and chelating properties.

What are the physicochemical properties of oxalic acid?

Oxalic acid is a white crystalline solid at room temperature with no distinctive odor. It is highly soluble in water and alcohol but poorly soluble in organic solvents. The compound has a melting point of approximately 189°C and decomposes before boiling. It forms stable dihydrate crystals under normal conditions and exhibits strong acidic properties with two ionizable hydrogen atoms, making it a diprotic acid.

What is oxalic acid used for?

Oxalic acid is used primarily as a cleaning and bleaching agent, particularly for removing rust stains and mineral deposits. It serves as a reducing agent in photography and textile industries. The compound is utilized in metal polishing, wood bleaching, and as a mordant in dyeing processes. Additionally, it functions as a chemical intermediate in pharmaceutical synthesis and as a laboratory reagent for analytical chemistry applications.

How to handle oxalic acid safely?

Oxalic acid requires careful handling as it carries Acute Tox. 4 classification with GHS07 pictogram and Warning signal word. Wear appropriate personal protective equipment including safety goggles, gloves, and protective clothing. Ensure adequate ventilation when handling to avoid inhalation of dust particles. Avoid direct skin and eye contact, and never ingest the substance. Work in well-ventilated areas and have emergency washing facilities readily available.

How to store oxalic acid correctly?

Oxalic acid should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers away from incompatible materials such as strong bases, oxidizing agents, and metals. Store in original packaging with proper labeling intact. Ensure storage areas are equipped with appropriate spill containment measures and maintain temperatures below 25°C to prevent decomposition and maintain product stability.

What to do in case of contact with oxalic acid?

In case of skin contact with oxalic acid, immediately remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. For eye contact, rinse thoroughly with clean water for at least 15 minutes and seek immediate medical attention. If ingested, do not induce vomiting, rinse mouth with water and seek immediate medical care. For inhalation, move person to fresh air and monitor breathing.

How to dispose of oxalic acid properly?

Oxalic acid disposal must comply with local, national, and EU waste regulations as it is classified as hazardous waste. Small quantities can be neutralized carefully with sodium bicarbonate solution under controlled conditions before disposal. Large quantities require professional hazardous waste disposal services. Never dispose of oxalic acid in regular drains or municipal waste systems. Contact licensed waste management companies for proper collection, treatment, and disposal according to regulatory requirements.

How to transport oxalic acid?

Oxalic acid is classified under ADR as Class 8 (corrosive substances), Packing Group III for transportation purposes. It must be packaged in UN-approved containers with proper hazard labels and documentation. Transport vehicles must carry appropriate emergency equipment and drivers require ADR certification. Ensure packages are properly secured, labeled, and accompanied by transport documents including safety data sheets for emergency response purposes.

Is oxalic acid subject to particular regulations?

Oxalic acid is subject to standard EU chemical regulations including REACH registration and CLP classification requirements but is not listed as a Substance of Very High Concern (SVHC). It must be supplied with compliant safety data sheets and appropriate hazard labeling showing Acute Tox. 4 classification. Industrial users must comply with occupational exposure limits and workplace safety regulations. No specific restrictions apply beyond standard chemical safety requirements.

Where to buy oxalic acid in Europe?

Oxalic acid is available throughout Europe from OYSI, a specialized chemical distributor offering high-quality industrial chemicals to professional customers. OYSI provides reliable supply chain management with proper documentation, safety data sheets, and regulatory compliance. The company serves various industries across European markets with technical support and customized packaging solutions. Contact OYSI directly for quotations, availability, and delivery options in your region.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.