2-methylbenzene-1,4-diamine

C7H10N2

CAS95-70-5
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
95-70-5
EC Number
202-442-1
UN Number
2811
Index Number
612-125-00-3
PubChem CID
7252

Physical-chemical properties

Molecular Formula
C7H10N2
Molar Mass
122.17 g/mol
IUPAC Name
2-methylbenzene-1,4-diamine

Chemical Identifiers

InChI
InChI=1S/C7H10N2/c1-5-4-6(8)2-3-7(5)9/h2-4H,8-9H2,1H3
InChI Key
OBCSAIDCZQSFQH-UHFFFAOYSA-N

Overview

2-methylbenzene-1,4-diamine (CAS 95-70-5) is an aromatic diamine compound with two amino groups positioned para to each other on a methylated benzene ring. This organic chemical intermediate, also known by its CAS number 95-70-5 and EC number 202-442-1, represents a significant compound in industrial chemistry applications. With a molecular formula of C7H10N2 and molecular weight of 122.17 g/mol, 2-methylbenzene-1,4-diamine belongs to the family of aromatic diamines, sharing structural similarities with other aniline derivatives such as N-methylaniline in terms of aromatic amine functionality. The compound presents notable safety considerations, classified under multiple acute toxicity categories (Acute Tox. 3 and 4) and as a skin sensitizer (Skin Sens. 1), requiring careful handling protocols. Its hazard classification includes GHS06 and GHS09 pictograms with a "Danger" signal word, and it falls under ADR transport class 6.1 for toxic substances. The aquatic chronic toxicity classification (Aquatic Chronic 2) indicates potential environmental concerns requiring appropriate waste management procedures. In industrial applications, 2-methylbenzene-1,4-diamine serves primarily as an intermediate in organic synthesis, particularly in the production of dyes, pigments, and polymer additives. The compound finds significant use in the manufacture of hair dye formulations and as a building block for specialty chemicals requiring aromatic diamine functionality. Its dual amino group structure makes it valuable in crosslinking applications and as a curing agent precursor in certain polymer systems. OYSI maintains reliable supply chains for 2-methylbenzene-1,4-diamine to support European industrial customers requiring this specialized aromatic diamine intermediate.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 3 *; Skin Sens. 1; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H301

Toxic if swallowed.

H317

May cause an allergic skin reaction.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2811
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping Name2,5-Toluylendiamin, fest
Marine PollutantNo

Frequently Asked Questions

What is 2-methylbenzene-1,4-diamine?

2-methylbenzene-1,4-diamine is an aromatic diamine compound with the molecular formula C7H10N2 and CAS number 95-70-5. This organic chemical features a benzene ring substituted with a methyl group and two amino groups in specific positions. With a molecular weight of 122.17 g/mol, it belongs to the family of methylated phenylenediamines and is classified as a hazardous substance requiring careful handling due to its toxicity and sensitizing properties.

What are the physicochemical properties of 2-methylbenzene-1,4-diamine?

2-methylbenzene-1,4-diamine is typically a crystalline solid at room temperature with a characteristic amine odor. The compound exhibits moderate water solubility and good solubility in organic solvents. Its aromatic structure with two amino groups makes it reactive toward oxidation and capable of forming salts with acids. The presence of the methyl substituent affects its physical properties compared to unsubstituted phenylenediamine, influencing its melting point, solubility, and reactivity patterns.

What is 2-methylbenzene-1,4-diamine used for?

2-methylbenzene-1,4-diamine is primarily used as an intermediate in the synthesis of dyes, pigments, and hair colorants. It serves as a building block for producing various azo dyes and serves in the manufacture of polymers and resins. The compound finds applications in the chemical industry for synthesizing pharmaceuticals and agricultural chemicals. Its diamine structure makes it valuable for cross-linking reactions and as a curing agent in certain polymer applications.

How to handle 2-methylbenzene-1,4-diamine safely?

2-methylbenzene-1,4-diamine requires strict safety measures due to its Acute Tox. 3-4 and Skin Sens. 1 classifications. Always wear appropriate PPE including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume extraction systems to prevent inhalation exposure. Avoid direct skin contact as the substance is a known skin sensitizer. Use non-sparking tools and equipment, and ensure proper grounding to prevent static electricity buildup during handling operations.

How to store 2-methylbenzene-1,4-diamine correctly?

2-methylbenzene-1,4-diamine must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep away from incompatible materials such as strong oxidizers and acids. Storage areas should be equipped with appropriate containment measures and emergency equipment. Maintain storage temperatures below recommended limits and ensure containers are properly labeled according to CLP regulations. Regular inspection of storage containers for signs of deterioration or leakage is essential.

What to do in case of contact with 2-methylbenzene-1,4-diamine?

2-methylbenzene-1,4-diamine exposure requires immediate emergency response due to its toxicity. For skin contact, immediately remove contaminated clothing and wash affected areas thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician and provide the safety data sheet.

How to dispose of 2-methylbenzene-1,4-diamine appropriately?

2-methylbenzene-1,4-diamine disposal must comply with local, national, and EU waste regulations as it is classified as hazardous waste. The substance cannot be disposed of in regular waste streams due to its toxicity and environmental classification (Aquatic Chronic 2). Arrange disposal through licensed hazardous waste contractors who can ensure proper treatment or incineration at authorized facilities. Never discharge into sewers, waterways, or soil. Maintain proper documentation of waste disposal for regulatory compliance.

How to transport 2-methylbenzene-1,4-diamine?

2-methylbenzene-1,4-diamine is classified under ADR Class 6.1 (Toxic substances), Packing Group III, requiring compliance with dangerous goods transport regulations. The substance must be packaged in UN-approved containers with appropriate hazard labels and documentation. Transport vehicles must carry proper placarding and emergency response information. Only authorized personnel trained in dangerous goods handling should manage transportation. Ensure segregation from incompatible materials and follow specific loading, unloading, and emergency procedures during transport.

Is 2-methylbenzene-1,4-diamine subject to specific regulations?

2-methylbenzene-1,4-diamine is subject to comprehensive EU chemical regulations including REACH registration requirements and CLP classification obligations. The substance carries GHS06 and GHS09 pictograms with 'Danger' signal word, requiring specific labeling and safety data sheet provisions. While not currently listed as SVHC under REACH, its toxic and sensitizing properties may subject it to additional restrictions or authorizations. Manufacturers and importers must comply with registration requirements and downstream users must follow exposure scenario recommendations.

Where to buy 2-methylbenzene-1,4-diamine in Europe?

2-methylbenzene-1,4-diamine is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this substance to industrial customers with proper documentation including certificates of analysis and safety data sheets. As a regulated chemical requiring specialized handling and storage, purchase is typically restricted to qualified industrial users with appropriate facilities and safety measures. Contact OYSI directly for availability, specifications, and regulatory compliance support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.