Hydroxylamine;nitric acid

H4N2O4

hydroxylamine;nitric acid

CAS13465-08-2
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
13465-08-2
EC Number
236-691-2
UN Number
Index Number
007-028-00-2
PubChem CID
10129901

Physical-chemical properties

Molecular Formula
H4N2O4
Molar Mass
96.04 g/mol
IUPAC Name
hydroxylamine;nitric acid

Chemical Identifiers

InChI
InChI=1S/HNO3.H3NO/c2-1(3)4;1-2/h(H,2,3,4);2H,1H2
InChI Key
NILJXUMQIIUAFY-UHFFFAOYSA-N

Overview

Hydroxylamine nitrate (CAS 13465-08-2) is an energetic inorganic salt with explosive properties and strong oxidizing characteristics. Hydroxylamine nitrate represents a highly specialized chemical compound formed by the combination of hydroxylamine and nitric acid, resulting in a crystalline salt with the molecular formula H4N2O4. This energetic material exhibits significant hazard properties, classified as a Class 1.1 explosive with additional concerns including potential carcinogenicity, acute toxicity, and various irritant effects. The compound's explosive nature places it in the same category of concern as other energetic materials such as 2-methyl-1,3,5-trinitrobenzene, requiring stringent handling protocols and specialized storage conditions. The substance presents multiple safety challenges due to its classification under several GHS pictograms including explosive (GHS01), health hazard (GHS08), acute toxicity (GHS06), and environmental hazard (GHS09). These classifications reflect its potential to cause serious harm through explosion, toxicity, skin and eye irritation, and possible long-term health effects including carcinogenic properties. The "Danger" signal word emphasizes the critical importance of proper safety measures during handling, storage, and transportation. In industrial applications, hydroxylamine nitrate finds use primarily in specialized chemical synthesis processes, particularly in the production of certain pharmaceuticals and as an intermediate in organic chemistry reactions. It also serves applications in analytical chemistry and research environments where its unique chemical properties are required. Additionally, the compound may be utilized in specific metallurgical processes where controlled oxidation reactions are necessary. OYSI maintains availability of hydroxylamine nitrate for qualified industrial customers requiring this specialized energetic material for legitimate chemical processing applications.

Safety & Classification

Danger
Classification:

Expl. 1.1 ****; Carc. 2; Acute Tox. 3 *; Acute Tox. 4 *; STOT RE 2 *; Skin Irrit. 2; Eye Irrit. 2...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H201

Explosive; mass explosion hazard.

H351

Suspected of causing cancer.

H311

Toxic in contact with skin.

H302

Harmful if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is hydroxylamine nitrate?

Hydroxylamine nitrate is an inorganic chemical compound with the molecular formula H4N2O4 and CAS number 13465-08-2. This substance has a molecular weight of 96.04 g/mol and is classified as a highly hazardous material due to its explosive properties (Class 1.1) and potential carcinogenic effects (Category 2). It presents multiple health risks including acute toxicity and poses significant safety concerns requiring specialized handling protocols in industrial applications.

What are the physicochemical properties of hydroxylamine nitrate?

Hydroxylamine nitrate is a crystalline solid at room temperature, typically appearing as white or colorless crystals. The compound is highly soluble in water and polar solvents due to its ionic nature. It exhibits hygroscopic properties, readily absorbing moisture from air. The substance is thermally unstable and can decompose explosively under certain conditions, making temperature control critical during handling and storage operations.

What is hydroxylamine nitrate used for?

Hydroxylamine nitrate is primarily used as an intermediate in chemical synthesis and pharmaceutical manufacturing. It serves as a reducing agent in various organic reactions and is utilized in the production of specialized chemicals. The compound finds applications in analytical chemistry laboratories and research facilities. Due to its hazardous classification, its use is restricted to professional industrial settings with appropriate safety infrastructure and trained personnel.

How to handle hydroxylamine nitrate safely?

Hydroxylamine nitrate requires extreme caution during handling due to its explosive and toxic nature. Personnel must wear full personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or fume hoods, away from heat sources and incompatible materials. Only trained professionals should handle this substance, following strict standard operating procedures to prevent accidental detonation or exposure incidents.

How to store hydroxylamine nitrate correctly?

Hydroxylamine nitrate must be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and incompatible materials. The storage facility should be designed for explosive materials with appropriate safety measures. Containers must be tightly sealed to prevent moisture absorption and contamination. Temperature should be maintained below recommended limits, and the storage area must be separated from organic materials, reducing agents, and other potentially reactive substances.

What to do in case of contact with hydroxylamine nitrate?

Immediate medical attention is required for any contact with hydroxylamine nitrate. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with water and seek urgent medical care. If inhaled, move person to fresh air and provide oxygen if breathing is difficult. Never induce vomiting if ingested. Contact emergency services immediately and provide safety data sheet information to medical personnel.

How to dispose of hydroxylamine nitrate properly?

Hydroxylamine nitrate disposal must be conducted by licensed hazardous waste management companies due to its explosive and toxic properties. The substance cannot be disposed of through normal waste streams and requires specialized treatment facilities. Small quantities should be neutralized following approved procedures by qualified personnel. All disposal activities must comply with local environmental regulations and waste management directives, including proper documentation and tracking of hazardous waste movements.

How to transport hydroxylamine nitrate?

Hydroxylamine nitrate transportation requires compliance with dangerous goods regulations due to its explosive classification. Specialized packaging designed for explosive materials must be used, with appropriate labeling including GHS pictogrammes GHS01, GHS08, GHS06, and GHS09. Only certified carriers with dangerous goods training can transport this substance. All shipments must be accompanied by proper documentation, emergency response information, and safety data sheets for emergency responders.

Is hydroxylamine nitrate subject to specific regulations?

Hydroxylamine nitrate is subject to extensive regulatory controls under REACH, CLP, and dangerous goods regulations. Its explosive classification (1.1) and carcinogenic properties (Category 2) trigger strict handling, storage, and transport requirements. The substance requires safety data sheets and hazard labeling with the signal word 'Danger'. Companies handling this material must implement risk management measures and may need special permits or licenses depending on quantities and intended use.

Where to buy hydroxylamine nitrate in Europe?

Hydroxylamine nitrate is available through specialized chemical distributors like OYSI, which serves the European market with technical-grade chemicals. Due to its hazardous classification, purchases are restricted to qualified industrial users with appropriate safety infrastructure and regulatory compliance. Buyers must provide proper documentation regarding intended use, safety measures, and waste management procedures. Contact OYSI's technical team for availability, specifications, and regulatory guidance for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.