Chromium(2+);dioxido(dioxo)chromium

Cr2O4

chromium(2+);dioxido(dioxo)chromium

CAS24613-89-6
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
24613-89-6
EC Number
246-356-2
UN Number
3085
Index Number
024-010-00-X
PubChem CID
38824

Physical-chemical properties

Molecular Formula
Cr2O4
Molar Mass
167.99 g/mol
IUPAC Name
chromium(2+);dioxido(dioxo)chromium

Chemical Identifiers

InChI
InChI=1S/2Cr.4O/q;+2;;;2*-1
InChI Key
ZTPKOWRHFDMHPS-UHFFFAOYSA-N

Overview

Chromium(2+);dioxido(dioxo)chromium (CAS 24613-89-6) is an inorganic chromium compound with strong oxidizing properties and significant toxicological concerns. This chromium oxide compound, with the molecular formula Cr2O4 and a molar mass of 167.99 g/mol, represents a critical industrial chemical requiring specialized handling protocols. The substance exhibits dual oxidation states of chromium, combining Cr(II) and Cr(VI) species within its molecular structure, which contributes to its distinctive chemical reactivity profile. As indicated by its EC number 246-356-2, this compound is well-documented in European chemical regulations and subject to stringent safety requirements. The hazard classification profile reveals the compound's complex safety considerations. It carries a Danger signal word with multiple GHS pictograms (GHS03, GHS05, GHS07, GHS08, GHS09), indicating oxidizing properties (Ox. Sol. 1), severe skin corrosion potential (Skin Corr. 1A), skin sensitization risks (Skin Sens. 1), carcinogenic properties (Carc. 1B), and significant aquatic toxicity (Aquatic Acute 1, Aquatic Chronic 1). The ADR classification 5.1 confirms its oxidizing nature for transportation purposes. Industrial applications typically include specialized oxidation processes in chemical synthesis, certain metallurgical operations, and specific catalytic systems where controlled chromium chemistry is required. Unlike more common chromium compounds such as trioxochromium, this mixed-valence species offers unique reactivity patterns. It shares some oxidizing characteristics with compounds like potassium permanganate, though with distinctly different selectivity profiles. OYSI maintains technical-grade supplies of chromium(2+);dioxido(dioxo)chromium for qualified industrial customers, ensuring compliance with European chemical safety regulations and proper documentation for specialized applications.

Safety & Classification

Danger
Classification:

Ox. Sol. 1; Carc. 1B; Skin Corr. 1A; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H271

May cause fire or explosion; strong oxidiser.

H350

May cause cancer.

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3085
ADR Class5.1
Packing GroupI
Tunnel CodeE
Proper Shipping NameDichromtris(chromat)
Marine PollutantNo

Frequently Asked Questions

What is chromium(2+);dioxido(dioxo)chromium?

Chromium(2+);dioxido(dioxo)chromium is an inorganic compound with the chemical formula Cr2O4 and molecular weight of 167.99 g/mol. This chromium oxide compound contains chromium in different oxidation states and exhibits strong oxidizing properties. It is classified as a highly hazardous substance due to its carcinogenic, corrosive, and sensitizing properties. The compound poses significant environmental risks and requires careful handling in industrial applications.

What are the physicochemical properties of chromium(2+);dioxido(dioxo)chromium?

Chromium(2+);dioxido(dioxo)chromium is a solid inorganic compound with the molecular formula Cr2O4. As a chromium oxide, it typically appears as a crystalline solid with distinctive coloration. The compound exhibits strong oxidizing properties, making it reactive with organic materials and reducing agents. Its exact physical properties like melting point and solubility depend on the specific crystal structure and preparation method.

What is chromium(2+);dioxido(dioxo)chromium used for?

Chromium(2+);dioxido(dioxo)chromium is primarily used in specialized industrial applications where its oxidizing properties are required. The compound may be utilized in certain chemical synthesis processes, catalytic reactions, or as an intermediate in the production of other chromium compounds. Due to its highly hazardous nature and carcinogenic properties, its use is restricted to professional applications with appropriate safety controls and regulatory compliance.

How to handle chromium(2+);dioxido(dioxo)chromium safely?

Chromium(2+);dioxido(dioxo)chromium must be handled with extreme caution using full personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Avoid contact with skin, eyes, and clothing. Keep away from heat sources, combustible materials, and reducing agents due to its strong oxidizing properties.

How to store chromium(2+);dioxido(dioxo)chromium correctly?

Chromium(2+);dioxido(dioxo)chromium should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and separate from combustible materials, organic substances, and reducing agents due to its oxidizing nature. Storage areas must comply with regulations for carcinogenic substances and oxidizing materials. Ensure proper labeling and restrict access to authorized personnel only.

What to do in case of contact with chromium(2+);dioxido(dioxo)chromium?

Chromium(2+);dioxido(dioxo)chromium contact requires immediate emergency response due to its corrosive nature. For skin contact, immediately flush with copious amounts of water for at least 15 minutes and remove contaminated clothing. For eye contact, rinse immediately with water and seek medical attention. If inhaled, move to fresh air immediately. Seek immediate medical attention for any exposure, informing medical personnel of the carcinogenic and corrosive properties.

How to dispose of chromium(2+);dioxido(dioxo)chromium appropriately?

Chromium(2+);dioxido(dioxo)chromium must be disposed of as hazardous waste through licensed waste management companies specializing in carcinogenic and heavy metal-containing materials. The compound cannot be disposed of in regular waste streams due to its environmental hazard classification and carcinogenic properties. Contact local environmental authorities for specific disposal requirements and ensure compliance with all applicable regulations for chromium-containing wastes.

How to transport chromium(2+);dioxido(dioxo)chromium?

Chromium(2+);dioxido(dioxo)chromium is classified as ADR Class 5.1 (Oxidizing substances), Packing Group I, indicating high transport hazard. Transportation requires specialized packaging approved for oxidizing substances and proper hazard labeling including appropriate placards. Only authorized carriers with training in hazardous materials transport should handle shipments. All transport documentation must clearly identify the substance and associated hazards according to international dangerous goods regulations.

Is chromium(2+);dioxido(dioxo)chromium subject to specific regulations?

Chromium(2+);dioxido(dioxo)chromium is subject to extensive regulatory oversight under REACH and CLP regulations due to its classification as carcinogenic (Category 1B), skin corrosive, and environmentally hazardous. The compound requires safety data sheets, risk assessments, and specific workplace controls. Its use may be restricted or require authorization depending on applications. Employers must implement strict occupational exposure controls and health surveillance programs for workers potentially exposed.

Where to buy chromium(2+);dioxido(dioxo)chromium in Europe?

Chromium(2+);dioxido(dioxo)chromium is available through specialized chemical distributors in Europe, including OYSI, which supplies technical chemicals to industrial customers. Due to the hazardous nature of this compound, purchases typically require verification of appropriate handling facilities, trained personnel, and regulatory compliance. Suppliers will require detailed information about intended use and safety measures before processing orders for this restricted substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.