Hexane-1,6-diamine
C6H16N2
hexane-1,6-diamine
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Identification
- CAS Number
- 124-09-4
- EC Number
- 204-679-6
- UN Number
- 2280
- Index Number
- 612-104-00-9
- PubChem CID
- 16402
Physical-chemical properties
- Molecular Formula
- C6H16N2
- Molar Mass
- 116.20 g/mol
- IUPAC Name
- hexane-1,6-diamine
Chemical Identifiers
- InChI
- InChI=1S/C6H16N2/c7-5-3-1-2-4-6-8/h1-8H2
- InChI Key
- NAQMVNRVTILPCV-UHFFFAOYSA-N
Overview
Hexane-1,6-diamine (CAS 124-09-4) is an aliphatic diamine compound featuring two primary amino groups separated by a six-carbon methylene chain. This linear diamine, also known by its IUPAC designation hexane-1,6-diamine, represents a crucial building block in polymer chemistry and industrial synthesis. With the molecular formula C6H16N2 and a molar mass of 116.2 g/mol, this compound exhibits the characteristic reactivity of primary amines while offering unique structural properties due to its symmetric configuration and optimal chain length. The presence of two terminal amino groups makes hexane-1,6-diamine highly reactive and versatile for cross-linking applications. However, this reactivity necessitates careful handling protocols, as the substance carries significant safety considerations. Classified under ADR Class 8, it presents corrosive properties (Skin Corr. 1B) and acute toxicity concerns (Acute Tox. 4), requiring appropriate personal protective equipment and engineering controls during use. The GHS07 and GHS05 pictogrammes reflect these hazard characteristics, emphasizing the need for proper training and safety measures. Industrial applications of hexane-1,6-diamine primarily center on polymer production, particularly in the manufacture of polyamides and polyurethanes where its six-carbon chain length provides optimal mechanical properties. The compound serves as a key intermediate in specialty chemical synthesis and finds use in epoxy curing systems. Unlike simpler amines such as phenylmethanamine, hexane-1,6-diamine offers enhanced cross-linking density due to its difunctional nature, making it valuable for high-performance applications requiring superior mechanical strength and chemical resistance. OYSI maintains strategic inventory of hexane-1,6-diamine to support European industrial customers requiring reliable access to this essential chemical intermediate.
Safety & Classification
Acute Tox. 4 *; Acute Tox. 4 *; STOT SE 3; Skin Corr. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2280 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Hexamethylendiamin, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is hexane-1,6-diamine?
Hexane-1,6-diamine is an organic chemical compound with the molecular formula C6H16N2 and CAS number 124-09-4. This aliphatic diamine consists of a six-carbon chain with amino groups (-NH2) at both ends, giving it a molecular weight of 116.2 g/mol. It is classified as a hazardous substance with corrosive properties and is widely used in industrial applications, particularly in polymer synthesis and chemical manufacturing processes.
What are the physicochemical properties of hexane-1,6-diamine?
Hexane-1,6-diamine is typically a white crystalline solid at room temperature with a characteristic amine odor. It exhibits good solubility in water and polar solvents due to its amino groups, which can form hydrogen bonds. The compound has a relatively low molecular weight of 116.2 g/mol and displays basic properties due to the presence of two primary amine groups. Its chemical structure makes it reactive towards acids, forming stable salts.
What is hexane-1,6-diamine used for?
Hexane-1,6-diamine is primarily used as a monomer in the production of polyamides, particularly nylon 6,6, where it reacts with adipic acid to form the polymer chain. It serves as an intermediate in the synthesis of various chemicals including corrosion inhibitors, fuel additives, and specialty polymers. The compound is also utilized in the manufacture of epoxy curing agents, polyurethane systems, and as a building block for pharmaceuticals and agrochemicals in industrial applications.
How to handle hexane-1,6-diamine safely?
Hexane-1,6-diamine must be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing due to its corrosive nature (Skin Corr. 1B). Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid direct skin and eye contact, and ensure emergency eyewash and shower facilities are readily available. Handle containers carefully to prevent spills and always follow established safety protocols for corrosive materials.
How to store hexane-1,6-diamine correctly?
Hexane-1,6-diamine should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers away from acids, oxidizing agents, and moisture to prevent unwanted reactions. Storage areas should be equipped with appropriate spill containment measures and maintained at stable temperatures. Ensure proper labeling with GHS pictogramms (GHS05, GHS07) and follow local regulations for hazardous chemical storage. Regular container inspection is recommended to detect any deterioration.
What to do in case of contact with hexane-1,6-diamine?
In case of skin contact with hexane-1,6-diamine, immediately flush the affected area with plenty of water for at least 15 minutes and remove contaminated clothing. For eye contact, rinse thoroughly with water for at least 15 minutes and seek immediate medical attention due to its corrosive properties. If inhaled, move the person to fresh air and seek medical advice if respiratory irritation occurs. In case of ingestion, do not induce vomiting and seek immediate medical attention.
How to dispose of hexane-1,6-diamine properly?
Hexane-1,6-diamine must be disposed of as hazardous waste in accordance with local, national, and international environmental regulations. The substance cannot be disposed of in regular waste streams due to its corrosive and toxic properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities should be neutralized carefully under controlled conditions by qualified personnel before disposal. Always consult current waste disposal regulations and maintain proper documentation of disposal activities.
How to transport hexane-1,6-diamine?
Hexane-1,6-diamine is classified under ADR Class 8 (corrosive substances), Packing Group III for transportation purposes. It must be packaged in UN-approved containers with appropriate labeling including the corrosive hazard pictogram. Transport vehicles must carry proper documentation and emergency response information. Drivers require ADR training for hazardous materials transport. Ensure containers are properly secured, leak-proof, and protected from physical damage during transit. Follow all international dangerous goods regulations for road transport.
Is hexane-1,6-diamine subject to particular regulations?
Hexane-1,6-diamine is subject to various regulatory frameworks including REACH registration requirements for manufacture and import in the European Union. It must be classified and labeled according to CLP regulation with appropriate hazard pictograms (GHS05, GHS07) and safety data sheets. The substance is not currently listed as a Substance of Very High Concern (SVHC). Industrial users must comply with occupational exposure limits and implement appropriate risk management measures as outlined in regulatory guidelines.
Where to buy hexane-1,6-diamine in Europe?
Hexane-1,6-diamine is available through OYSI, a European distributor of technical chemicals serving industrial customers across the continent. OYSI provides reliable supply chains for this specialty chemical with proper documentation including safety data sheets and certificates of analysis. As a regulated hazardous substance, purchases typically require verification of legitimate industrial use and compliance with local regulations. Contact OYSI directly for availability, specifications, and regulatory compliance information for your specific application requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.