Calcium dihypochlorite

CaCl2O2

calcium dihypochlorite

CAS7778-54-3
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7778-54-3
EC Number
231-908-7
UN Number
3485
Index Number
017-012-00-7
PubChem CID
24504

Physical-chemical properties

Molecular Formula
CaCl2O2
Molar Mass
142.98 g/mol
IUPAC Name
calcium dihypochlorite

Chemical Identifiers

InChI
InChI=1S/Ca.2ClO/c;2*1-2/q+2;2*-1
InChI Key
ZKQDCIXGCQPQNV-UHFFFAOYSA-N

Overview

Calcium dihypochlorite (CAS 7778-54-3) is an inorganic oxidizing compound with strong bleaching and disinfecting properties used primarily in water treatment applications. This white crystalline powder represents one of the most widely utilized chlorine-based oxidizing agents in industrial water treatment and sanitation processes. Calcium dihypochlorite contains approximately 65-70% available chlorine, making it significantly more concentrated than household bleach solutions. The compound readily dissolves in water, releasing hypochlorous acid which provides its characteristic antimicrobial and oxidizing action. From a safety perspective, calcium dihypochlorite requires careful handling due to its classification as Oxidizing Solid Category 2 under GHS regulations. The substance exhibits corrosive properties (Skin Corr. 1B) and poses acute toxicity risks, necessitating appropriate personal protective equipment during handling and storage. Its strong oxidizing nature means it must be stored away from combustible materials and reducing agents to prevent potentially hazardous reactions. The compound also presents environmental concerns as an aquatic acute toxin, requiring controlled discharge and proper waste management protocols. Primary industrial applications include municipal water treatment for drinking water disinfection, swimming pool sanitization, and industrial process water treatment. The textile and paper industries utilize calcium dihypochlorite for bleaching applications, while food processing facilities employ it for equipment sanitization and surface disinfection. Unlike other oxidizing compounds such as chromium-based oxidizers like chromium(2+);dioxido(dioxo)chromium, calcium dihypochlorite offers the advantage of complete solubility in water without heavy metal residues. OYSI provides high-quality calcium dihypochlorite to European industrial customers, ensuring consistent available chlorine content and reliable supply chain management for critical water treatment applications.

Safety & Classification

Danger
Classification:

Ox. Sol. 2; Acute Tox. 4 *; Skin Corr. 1B; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H272

May intensify fire; oxidiser.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3485
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameCalciumhypochlorit, trocken, entzündend (oxidierend) wirkend, ätzend oder schwach ätzend
Marine PollutantNo

Frequently Asked Questions

What is calcium dihydrochlorite?

Calcium dihydrochlorite is an inorganic chemical compound with the molecular formula CaCl2O2 and CAS number 7778-54-3. This oxidizing substance has a molecular weight of 142.98 g/mol and belongs to the hypochlorite family. It is classified as a hazardous substance under GHS regulations with oxidizing properties (Ox. Sol. 2), acute toxicity (Acute Tox. 4), skin corrosivity (Skin Corr. 1B), and aquatic toxicity (Aquatic Acute 1). The compound carries the danger signal word and multiple hazard pictograms indicating its reactive nature.

What are the physicochemical properties of calcium dihydrochlorite?

Calcium dihydrochlorite is typically a white to light gray crystalline solid with a characteristic chlorine-like odor. The compound is highly soluble in water, releasing hypochlorous acid and calcium ions upon dissolution. It demonstrates strong oxidizing properties due to its hypochlorite content, making it reactive with organic materials and reducing agents. The substance is hygroscopic, meaning it readily absorbs moisture from the atmosphere. Its oxidizing nature makes it incompatible with combustible materials, acids, and many organic compounds.

What is calcium dihydrochlorite used for?

Calcium dihydrochlorite is primarily used as a disinfectant and bleaching agent in various industrial applications. Its strong oxidizing properties make it effective for water treatment, swimming pool sanitation, and industrial bleaching processes. The compound serves as a source of available chlorine in disinfection systems and is utilized in the textile industry for fabric bleaching. It also finds applications in wastewater treatment facilities and as an antimicrobial agent in certain industrial cleaning formulations where controlled chlorine release is required.

How to handle calcium dihydrochlorite safely?

Calcium dihydrochlorite requires careful handling due to its corrosive and oxidizing properties. Personal protective equipment must include chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Respiratory protection should be used when handling powdered forms to avoid inhalation. Work areas must be well-ventilated to prevent accumulation of chlorine vapors. Avoid contact with combustible materials, acids, and organic substances. Always use non-sparking tools and ensure proper grounding to prevent static electricity buildup during handling operations.

How to store calcium dihydrochlorite correctly?

Calcium dihydrochlorite must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly sealed to prevent moisture absorption and decomposition. Store separately from combustible materials, acids, ammonia, and organic compounds due to incompatibility risks. Use corrosion-resistant containers and ensure storage areas have adequate ventilation to prevent chlorine gas accumulation. Maintain storage temperatures below 30°C and protect from humidity. Regular inspection of containers for signs of deterioration or leakage is essential for safe storage.

What to do in case of contact with calcium dihydrochlorite?

Calcium dihydrochlorite contact requires immediate first aid measures due to its corrosive nature. For skin contact, immediately remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and rinse mouth with water. Seek immediate medical attention for all exposure routes, especially for eye contact or ingestion.

How to dispose of calcium dihydrochlorite appropriately?

Calcium dihydrochlorite disposal must comply with local and European waste regulations as a hazardous substance. The compound cannot be disposed of in regular waste streams due to its oxidizing and corrosive properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized under controlled conditions by qualified personnel before disposal. Always consult local environmental authorities for specific disposal requirements. Never dispose of this substance in sewers, waterways, or soil as it poses environmental risks to aquatic life.

How to transport calcium dihydrochlorite?

Calcium dihydrochlorite is classified under ADR as Class 5.1 (Oxidizing substances) with Packing Group II, indicating significant transport hazards. Packaging must comply with ADR regulations using approved containers designed for oxidizing substances. Vehicles must carry appropriate placards and documentation. Drivers require ADR certification for dangerous goods transport. Segregation rules must be followed to prevent contact with incompatible materials during transport. Proper ventilation in transport vehicles is essential to prevent gas accumulation. Emergency response information must accompany shipments for incident management.

Is calcium dihydrochlorite subject to particular regulations?

Calcium dihydrochlorite is subject to multiple European regulations including REACH registration requirements and CLP classification and labeling. The substance is not currently listed as a Substance of Very High Concern (SVHC) under REACH. However, its hazardous properties require compliance with occupational safety regulations, environmental protection laws, and transport regulations (ADR). Users must maintain safety data sheets, implement risk management measures, and ensure proper worker training. Some applications may require additional permits or notifications depending on quantities used and specific industrial applications.

Where to buy calcium dihydrochlorite in Europe?

Calcium dihydrochlorite is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this oxidizing compound to industrial customers across Europe with full regulatory compliance and technical support. As a professional chemical distributor, OYSI ensures proper documentation, safety data sheets, and regulatory compliance for all shipments. The company serves various industries requiring this disinfectant and bleaching agent. Contact OYSI directly for specific availability, packaging options, and technical specifications tailored to your industrial application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.