Dipotassium;dioxido(dioxo)chromium
CrK2O4
dipotassium;dioxido(dioxo)chromium
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Identification
- CAS Number
- 7789-00-6
- EC Number
- 232-140-5
- UN Number
- 3288
- Index Number
- 024-006-00-8
- PubChem CID
- 24597
Physical-chemical properties
- Molecular Formula
- CrK2O4
- Molar Mass
- 194.19 g/mol
- IUPAC Name
- dipotassium;dioxido(dioxo)chromium
Chemical Identifiers
- InChI
- InChI=1S/Cr.2K.4O/q;2*+1;;;2*-1
- InChI Key
- XMXNVYPJWBTAHN-UHFFFAOYSA-N
Overview
Dipotassium;dioxido(dioxo)chromium (CAS 7789-00-6) is an inorganic chromate compound with strong oxidizing properties and significant industrial applications. This potassium chromate salt, with the molecular formula CrK2O4 and EC number 232-140-5, represents one of the most widely used hexavalent chromium compounds in industrial chemistry. With a molecular weight of 194.19 g/mol, this yellow crystalline solid exhibits excellent solubility in water and demonstrates powerful oxidizing characteristics that make it valuable across multiple technical applications. The substance requires careful handling due to its comprehensive hazard profile, classified under GHS pictograms GHS08, GHS07, and GHS09 with the signal word "Danger." Its classification as Carcinogenic 1B and Mutagenic 1B reflects the serious health risks associated with hexavalent chromium exposure, while additional hazard categories include skin and eye irritation, skin sensitization, and acute aquatic toxicity. Transportation falls under ADR class 6.1, emphasizing its toxic nature during shipping and storage. Primary industrial applications include leather tanning processes, where its oxidizing properties facilitate chrome tanning of hides, pigment manufacturing for producing chrome yellow and other chromate-based colorants, and specialized analytical chemistry procedures. The compound also serves in metal finishing operations and as an intermediate in producing other chromium-containing chemicals. Unlike organic compounds such as 4-[(4-aminophenyl)methyl]aniline used in dye synthesis, potassium chromate's inorganic nature provides unique oxidative capabilities essential for specific industrial transformations. OYSI maintains reliable supply chains for this critical industrial chemical, ensuring consistent availability for European customers requiring technical-grade chromate compounds for their manufacturing processes.
Safety & Classification
Carc. 1B; Muta. 1B; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquati...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3288 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Kaliumchromat |
| Marine Pollutant | No |
Frequently Asked Questions
What is dipotassium;dioxido(dioxo)chromium?
Dipotassium;dioxido(dioxo)chromium is an inorganic chemical compound with the molecular formula CrK2O4 and CAS number 7789-00-6. This chromium-based salt has a molecular weight of 194.19 g/mol and is classified as a highly hazardous substance. It presents significant health risks including carcinogenic and mutagenic properties, making it a Category 1B carcinogen and mutagen. The compound is also classified as a skin and eye irritant, skin sensitizer, and poses acute aquatic toxicity risks to environmental systems.
What are the physicochemical properties of dipotassium;dioxido(dioxo)chromium?
Dipotassium;dioxido(dioxo)chromium is a solid inorganic compound that typically appears as a crystalline material. As a chromium(VI) compound, it generally exhibits good water solubility, forming bright colored solutions. The compound has a molecular weight of 194.19 g/mol and contains potassium and chromium in its structure. Like most chromium(VI) compounds, it is likely to be hygroscopic and may decompose under certain temperature conditions, releasing potentially harmful vapors.
What is dipotassium;dioxido(dioxo)chromium used for?
Dipotassium;dioxido(dioxo)chromium is primarily used in specialized industrial applications where chromium chemistry is required. Common applications include analytical chemistry as a reagent, electroplating processes, and certain manufacturing procedures requiring chromium compounds. Due to its high toxicity profile and carcinogenic properties, its use is heavily restricted and limited to professional industrial settings with appropriate safety controls. Many traditional applications have been replaced by safer alternatives due to health and environmental concerns.
How to handle dipotassium;dioxido(dioxo)chromium safely?
Dipotassium;dioxido(dioxo)chromium requires extreme caution during handling due to its carcinogenic and mutagenic properties. Essential personal protective equipment includes chemical-resistant gloves, protective clothing, eye protection, and respiratory protection when dust generation is possible. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid skin contact, inhalation, and ingestion. Personnel must be trained in proper handling procedures, and emergency procedures should be readily available. Regular health monitoring may be required for exposed workers.
How to store dipotassium;dioxido(dioxo)chromium correctly?
Dipotassium;dioxido(dioxo)chromium must be stored in a cool, dry, well-ventilated area away from incompatible materials. The storage area should be secure and accessible only to trained personnel due to its hazardous nature. Containers must be tightly sealed and properly labeled with appropriate hazard warnings. Store away from heat sources, acids, and organic materials that could potentially react. Regular inspection of storage containers is essential to detect any deterioration or leakage. Temperature and humidity control help maintain product stability.
What to do in case of contact with dipotassium;dioxido(dioxo)chromium?
Immediate action is critical following contact with dipotassium;dioxido(dioxo)chromium. For skin contact, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. For eye contact, rinse immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. If ingested, do not induce vomiting and seek immediate medical attention. In all cases, obtain prompt medical care and provide the safety data sheet to healthcare providers.
How to dispose of dipotassium;dioxido(dioxo)chromium appropriately?
Dipotassium;dioxido(dioxo)chromium must be disposed of as hazardous waste through licensed waste management contractors specialized in chromium compound disposal. The compound cannot be disposed of in regular waste streams due to its carcinogenic properties and environmental toxicity. Waste containers must be properly labeled and segregated from other waste types. Recovery or recycling may be possible through specialized facilities. All disposal activities must comply with local, national, and European waste regulations, including proper documentation and tracking requirements.
How to transport dipotassium;dioxido(dioxo)chromium?
Dipotassium;dioxido(dioxo)chromium is classified under ADR Class 6.1 (Toxic substances) with Packing Group II, indicating significant toxicity requiring special transport precautions. Transportation must comply with dangerous goods regulations including proper packaging, labeling, and documentation. Vehicles must display appropriate hazard placards, and drivers require dangerous goods training certification. Emergency response information must accompany shipments. Only authorized carriers with dangerous goods permits can transport this substance, and specific routing restrictions may apply in certain areas.
Is dipotassium;dioxido(dioxo)chromium subject to specific regulations?
Dipotassium;dioxido(dioxo)chromium is subject to extensive regulatory oversight under European legislation. It falls under REACH registration requirements and CLP classification as a Category 1B carcinogen and mutagen. The compound is classified with GHS pictograms GHS08, GHS07, and GHS09, requiring specific labeling and safety data sheets. Workplace exposure limits and health surveillance requirements typically apply. Additional restrictions may exist for certain uses, and authorization requirements under REACH may be necessary for continued industrial use in Europe.
Where to buy dipotassium;dioxido(dioxo)chromium in Europe?
Dipotassium;dioxido(dioxo)chromium is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous substances. Due to the compound's high-risk classification and regulatory requirements, purchase is typically restricted to qualified industrial users with appropriate handling capabilities and regulatory compliance. OYSI provides comprehensive technical support, proper packaging, and documentation required for safe handling and regulatory compliance. Professional guidance on safety measures, storage, and application is included with supply to ensure proper industrial use.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.