3-chloro-2-methylprop-1-ene
C4H7Cl
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Identification
- CAS Number
- 563-47-3
- EC Number
- 209-251-2
- UN Number
- 2554
- Index Number
- 602-032-00-6
- PubChem CID
- 11241
Physical-chemical properties
- Molecular Formula
- C4H7Cl
- Molar Mass
- 90.55 g/mol
- IUPAC Name
- 3-chloro-2-methylprop-1-ene
Chemical Identifiers
- InChI
- InChI=1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3
- InChI Key
- OHXAOPZTJOUYKM-UHFFFAOYSA-N
Overview
3-chloro-2-methylprop-1-ene (CAS 563-47-3) is an organochlorine compound with reactive allylic chloride functionality and flammable liquid properties. This chlorinated alkene serves as an important intermediate in organic synthesis and industrial chemical manufacturing. With the molecular formula C4H7Cl and a molecular weight of 90.55 g/mol, 3-chloro-2-methylprop-1-ene belongs to the family of allylic halides, characterized by a chlorine atom adjacent to a carbon-carbon double bond. This structural feature imparts significant reactivity, making it valuable for various chemical transformations including nucleophilic substitution and elimination reactions. The compound presents notable safety considerations due to its classification under multiple hazard categories. As a Class 2 flammable liquid with acute toxicity properties, it requires careful handling protocols. The substance exhibits corrosive effects on skin (Category 1B) and acts as a skin sensitizer, necessitating appropriate personal protective equipment during handling. Its environmental classification as Aquatic Chronic 2 indicates potential long-term effects on aquatic ecosystems. Industrial applications primarily focus on its role as a synthetic intermediate in pharmaceutical manufacturing, agrochemical production, and specialty chemical synthesis. The compound's reactivity profile makes it particularly useful in the preparation of more complex molecular structures, similar to how other reactive intermediates like butan-2-amine serve in different synthetic pathways. Transportation under ADR Class 3 regulations reflects its flammable nature, requiring specialized logistics considerations. The compound's versatility in organic synthesis, combined with its defined reactivity patterns, makes it a sought-after building block in various industrial processes. OYSI maintains availability of 3-chloro-2-methylprop-1-ene for qualified industrial customers across Europe, supporting diverse chemical manufacturing applications.
Safety & Classification
Flam. Liq. 2; Acute Tox. 4 *; Acute Tox. 4 *; Skin Corr. 1B; Skin Sens. 1; Aquatic Chronic 2
GHS Pictograms
Flame
GHS02
Flammable. May ignite on contact with air, water, or heat sources.
Exclamation Mark
GHS07
Harmful. May cause irritation, allergic reactions, or drowsiness.
Corrosion
GHS05
Corrosive. Causes severe skin burns and eye damage.
Environment
GHS09
Environmental hazard. Toxic to aquatic life with long lasting effects.
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2554 |
| ADR Class | 3 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Methylallylchlorid |
| Marine Pollutant | No |
Frequently Asked Questions
What is 3-chloro-2-methylprop-1-ene?
3-chloro-2-methylprop-1-ene is an organochlorine compound with the molecular formula C4H7Cl and CAS number 563-47-3. This chemical features a propene backbone with a chlorine atom attached to the third carbon and a methyl group on the second carbon. With a molecular weight of 90.55 g/mol, it belongs to the class of halogenated alkenes and is classified as a hazardous substance requiring careful handling due to its flammability and toxicity properties.
What are the physicochemical properties of 3-chloro-2-methylprop-1-ene?
3-chloro-2-methylprop-1-ene is a volatile organic liquid at room temperature with characteristic properties typical of halogenated alkenes. As an unsaturated chlorinated hydrocarbon, it exhibits moderate polarity due to the chlorine substituent. The compound is flammable and classified as Flam. Liq. 2, indicating high flammability. Its molecular structure with both a double bond and chlorine substitution influences its reactivity and solubility characteristics in organic solvents.
