Barium(2+) peroxide

BaO2

barium(2+) peroxide

CAS1304-29-6
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
1304-29-6
EC Number
215-128-4
UN Number
1449
Index Number
056-001-00-1
PubChem CID
14773

Physical-chemical properties

Molecular Formula
BaO2
Molar Mass
169.33 g/mol
IUPAC Name
barium(2+) peroxide

Chemical Identifiers

InChI
InChI=1S/Ba.O2/c;1-2/q+2;-2
InChI Key
ZJRXSAYFZMGQFP-UHFFFAOYSA-N

Overview

Barium(2+) peroxide (CAS 1304-29-6) is an inorganic oxidizing compound with strong oxygen-releasing properties and distinctive chemical reactivity. This white crystalline solid, with the molecular formula BaO2 and molar mass of 169.33 g/mol, represents one of the most important alkaline earth metal peroxides used in industrial applications. Barium peroxide demonstrates exceptional oxidizing capabilities, making it valuable in various chemical processes where controlled oxygen release is required. The compound's unique structure allows it to decompose upon heating, releasing nascent oxygen which provides its characteristic oxidizing behavior. From a safety perspective, barium(2+) peroxide requires careful handling due to its classification as Oxidizing Solid Category 2 and Acute Toxicity Category 4. The GHS03 and GHS07 pictograms indicate both its oxidizing nature and health hazards, while the ADR Class 5.1 classification governs its transportation requirements. Personnel must observe appropriate safety protocols when working with this material, including proper ventilation and protective equipment to prevent inhalation or skin contact. Industrial applications of barium peroxide include its use as an oxidizing agent in organic synthesis, as a bleaching agent for certain materials, and in the production of hydrogen peroxide through acid treatment. The compound also finds application in analytical chemistry and specialized manufacturing processes requiring controlled oxidation conditions. While related compounds such as barium(2+) diperchlorate offer different oxidizing characteristics, barium peroxide's stability and controlled reactivity make it particularly suitable for specific industrial requirements. OYSI maintains reliable supply chains for barium(2+) peroxide to support European industrial customers' technical applications and manufacturing needs.

Safety & Classification

Danger
Classification:

Ox. Sol. 2; Acute Tox. 4 *; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H272

May intensify fire; oxidiser.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1449
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameBariumperoxid, wasserfrei
Marine PollutantNo

Frequently Asked Questions

What is barium(2+) peroxide?

Barium(2+) peroxide is an inorganic chemical compound with the formula BaO2 and CAS number 1304-29-6. This barium salt has a molecular weight of 169.33 g/mol and belongs to the peroxide family. It is classified as a solid oxidizing agent (Ox. Sol. 2) with acute toxicity properties. The compound appears as a white to grayish crystalline powder and is primarily used in industrial applications requiring strong oxidizing properties.

What are the physicochemical properties of barium(2+) peroxide?

Barium(2+) peroxide is a white to light gray crystalline solid at room temperature with no characteristic odor. The compound is sparingly soluble in water and decomposes upon contact with moisture, releasing oxygen. It has a high melting point and demonstrates strong oxidizing properties due to its peroxide structure. The substance is denser than water and can release oxygen when heated or in contact with organic materials or reducing agents.

What is barium(2+) peroxide used for?

Barium(2+) peroxide is primarily used as an oxidizing agent in various industrial processes and chemical synthesis. It serves as a source of oxygen in pyrotechnic compositions and serves as a bleaching agent for certain materials. The compound is also utilized in the production of hydrogen peroxide and as an analytical reagent in laboratory applications. Its strong oxidizing properties make it valuable in specialized chemical manufacturing processes.

How to handle barium(2+) peroxide safely?

Barium(2+) peroxide requires careful handling due to its oxidizing and toxic properties (Acute Tox. 4). Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work in well-ventilated areas or under fume hoods to avoid inhalation. Keep the substance away from combustible materials, reducing agents, and sources of ignition. Use non-sparking tools and avoid generating dust during handling operations.

How to store barium(2+) peroxide correctly?

Barium(2+) peroxide must be stored in a cool, dry, well-ventilated area away from incompatible materials. Keep containers tightly sealed and protect from moisture, as the compound decomposes in humid conditions. Store separately from combustible materials, organic compounds, reducing agents, and acids. Use appropriate secondary containment and ensure storage areas are equipped with suitable fire suppression systems. Regular inspection of containers for signs of deterioration is recommended.

What to do in case of contact with barium(2+) peroxide?

Immediate action is required due to the acute toxicity of barium(2+) peroxide. For skin contact, remove contaminated clothing and rinse thoroughly with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with water and seek medical attention. If inhaled, move the person to fresh air and provide artificial respiration if necessary. For ingestion, do not induce vomiting and seek immediate medical attention while providing supportive care.

How to dispose of barium(2+) peroxide appropriately?

Barium(2+) peroxide disposal must comply with local and national hazardous waste regulations due to its oxidizing and toxic properties. The substance cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal companies. Small quantities should be neutralized carefully under controlled conditions before disposal. Always consult local environmental authorities for specific disposal requirements and approved waste management facilities in your region.

How to transport barium(2+) peroxide?

Barium(2+) peroxide is classified under ADR as Class 5.1 (Oxidizing substances), Packing Group II, indicating moderate danger during transport. Packages must meet UN specification requirements and display appropriate hazard labels including oxidizing agent markings. Vehicles must carry appropriate emergency equipment and drivers require ADR certification. The substance must be segregated from incompatible materials during transport and proper shipping documentation must accompany all shipments.

Is barium(2+) peroxide subject to specific regulations?

Barium(2+) peroxide is regulated under various European legislation including CLP Regulation for classification and labeling, displaying GHS03 and GHS07 pictograms with the signal word 'Danger'. While not currently listed as an SVHC substance under REACH, it requires registration for commercial use above certain tonnages. Users must comply with occupational safety regulations and may need special permits depending on quantities and applications in different EU member states.

Where to buy barium(2+) peroxide in Europe?

Barium(2+) peroxide is available through OYSI, a specialized European distributor of technical chemicals. As an established chemical supplier, OYSI can provide this oxidizing compound to qualified industrial customers across Europe. Due to the hazardous nature of this substance, purchases typically require proper documentation, safety data sheets, and compliance with transportation regulations. Contact OYSI directly for availability, technical specifications, and regulatory compliance support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.