3-chloro-2-methylprop-1-ene
C4H7Cl
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Identification
- CAS Number
- 563-47-3
- EC Number
- 209-251-2
- UN Number
- 2554
- Index Number
- 602-032-00-6
- PubChem CID
- 11241
Physical-chemical properties
- Molecular Formula
- C4H7Cl
- Molar Mass
- 90.55 g/mol
- IUPAC Name
- 3-chloro-2-methylprop-1-ene
Chemical Identifiers
- InChI
- InChI=1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3
- InChI Key
- OHXAOPZTJOUYKM-UHFFFAOYSA-N
Overview
3-chloro-2-methylprop-1-ene (CAS 563-47-3) is a chlorinated alkene compound with significant industrial applications and notable safety considerations. This organic halide compound, with the molecular formula C4H7Cl and molecular weight of 90.55 g/mol, represents an important intermediate in chemical synthesis processes. The molecule features both an alkene double bond and a chlorine substituent, making it a versatile building block for various chemical transformations. Its structure combines the reactivity of unsaturated hydrocarbons with the synthetic utility of organochlorine compounds. The substance presents considerable safety challenges due to its classification under multiple hazard categories. As a Category 2 flammable liquid, it requires careful handling protocols and appropriate fire prevention measures. The compound exhibits acute toxicity (Category 4) and causes severe skin burns and eye damage (Skin Corrosion 1B), necessitating comprehensive personal protective equipment during handling. Additionally, it may cause allergic skin reactions (Skin Sensitization 1) and poses environmental concerns with chronic aquatic toxicity. These hazard properties are reflected in its "Danger" signal word and associated GHS pictograms including flame, exclamation mark, corrosion, and environmental hazard symbols. In industrial applications, 3-chloro-2-methylprop-1-ene serves primarily as a chemical intermediate in organic synthesis, particularly in the production of pharmaceuticals and agrochemicals. It also finds use in polymer chemistry as a reactive monomer component. The compound's reactivity profile differs significantly from related substances such as butan-2-amine, which lacks the halogen functionality and unsaturation that make this chloroalkene particularly valuable in synthetic chemistry. OYSI provides reliable access to 3-chloro-2-methylprop-1-ene for qualified industrial customers throughout Europe, ensuring compliance with all relevant safety and regulatory requirements.
Safety & Classification
Flam. Liq. 2; Acute Tox. 4 *; Acute Tox. 4 *; Skin Corr. 1B; Skin Sens. 1; Aquatic Chronic 2
GHS Pictograms
Flame
GHS02
Flammable. May ignite on contact with air, water, or heat sources.
Exclamation Mark
GHS07
Harmful. May cause irritation, allergic reactions, or drowsiness.
Corrosion
GHS05
Corrosive. Causes severe skin burns and eye damage.
Environment
GHS09
Environmental hazard. Toxic to aquatic life with long lasting effects.
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2554 |
| ADR Class | 3 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Methylallylchlorid |
| Marine Pollutant | No |
Frequently Asked Questions
What is 3-chloro-2-methylprop-1-ene?
3-chloro-2-methylprop-1-ene is an organochlorine compound with the molecular formula C4H7Cl and CAS number 563-47-3. This chemical features a propene backbone with a chlorine atom at position 3 and a methyl group at position 2. With a molecular weight of 90.55 g/mol, it belongs to the class of halogenated alkenes and is classified as a flammable liquid with significant health hazards including acute toxicity and skin corrosion properties.
What are the physicochemical properties of 3-chloro-2-methylprop-1-ene?
3-chloro-2-methylprop-1-ene is a colorless to pale yellow liquid at room temperature with a characteristic pungent odor. As an unsaturated organochlorine compound, it exhibits moderate volatility and is sparingly soluble in water but miscible with most organic solvents. The presence of both the double bond and chlorine substituent influences its reactivity, making it susceptible to polymerization and addition reactions under certain conditions.
What is 3-chloro-2-methylprop-1-ene used for?
3-chloro-2-methylprop-1-ene serves primarily as an intermediate in organic synthesis and chemical manufacturing processes. It is commonly used in the production of specialty chemicals, pharmaceuticals, and agrochemical compounds. The compound's reactive double bond and chlorine functionality make it valuable for various chemical transformations including alkylation reactions, polymer synthesis, and as a building block for more complex molecular structures in fine chemical applications.
How to handle 3-chloro-2-methylprop-1-ene safely?
3-chloro-2-methylprop-1-ene requires strict safety protocols due to its corrosive and toxic properties. Personnel must wear chemical-resistant gloves, safety goggles, and protective clothing when handling this substance. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Given its flammable nature (Class 2), eliminate ignition sources and use explosion-proof equipment. Regular monitoring and proper training are essential for safe handling procedures.
How to store 3-chloro-2-methylprop-1-ene correctly?
3-chloro-2-methylprop-1-ene must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. The storage area should be equipped with appropriate fire suppression systems due to its flammable properties. Keep containers away from oxidizing agents, strong acids, and bases. Storage temperature should be controlled to prevent degradation, and containers should be regularly inspected for signs of corrosion or leakage.
What to do in case of contact with 3-chloro-2-methylprop-1-ene?
Immediate action is required for any contact with 3-chloro-2-methylprop-1-ene due to its corrosive properties. For skin contact, remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with water for 15-20 minutes and remove contact lenses if present. If inhaled, move the person to fresh air immediately. Seek medical attention promptly for all exposure scenarios and provide the safety data sheet to medical personnel.
How to dispose of 3-chloro-2-methylprop-1-ene appropriately?
3-chloro-2-methylprop-1-ene disposal must comply with local and national hazardous waste regulations as it contains halogenated organic compounds. The substance should never be discharged into drains, soil, or waterways due to its environmental hazard classification. Disposal should be handled by licensed hazardous waste contractors through approved methods such as high-temperature incineration with appropriate emission controls. Consult local environmental authorities for specific disposal requirements and authorized waste management facilities.
How to transport 3-chloro-2-methylprop-1-ene?
3-chloro-2-methylprop-1-ene is classified as ADR Class 3 (flammable liquid), Packing Group II, requiring specific transport protocols. Packages must meet UN specification standards and be properly labeled with appropriate hazard markings. Transport vehicles must comply with ADR regulations for flammable liquids, including proper ventilation and fire safety equipment. Drivers must hold valid ADR certification, and transport documents must include emergency response information. Quantities above certain thresholds may require additional safety measures and routing restrictions.
Is 3-chloro-2-methylprop-1-ene subject to specific regulations?
3-chloro-2-methylprop-1-ene is regulated under various European chemical legislation including REACH registration requirements and CLP classification standards. While not currently listed as a Substance of Very High Concern (SVHC), it must comply with standard chemical safety regulations due to its hazardous properties. Users must ensure proper risk assessments, safety data sheet provision, and workplace exposure controls. Import/export may require additional documentation, and specific industry applications might face sector-specific restrictions.
Where to buy 3-chloro-2-methylprop-1-ene in Europe?
3-chloro-2-methylprop-1-ene is available through specialized chemical distributors across Europe, with OYSI serving as a reliable European supplier for this substance. As an established chemical distributor, OYSI can provide technical support, proper documentation, and ensure compliance with European regulations. When sourcing this hazardous chemical, verify that suppliers maintain appropriate certifications, provide comprehensive safety data sheets, and offer proper packaging that meets ADR transport requirements for safe delivery.
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3-chloro-2-methylprop-1-ene is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.