Methanedithione

CS2

methanedithione

CAS75-15-0
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
75-15-0
EC Number
200-843-6
UN Number
1131
Index Number
006-003-00-3
PubChem CID
6348

Physical-chemical properties

Molecular Formula
CS2
Molar Mass
76.15 g/mol
IUPAC Name
methanedithione

Chemical Identifiers

InChI
InChI=1S/CS2/c2-1-3
InChI Key
QGJOPFRUJISHPQ-UHFFFAOYSA-N

Overview

Methanedithione (CAS 75-15-0) is a volatile organic solvent with high flammability and distinctive properties for industrial applications. Methanedithione, commonly known as carbon disulfide, represents a crucial industrial chemical compound with the molecular formula CS2 and a molecular weight of 76.15 g/mol. This colorless liquid exhibits exceptional volatility and distinctive chemical properties that make it valuable across multiple industrial sectors, despite its significant safety considerations. The compound is classified as a highly flammable liquid (Category 2) and carries serious health hazard warnings, including reproductive toxicity (Category 2) and specific target organ toxicity following repeated exposure (Category 1). Its vapor pressure characteristics and low flash point require stringent handling protocols and specialized storage conditions. The substance displays skin and eye irritant properties, necessitating appropriate personal protective equipment during handling operations. Industrial applications of methanedithione span several key sectors, with primary usage in the production of viscose rayon fibers and cellophane manufacturing. The chemical serves as an essential solvent in rubber vulcanization accelerator production and finds application in pesticide formulation processes. Unlike related aromatic compounds such as ethylbenzene, methanedithione's unique sulfur-carbon structure provides specific reactivity patterns that make it irreplaceable in certain chemical synthesis pathways. The compound's ADR classification as Class 3 material reflects its transportation requirements and regulatory compliance needs. Proper ventilation systems and fire suppression measures are mandatory in facilities handling this substance due to its extreme flammability and vapor formation characteristics. OYSI maintains reliable supply chains for methanedithione, ensuring consistent availability for European industrial customers requiring this specialized chemical solvent.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Repr. 2; STOT RE 1; Skin Irrit. 2; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1131
ADR Class3
Packing GroupI
Tunnel CodeC/E
Proper Shipping NameKohlenstoffdisulfid
Marine PollutantNo

Frequently Asked Questions

What is methanedithione?

Methanedithione is a chemical compound with the formula CS2, also commonly known as carbon disulfide. This colorless liquid has a molecular weight of 76.15 g/mol and is classified as a highly flammable substance. It is characterized by its distinctive sweet odor at low concentrations, though it becomes unpleasant at higher levels. Methanedithione is volatile and has a low boiling point, making it an important industrial solvent despite its hazardous properties.

What are the physicochemical properties of methanedithione?

Methanedithione is a colorless, volatile liquid with a characteristic sweet odor that becomes disagreeable at higher concentrations. It has a boiling point of 46°C and is highly volatile at room temperature. The substance is insoluble in water but miscible with many organic solvents including alcohol, ether, and benzene. It has a density of approximately 1.26 g/cm³ and is highly refractive, giving it optical properties useful in certain applications.

What is methanedithione used for?

Methanedithione serves primarily as an industrial solvent and chemical intermediate. It is extensively used in the production of viscose rayon fibers and cellophane manufacturing. The substance also functions as a solvent for rubber, sulfur, oils, and waxes in various industrial processes. Additionally, it serves as a raw material in the synthesis of carbon tetrachloride and other organosulfur compounds, and finds applications in the pesticide and pharmaceutical industries.

How to handle methanedithione safely?

Methanedithione requires careful handling due to its flammable and toxic properties. Workers must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in poorly ventilated areas. All ignition sources must be eliminated from the work area due to its high flammability. Work should be conducted in well-ventilated spaces or under fume hoods to prevent vapor accumulation and potential exposure to this hazardous substance.

How to store methanedithione correctly?

Methanedithione must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from heat sources, sparks, and open flames. Storage areas should be equipped with appropriate fire suppression systems and maintained below 25°C. The substance should be kept away from oxidizing agents, bases, and metals that could cause dangerous reactions. Storage facilities must comply with local fire codes and regulations for flammable liquids of Packing Group I classification.

What to do in case of contact with methanedithione?

Immediate action is required following methanedithione exposure. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician following any significant exposure.

How to dispose of methanedithione properly?

Methanedithione disposal must comply with local and national hazardous waste regulations. The substance cannot be disposed of in regular waste streams due to its toxic and flammable properties. Disposal should only be conducted through licensed hazardous waste management companies that can properly treat or incinerate the material at appropriate high-temperature facilities. Empty containers may still contain hazardous residues and require special handling according to local environmental regulations.

How to transport methanedithione?

Methanedithione is classified under ADR as Class 3 (flammable liquids), Packing Group I, indicating high danger during transport. Shipments must use UN-approved packaging and be properly labeled with appropriate hazard placards. Transport vehicles must comply with ADR regulations for flammable substances, including proper ventilation, fire extinguishing equipment, and driver training requirements. All transport documentation must include proper shipping names, hazard classifications, and emergency response information.

Is methanedithione subject to particular regulations?

Methanedithione is subject to comprehensive chemical safety regulations under REACH and CLP in Europe. It is classified as a Category 2 reproductive toxin and Category 1 specific target organ toxin with repeated exposure, requiring special handling procedures. Occupational exposure limits are strictly regulated, and workplace monitoring may be mandatory. The substance requires safety data sheets for all commercial transactions and may be subject to additional restrictions depending on specific applications and local regulations.

Where to buy methanedithione in Europe?

Methanedithione is available through specialized chemical distributors across Europe who can ensure proper handling and regulatory compliance. OYSI, as a European chemical distributor, can supply methanedithione to qualified industrial customers with appropriate safety protocols and documentation. Due to its hazardous classification, purchases typically require verification of proper storage facilities, trained personnel, and legitimate industrial applications. Contact professional chemical suppliers for availability, technical specifications, and regulatory documentation.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.