Benzene-1,4-diamine
C6H8N2
benzene-1,4-diamine
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Identification
- CAS Number
- 106-50-3
- EC Number
- 203-404-7
- UN Number
- 1673
- Index Number
- 612-028-00-6
- PubChem CID
- 7814
Physical-chemical properties
- Molecular Formula
- C6H8N2
- Molar Mass
- 108.14 g/mol
- IUPAC Name
- benzene-1,4-diamine
Chemical Identifiers
- InChI
- InChI=1S/C6H8N2/c7-5-1-2-6(8)4-3-5/h1-4H,7-8H2
- InChI Key
- CBCKQZAAMUWICA-UHFFFAOYSA-N
Overview
Benzene-1,4-diamine (CAS 106-50-3) is an aromatic diamine compound with two amino groups positioned para to each other on a benzene ring. This organic chemical compound, also known by its IUPAC designation benzene-1,4-diamine, represents a fundamental building block in industrial chemistry with the molecular formula C6H8N2 and a molecular weight of 108.14 g/mol. The substance belongs to the aromatic amine family, characterized by its distinctive structure featuring amino groups (-NH2) at opposite positions on the benzene ring, which imparts unique reactivity patterns essential for various synthetic processes. The compound exhibits significant safety considerations, classified under multiple acute toxicity categories and requiring careful handling protocols. Its hazard profile includes acute toxicity via oral, dermal, and inhalation routes, along with eye irritation potential and skin sensitization properties. The substance also presents environmental concerns with acute aquatic toxicity, necessitating appropriate containment and disposal measures. These safety characteristics are reflected in its GHS06 and GHS09 pictograms and ADR classification 6.1, indicating its status as a toxic substance requiring specialized transport conditions. Industrially, benzene-1,4-diamine serves primarily as an intermediate in polymer synthesis, particularly in the production of aramid fibers and high-performance plastics. It also functions as a crucial component in dye manufacturing and serves as a curing agent for epoxy resins in specialized applications. The compound shares structural similarities with other aromatic amines like N-methylaniline, though its para-disubstituted configuration provides distinct reactivity advantages in polymerization reactions. OYSI provides benzene-1,4-diamine to European industrial customers with comprehensive technical documentation and safety data sheets to ensure proper handling and application.
Safety & Classification
Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *; Eye Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aqua...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1673 |
| ADR Class | 6.1 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | p-Phenylendiamin, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is benzene-1,4-diamine?
Benzene-1,4-diamine is an organic aromatic compound with the molecular formula C6H8N2 and CAS number 106-50-3. Also known as para-phenylenediamine (p-PDA), it consists of a benzene ring with two amino groups (-NH2) positioned at opposite ends (para position). With a molecular weight of 108.14 g/mol, this compound appears as crystalline solid and serves as an important industrial intermediate in chemical synthesis.
What are the physico-chemical properties of benzene-1,4-diamine?
Benzene-1,4-diamine is a white to slightly pink crystalline solid at room temperature with a characteristic amine odor. It has good solubility in water, alcohol, and other polar solvents due to its amino groups. The compound is sensitive to light and air, which can cause oxidation and darkening. It has a relatively low melting point and exhibits basic properties due to the presence of two amino functional groups.
What is benzene-1,4-diamine used for?
Benzene-1,4-diamine is primarily used as an intermediate in the production of aramid fibers, particularly para-aramids like Kevlar. It serves as a key component in manufacturing high-performance polymers, dyes, and pigments. The compound is also utilized in the production of antioxidants for rubber and plastics, photographic developers, and hair dyes. Its applications span across textile, automotive, and chemical industries where high-strength materials are required.
How to handle benzene-1,4-diamine safely?
Benzene-1,4-diamine must be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods due to its toxic properties (Acute Tox. 3) and skin sensitization potential (Skin Sens. 1). Avoid direct skin and eye contact, and prevent inhalation of dust or vapors. Emergency eyewash stations and safety showers should be readily accessible.
How to store benzene-1,4-diamine correctly?
Benzene-1,4-diamine should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep away from oxidizing agents, acids, and incompatible materials. Storage areas should be equipped with appropriate spill containment measures and maintained at stable temperatures. Containers should be clearly labeled with hazard information and stored according to local chemical storage regulations to prevent degradation and ensure safety.
What to do in case of contact with benzene-1,4-diamine?
In case of skin contact with benzene-1,4-diamine, immediately remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15-20 minutes and remove contact lenses if present. If inhaled, move to fresh air immediately. Seek medical attention promptly in all cases of exposure, especially if irritation persists or symptoms develop, due to the compound's sensitization potential.
How to dispose of benzene-1,4-diamine appropriately?
Benzene-1,4-diamine must be disposed of as hazardous waste through licensed waste management companies in accordance with local and European regulations. Do not discharge into drains, soil, or water bodies due to its aquatic toxicity classification (Aquatic Acute 1). Contaminated packaging should also be treated as hazardous waste. Consult local environmental authorities for specific disposal requirements and approved treatment facilities in your region.
How to transport benzene-1,4-diamine?
Benzene-1,4-diamine is classified under ADR Class 6.1 (toxic substances), Packing Group III for transport purposes. It must be packaged in appropriate UN-approved containers with proper labeling including GHS06 (skull and crossbones) and GHS09 (environmental hazard) pictograms. Transport documentation must include the correct shipping name, UN number, and hazard class. Only authorized carriers with proper training and equipment should handle the transportation of this substance.
Is benzene-1,4-diamine subject to particular regulations?
Benzene-1,4-diamine is subject to CLP regulation with hazard classifications including Acute Tox. 3, Eye Irrit. 2, Skin Sens. 1, and Aquatic Acute 1, requiring 'Danger' signal word. While not currently listed as SVHC under REACH, it must comply with registration requirements for manufacturing or import above one tonne per year. Users must follow occupational exposure limits and safety data sheet requirements under European chemical legislation.
Where to buy benzene-1,4-diamine in Europe?
Benzene-1,4-diamine is available through OYSI, a specialized European distributor of industrial chemicals. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures quality products meeting European standards and provides technical support for safe handling and application guidance. Contact OYSI directly for availability, specifications, and delivery options in your region.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.