Nitric acid

HNO3

nitric acid

CAS7697-37-2
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
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Identification

CAS Number
7697-37-2
EC Number
231-714-2
UN Number
2031
Index Number
007-004-00-1
PubChem CID
944

Physical-chemical properties

Molecular Formula
HNO3
Molar Mass
63.01 g/mol
IUPAC Name
nitric acid

Chemical Identifiers

InChI
InChI=1S/HNO3/c2-1(3)4/h(H,2,3,4)
InChI Key
GRYLNZFGIOXLOG-UHFFFAOYSA-N

Overview

Nitric acid (CAS 7697-37-2) is a highly corrosive inorganic acid with strong oxidizing properties and widespread industrial applications. This colorless to slightly yellow liquid represents one of the most important industrial chemicals in modern manufacturing processes. With the molecular formula HNO3 and a molar mass of 63.013 g/mol, nitric acid exhibits exceptional chemical reactivity that makes it indispensable across numerous sectors. The compound's classification under multiple hazard categories - including Oxidizing Liquid 3, Acute Toxicity 3, and Skin Corrosion 1A - reflects its potent nature and the critical importance of proper handling procedures. The substance's oxidizing capabilities are particularly noteworthy, as it can readily donate oxygen atoms to other compounds, making it valuable in various chemical synthesis processes. Unlike other corrosive chemicals such as pentachloro-lambda5-phosphane, nitric acid's unique combination of acidic and oxidizing properties sets it apart in industrial applications. Its high reactivity with metals and organic materials requires specialized storage and transportation protocols, classified under ADR Class 8 for corrosive substances. Primary industrial applications include fertilizer production, where nitric acid serves as a precursor for ammonium nitrate and other nitrogen-containing compounds. The chemical industry extensively utilizes it in the manufacture of explosives, dyes, and pharmaceuticals. Additionally, the electronics sector employs nitric acid in semiconductor manufacturing and metal surface treatment processes. OYSI maintains comprehensive stocks of technical-grade nitric acid to support European industrial operations, ensuring reliable supply chains for critical manufacturing processes across multiple industries.

Safety & Classification

Danger
Classification:

Ox. Liq. 3; Acute Tox. 3; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H272

May intensify fire; oxidiser.

H331

Toxic if inhaled.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2031
ADR Class8
Packing GroupI
ADR Labels5.1, 8
Tunnel CodeB/E
Proper Shipping NameSALPETERSÄURE, außer rauchender, mit mehr als 70 % Säure
Marine PollutantNo

Frequently Asked Questions

What is nitric acid?

Nitric acid is a highly corrosive and oxidizing inorganic acid with the chemical formula HNO3. This colorless to slightly yellow liquid is one of the most important industrial chemicals, characterized by its strong acidic properties and powerful oxidizing capabilities. With a molecular weight of 63.013 g/mol and CAS number 7697-37-2, nitric acid is classified as a dangerous substance requiring careful handling due to its corrosive nature and acute toxicity.

What are the physicochemical properties of nitric acid?

Nitric acid is a colorless to pale yellow liquid at room temperature with a characteristic pungent, suffocating odor. It is highly miscible with water in all proportions and has a high density. The substance is hygroscopic, meaning it readily absorbs moisture from air. Nitric acid is thermally unstable and decomposes when heated, releasing toxic nitrogen oxides. It exhibits strong oxidizing properties and reacts violently with organic materials and reducing agents.

What is nitric acid used for?

Nitric acid serves multiple industrial applications, primarily in fertilizer production where it's used to manufacture ammonium nitrate and other nitrogen-based fertilizers. It's essential in explosives manufacturing, metal processing for pickling and etching, and in the production of nitrocellulose for plastics and lacquers. The chemical industry uses it for synthesizing various organic and inorganic compounds, while the electronics sector employs it for semiconductor processing and PCB manufacturing.

How to handle nitric acid safely?

Nitric acid requires strict safety protocols due to its corrosive and oxidizing nature. Personnel must wear appropriate PPE including acid-resistant gloves, chemical-resistant clothing, safety goggles, and respiratory protection when necessary. Work should be conducted in well-ventilated areas or under fume hoods. Avoid contact with organic materials, metals, and reducing agents. Use acid-resistant tools and equipment, and ensure emergency shower and eyewash stations are readily accessible.

How to store nitric acid correctly?

Nitric acid must be stored in cool, dry, well-ventilated areas away from direct sunlight and heat sources. Use only containers made of compatible materials such as glass or specific acid-resistant plastics. Keep separated from organic materials, metals, alkalis, and reducing agents to prevent dangerous reactions. Storage areas should have appropriate spill containment systems and be equipped with emergency response materials. Maintain temperatures below 25°C when possible.

What to do in case of contact with nitric acid?

Immediate action is crucial following nitric acid contact. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15-20 minutes. If eyes are affected, rinse immediately with clean water for at least 15 minutes while holding eyelids open. For inhalation, move victim to fresh air immediately. If ingested, do not induce vomiting; rinse mouth and seek immediate medical attention for all exposure scenarios.

How to dispose of nitric acid appropriately?

Nitric acid disposal must comply with local environmental regulations and waste management laws. Small quantities can be neutralized carefully with appropriate alkaline materials under controlled conditions, but this should only be done by trained personnel. Large quantities require professional hazardous waste disposal services. Never pour nitric acid down drains or into the environment. Contact licensed waste disposal companies familiar with corrosive and oxidizing substances for proper treatment and disposal.

How to transport nitric acid?

Nitric acid is classified under ADR as Class 8 (corrosive substances), Packing Group I, indicating high danger level. Transportation requires specialized packaging meeting UN specifications and appropriate hazard labeling including corrosive and oxidizing pictograms. Vehicles must carry proper documentation, emergency response information, and drivers need hazmat certification. Shipments must comply with quantity limitations and routing restrictions as specified in dangerous goods transportation regulations.

Is nitric acid subject to specific regulations?

Nitric acid is extensively regulated under multiple European frameworks including REACH registration requirements and CLP classification as Oxidizing Liquid 3, Acute Toxicity 3, and Skin Corrosion 1A. It requires appropriate GHS pictograms (GHS03, GHS06, GHS05) and 'Danger' signal word on labels. Industrial users must comply with occupational exposure limits, environmental discharge restrictions, and may need permits for storage and use. The substance is not currently listed as SVHC under REACH.

Where to buy nitric acid in Europe?

Nitric acid is available through OYSI, a specialized European distributor of industrial chemicals. As professional chemical suppliers, OYSI provides nitric acid in various concentrations and packaging sizes suitable for industrial applications. They ensure compliance with European regulations including proper documentation, safety data sheets, and transportation requirements. For pricing, availability, and technical specifications, contact OYSI directly to discuss your specific nitric acid requirements and delivery options across Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.