What is 3-chloro-2-methylprop-1-ene used for?
3-chloro-2-methylprop-1-ene serves primarily as a chemical intermediate in organic synthesis and pharmaceutical manufacturing. The compound is utilized in the production of various chemicals through nucleophilic substitution and addition reactions. Its reactive chlorine atom and double bond make it valuable for creating more complex molecular structures. Industrial applications include use as a building block in specialty chemical synthesis and as a reagent in research and development laboratories.
How to handle 3-chloro-2-methylprop-1-ene safely?
3-chloro-2-methylprop-1-ene requires strict safety measures due to its multiple hazard classifications including acute toxicity, skin corrosion, and skin sensitization. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and appropriate respiratory protection. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin contact completely as the substance is classified as Skin Corr. 1B, and ensure no ignition sources are present due to its flammable nature.
How to store 3-chloro-2-methylprop-1-ene correctly?
3-chloro-2-methylprop-1-ene must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames due to its Flam. Liq. 2 classification. Use only approved containers made of compatible materials that resist corrosion from the chlorinated compound. Storage areas should be equipped with appropriate fire suppression systems and secondary containment. Keep containers tightly sealed to prevent vapor release and store away from incompatible materials such as strong bases and oxidizing agents.
What to do in case of contact with 3-chloro-2-methylprop-1-ene?
3-chloro-2-methylprop-1-ene contact requires immediate emergency response due to its corrosive and toxic properties. For skin contact, immediately flush with copious amounts of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, rinse continuously with water and seek immediate medical attention. If inhaled, move to fresh air immediately and provide respiratory support if needed. For ingestion, do not induce vomiting and seek immediate medical care. Always consult a physician after any exposure.
How to dispose of 3-chloro-2-methylprop-1-ene properly?
3-chloro-2-methylprop-1-ene disposal must comply with local and international hazardous waste regulations due to its multiple hazard classifications and environmental impact. The substance cannot be disposed of through normal waste streams and requires treatment by licensed hazardous waste disposal facilities. Incineration at appropriate high temperatures with proper emission controls is typically the preferred method. Ensure proper documentation and manifesting according to waste transport regulations, and never discharge into drains, soil, or water bodies.
How to transport 3-chloro-2-methylprop-1-ene?
3-chloro-2-methylprop-1-ene is classified under ADR Class 3 (flammable liquids), Packing Group II, indicating moderate danger level during transport. Transportation requires compliance with dangerous goods regulations including proper packaging, labeling with appropriate hazard pictogrammes (GHS02, GHS07, GHS05, GHS09), and documentation. Vehicles must be equipped with appropriate safety equipment and drivers must hold valid dangerous goods certifications. Packages must meet UN specification requirements and display the 'Danger' signal word along with required hazard statements.
Is 3-chloro-2-methylprop-1-ene subject to specific regulations?
3-chloro-2-methylprop-1-ene is subject to comprehensive chemical safety regulations including REACH registration requirements in Europe and CLP classification obligations. The substance displays multiple hazard classifications requiring compliance with occupational safety standards and environmental protection measures. While not currently listed as an SVHC (Substance of Very High Concern), its hazardous properties mean it falls under strict handling, storage, and disposal regulations. Companies must maintain safety data sheets and implement appropriate risk management measures.
Where to buy 3-chloro-2-methylprop-1-ene in Europe?
3-chloro-2-methylprop-1-ene is available through OYSI, a specialized European distributor of technical chemicals and laboratory reagents. OYSI provides this regulated chemical compound to qualified industrial customers, research institutions, and chemical manufacturers across Europe. As a professional chemical distributor, OYSI ensures proper documentation, regulatory compliance, and appropriate packaging for safe delivery. Contact OYSI directly for availability, technical specifications, and regulatory documentation required for your specific application and location within Europe.
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3-chloro-2-methylprop-1-ene is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.