Methanedithione
CS2
methanedithione
Consulting for Methanedithione
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Identification
- CAS Number
- 75-15-0
- EC Number
- 200-843-6
- UN Number
- 1131
- Index Number
- 006-003-00-3
- PubChem CID
- 6348
Physical-chemical properties
- Molecular Formula
- CS2
- Molar Mass
- 76.15 g/mol
- IUPAC Name
- methanedithione
Chemical Identifiers
- InChI
- InChI=1S/CS2/c2-1-3
- InChI Key
- QGJOPFRUJISHPQ-UHFFFAOYSA-N
Overview
Methanedithione (CAS 75-15-0) is a highly volatile organic solvent with exceptional dissolving properties and significant industrial applications. Carbon disulfide, commonly known as methanedithione, represents one of the most important sulfur-containing solvents in industrial chemistry. This colorless, highly volatile liquid possesses a characteristic sweet odor in pure form, though technical grades often exhibit a foul smell due to impurities. With its molecular formula CS2 and molecular weight of 76.15 g/mol, this compound demonstrates remarkable solvent capabilities for a wide range of organic materials, making it invaluable across multiple industries. The substance exhibits significant safety considerations that require careful handling protocols. Classified as a flammable liquid category 2 under GHS regulations, methanedithione presents fire hazards with its low flash point and high vapor pressure. The compound carries reproductive toxicity warnings (Repr. 2) and can cause specific target organ toxicity following repeated exposure (STOT RE 1). Additionally, it may cause skin and eye irritation, necessitating appropriate personal protective equipment during handling. Industrial applications of methanedithione span several sectors, with primary uses in viscose fiber production, where it serves as a critical solvent in cellulose processing. The chemical industry extensively utilizes this compound as a reaction medium and extraction solvent, particularly in processes involving sulfur chemistry. Unlike aromatic solvents such as ethylbenzene, methanedithione offers unique selectivity for specific chemical reactions and purification processes. The compound's high volatility and excellent dissolving properties make it particularly valuable in specialized chemical manufacturing and laboratory applications. Transportation requires adherence to ADR class 3 regulations due to its flammable nature. OYSI maintains reliable supply chains for methanedithione, ensuring consistent availability for European industrial customers requiring this specialized solvent.
Safety & Classification
Flam. Liq. 2; Repr. 2; STOT RE 1; Skin Irrit. 2; Eye Irrit. 2
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1131 |
| ADR Class | 3 |
| Packing Group | I |
| Tunnel Code | C/E |
| Proper Shipping Name | Kohlenstoffdisulfid |
| Marine Pollutant | No |
Frequently Asked Questions
What is methanedithione?
Methanedithione is a chemical compound with the formula CS2, also commonly known as carbon disulfide. This colorless liquid has a molecular weight of 76.15 g/mol and CAS number 75-15-0. It is classified as a highly flammable substance with significant health hazards including reproductive toxicity and potential for causing organ damage through repeated exposure. The compound requires careful handling due to its dangerous properties.
What are the physicochemical properties of methanedithione?
Methanedithione is a colorless, highly volatile liquid at room temperature with a characteristic sweet odor when pure, though commercial grades often have an unpleasant smell due to impurities. It has low water solubility but is miscible with many organic solvents. The compound has a high vapor pressure, making it readily evaporable, and is denser than water with excellent solvent properties for various organic materials.
What is methanedithione used for?
Methanedithione is primarily used as an industrial solvent in the production of viscose rayon and cellophane. It serves as a key intermediate in manufacturing carbon tetrachloride and other chemicals. Additional applications include use in the rubber industry as a vulcanization accelerator, in pesticide formulations, and as a solvent for fats, oils, and resins in various industrial processes requiring powerful dissolving capabilities.
How to handle methanedithione safely?
Methanedithione requires strict safety precautions including use of chemical-resistant gloves, safety goggles, and appropriate respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods due to toxic vapor hazards. Eliminate all ignition sources as the substance is highly flammable. Avoid skin and eye contact, and prevent inhalation of vapors to minimize reproductive and organ toxicity risks.
How to store methanedithione correctly?
Methanedithione must be stored in cool, dry, well-ventilated areas away from heat sources, sparks, and open flames due to its high flammability (Class I flammable liquid). Use appropriate containers resistant to the solvent properties of the chemical. Keep away from oxidizing agents and incompatible materials. Storage areas should have appropriate fire suppression systems and spill containment measures to prevent environmental release.
What to do in case of contact with methanedithione?
In case of skin contact with methanedithione, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek medical attention promptly in all cases of exposure, especially given the substance's reproductive and organ toxicity potential.
How to dispose of methanedithione appropriately?
Methanedithione disposal must comply with local and European waste regulations as a hazardous chemical waste. The substance cannot be disposed of in regular waste streams due to its flammability and toxicity. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities may require special incineration at high temperatures in facilities equipped to handle toxic and flammable waste streams safely.
How to transport methanedithione?
Methanedithione is classified under ADR Class 3 (flammable liquids) Packing Group I, indicating maximum danger level for transport. It requires specific UN-approved packaging, proper labeling with flammable liquid hazard signs, and transport documentation. Vehicles must comply with ADR regulations for Class 3 substances, including appropriate fire extinguishers and driver training. Professional hazardous goods transport services are typically required for commercial shipments.
Is methanedithione subject to particular regulations?
Methanedithione is subject to comprehensive European chemical regulations under REACH and CLP classifications. It carries multiple hazard classifications including flammable liquid, reproductive toxicant, and specific target organ toxicity. While not currently listed as an SVHC substance, it requires safety data sheets, proper labeling with GHS pictograms (GHS02, GHS08, GHS07), and compliance with workplace exposure limits and reproductive health protection measures.
Where to buy methanedithione in Europe?
Methanedithione is available through OYSI, a specialized European distributor of technical chemicals. As a professional chemical supplier, OYSI can provide this regulated substance to qualified industrial customers with proper documentation and safety requirements. Due to the hazardous nature and regulatory requirements of methanedithione, purchases typically require verification of intended use and appropriate handling capabilities by the customer.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.