Disodium;dioxido(dioxo)chromium

CrNa2O4

disodium;dioxido(dioxo)chromium

CAS7775-11-3
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7775-11-3
EC Number
231-889-5
UN Number
3290
Index Number
024-018-00-3
PubChem CID
24488

Physical-chemical properties

Molecular Formula
CrNa2O4
Molar Mass
161.97 g/mol
IUPAC Name
disodium;dioxido(dioxo)chromium

Chemical Identifiers

InChI
InChI=1S/Cr.2Na.4O/q;2*+1;;;2*-1
InChI Key
PXLIDIMHPNPGMH-UHFFFAOYSA-N

Overview

Disodium dioxido(dioxo)chromium (CAS 7775-11-3) is an inorganic chromium compound with highly oxidizing properties and significant toxicological hazards. This yellow crystalline solid, also known by its molecular formula CrNa2O4, represents one of the most hazardous chromium compounds in industrial chemistry. With a molecular weight of 161.973 g/mol and EC number 231-889-5, this substance demands exceptional handling precautions due to its classification as a Category 1B carcinogen, mutagen, and reproductive toxicant. The compound exhibits acute toxicity across multiple exposure routes and causes severe skin corrosion, necessitating comprehensive safety protocols in any industrial application. The substance's danger classification encompasses multiple pictograms including GHS08 (health hazard), GHS06 (acute toxicity), GHS05 (corrosion), and GHS09 (environmental hazard), reflecting its broad spectrum of risks. Its ADR classification as Class 6.1 toxic substance further emphasizes the stringent transportation requirements. Unlike less hazardous industrial chemicals such as 2-chloroacetaldehyde, which shares some oxidizing characteristics, disodium dioxido(dioxo)chromium requires specialized containment and handling expertise. Primary industrial applications include specialized electroplating processes, certain pigment manufacturing operations, and as an analytical reagent in laboratory settings. However, its extreme toxicity profile has led to significant regulatory restrictions and the development of safer alternatives in many traditional applications. The compound's environmental persistence and bioaccumulation potential make it subject to strict waste disposal regulations across European markets. OYSI maintains specialized handling capabilities and regulatory compliance expertise for this highly controlled chromium compound, ensuring safe supply chain management for qualified industrial customers.

Safety & Classification

Danger
Classification:

Carc. 1B; Muta. 1B; Repr. 1B; Acute Tox. 2 *; Acute Tox. 4 *; Acute Tox. 3 *; STOT RE 1; Skin Cor...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H350

May cause cancer.

H340

May cause genetic defects.

H330

Fatal if inhaled.

H312

Harmful in contact with skin.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H314

Causes severe skin burns and eye damage.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3290
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameNatriumchromat
Marine PollutantNo

Frequently Asked Questions

What is disodium;dioxido(dioxo)chromium?

Disodium;dioxido(dioxo)chromium is an inorganic chromium compound with the chemical formula CrNa2O4 and CAS number 7775-11-3. This substance has a molecular weight of 161.973 g/mol and appears as a yellow crystalline solid. It is classified as extremely hazardous due to its carcinogenic, mutagenic, and reproductive toxicity properties, requiring strict safety measures during handling and use in industrial applications.

What are the physicochemical properties of disodium;dioxido(dioxo)chromium?

Disodium;dioxido(dioxo)chromium is a yellow crystalline solid at room temperature with high water solubility. The compound has a molecular weight of 161.973 g/mol and contains hexavalent chromium in its structure. It is hygroscopic and can form hydrates when exposed to moisture. The substance is stable under normal conditions but decomposes at high temperatures, releasing toxic chromium compounds.

What is disodium;dioxido(dioxo)chromium used for?

Disodium;dioxido(dioxo)chromium is primarily used in industrial applications including metal finishing, chrome plating, and as an oxidizing agent in chemical synthesis. It serves as a corrosion inhibitor in cooling systems and is utilized in the production of pigments and dyes. The compound also finds application in analytical chemistry and as a laboratory reagent, though its use is heavily restricted due to severe health hazards.

How to handle disodium;dioxido(dioxo)chromium safely?

Disodium;dioxido(dioxo)chromium requires maximum protection during handling due to its extreme toxicity. Essential PPE includes chemical-resistant gloves, full-face respiratory protection, and complete body coverage. Work must be conducted in well-ventilated areas or under fume hoods. Avoid skin contact, inhalation, and ingestion completely. Use only in controlled industrial settings with trained personnel and emergency procedures in place.

How to store disodium;dioxido(dioxo)chromium correctly?

Disodium;dioxido(dioxo)chromium must be stored in tightly sealed, corrosion-resistant containers in a cool, dry, well-ventilated area away from incompatible materials. Keep away from organic materials, reducing agents, and acids to prevent dangerous reactions. Storage areas should have restricted access, appropriate warning signs, and emergency equipment. Containers should be regularly inspected for integrity and properly labeled according to CLP regulations.

What to do in case of contact with disodium;dioxido(dioxo)chromium?

Immediate medical attention is critical for any contact with disodium;dioxido(dioxo)chromium. For skin contact, remove contaminated clothing and flush with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical help. For eye contact, rinse thoroughly with water and get immediate medical attention. Never induce vomiting if ingested. Call poison control or emergency services immediately in all cases.

How to dispose of disodium;dioxido(dioxo)chromium appropriately?

Disodium;dioxido(dioxo)chromium must be disposed of as hazardous waste through licensed waste management companies specializing in toxic metal compounds. The substance cannot be disposed of in regular waste streams due to its extreme toxicity and environmental persistence. Treatment typically involves stabilization and secure landfill disposal. All disposal activities must comply with local, national, and EU waste regulations including proper documentation and tracking procedures.

How to transport disodium;dioxido(dioxo)chromium?

Disodium;dioxido(dioxo)chromium is classified under ADR as Class 6.1 (toxic substances), Packing Group II, indicating high toxicity requiring special transport precautions. Packages must be properly labeled with appropriate hazard markings and documentation. Transport requires trained personnel, emergency response information, and compliance with dangerous goods regulations. Vehicles must carry appropriate safety equipment and follow designated routes where applicable.

Is disodium;dioxido(dioxo)chromium subject to specific regulations?

Disodium;dioxido(dioxo)chromium is subject to strict regulations under REACH and CLP due to its classification as carcinogenic, mutagenic, and toxic for reproduction (CMR Category 1B). The substance requires authorization for many uses and is restricted in consumer applications. Companies must comply with occupational exposure limits, worker protection requirements, and environmental discharge restrictions. Registration and safety data sheet obligations apply to all suppliers and users.

Where to buy disodium;dioxido(dioxo)chromium in Europe?

Disodium;dioxido(dioxo)chromium is available through specialized chemical distributors like OYSI, which serves the European market with technical-grade chemicals. Due to its hazardous classification, purchase is typically restricted to qualified industrial users with appropriate safety infrastructure and regulatory compliance. Buyers must demonstrate legitimate use, proper handling capabilities, and compliance with all applicable regulations before purchase authorization.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.