1,1,1-trichloroethane
C2H3Cl3
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Identification
- CAS Number
- 71-55-6
- EC Number
- 200-756-3
- UN Number
- 2831
- Index Number
- 602-013-00-2
- PubChem CID
- 6278
Physical-chemical properties
- Molecular Formula
- C2H3Cl3
- Molar Mass
- 133.40 g/mol
- IUPAC Name
- 1,1,1-trichloroethane
Chemical Identifiers
- InChI
- InChI=1S/C2H3Cl3/c1-2(3,4)5/h1H3
- InChI Key
- UOCLXMDMGBRAIB-UHFFFAOYSA-N
Overview
1,1,1-trichloroethane (CAS 71-55-6) is a chlorinated hydrocarbon solvent with excellent degreasing properties and low toxicity compared to other chlorinated compounds. This versatile organochlorine compound, also known as methyl chloroform, has served as an important industrial solvent for decades due to its unique combination of chemical stability, non-flammability, and relatively favorable safety profile. With the molecular formula C2H3Cl3 and a molecular weight of 133.4 g/mol, 1,1,1-trichloroethane demonstrates excellent solvency characteristics that make it valuable for specialized applications requiring precise cleaning and degreasing capabilities. The substance exhibits distinctive physical and chemical properties that distinguish it from related compounds. Unlike more hazardous chlorinated solvents, 1,1,1-trichloroethane presents a more manageable risk profile, classified under GHS07 pictogram with a Warning signal word. However, it requires careful handling due to its Acute Toxicity 4 classification and significant ozone depletion potential (Ozone 1 classification), which has led to regulatory restrictions under the Montreal Protocol. The compound's ADR classification as Class 6.1 necessitates appropriate transportation and storage protocols. Industrial applications primarily focus on precision cleaning operations, metal degreasing processes, and as a solvent in specialized chemical formulations. The electronics industry particularly values its non-conductive properties for cleaning sensitive components, while the aerospace sector utilizes it for critical degreasing applications. In chemical synthesis, it serves as an intermediate compound, sometimes alongside other industrial chemicals such as benzonitrile in specific manufacturing processes. OYSI provides 1,1,1-trichloroethane to qualified industrial customers, ensuring full compliance with current European regulations and supporting technical applications where this specialized solvent remains permitted and essential for specific industrial processes.
Safety & Classification
Acute Tox. 4 *; Ozone 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2831 |
| ADR Class | 6.1 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | 1,1,1-Trichlorethan |
| Marine Pollutant | No |
Frequently Asked Questions
What is 1,1,1-trichloroethane?
1,1,1-trichloroethane is a chlorinated hydrocarbon with the chemical formula C2H3Cl3 and molecular weight of 133.4 g/mol. This synthetic compound, identified by CAS number 71-55-6, belongs to the family of organochlorine solvents. It appears as a colorless liquid with a sweet, chloroform-like odor and is known for its excellent solvent properties and chemical stability under normal conditions.
What are the physical and chemical properties of 1,1,1-trichloroethane?
1,1,1-trichloroethane is a colorless liquid with a characteristic sweet odor similar to chloroform. It has a boiling point of approximately 74°C and is poorly soluble in water but miscible with most organic solvents. The compound is relatively stable under normal conditions, non-flammable, and has a density greater than water. It evaporates readily at room temperature, forming vapors heavier than air.
What is 1,1,1-trichloroethane used for?
1,1,1-trichloroethane is primarily used as a degreasing solvent in metal cleaning applications and precision cleaning of electronic components. It serves as an effective cleaning agent in vapor degreasing operations and cold cleaning processes. The compound is also utilized in adhesive formulations, as a chemical intermediate in synthesis reactions, and in specialized cleaning applications where its non-flammable properties are advantageous.
How to handle 1,1,1-trichloroethane safely?
Safe handling of 1,1,1-trichloroethane requires appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection when adequate ventilation is not available. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid skin contact and inhalation of vapors. The substance is classified as Acute Tox. 4, requiring careful handling to prevent exposure through dermal or inhalation routes.
How to store 1,1,1-trichloroethane correctly?
1,1,1-trichloroethane should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Storage areas must be equipped with appropriate ventilation systems to prevent vapor accumulation. Keep containers upright and properly labeled according to CLP requirements. Store away from incompatible materials such as strong bases, metals like aluminum, and oxidizing agents to prevent degradation or dangerous reactions.
What to do in case of contact with 1,1,1-trichloroethane?
In case of skin contact with 1,1,1-trichloroethane, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water. For eye contact, rinse immediately with plenty of clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and seek medical advice if symptoms persist. In case of ingestion, do not induce vomiting and seek immediate medical attention.
How to dispose of 1,1,1-trichloroethane properly?
1,1,1-trichloroethane must be disposed of as hazardous waste in accordance with local, national, and EU waste regulations. The substance cannot be discharged into sewers or the environment due to its ozone-depleting properties and toxicity. Disposal should be carried out by licensed waste management companies specializing in halogenated solvents. Empty containers must also be handled as hazardous waste and properly cleaned or disposed of according to regulations.
How to transport 1,1,1-trichloroethane?
1,1,1-trichloroethane is classified under ADR as Class 6.1 (toxic substances), Packing Group III, requiring specific packaging, marking, and documentation for transport. Packages must bear appropriate hazard labels and proper shipping names. Transport vehicles must comply with ADR regulations including equipment requirements and driver training. Shipping documents must include the correct UN number, proper shipping name, hazard class, and packing group information.
Is 1,1,1-trichloroethane subject to specific regulations?
1,1,1-trichloroethane is subject to multiple regulatory frameworks including REACH registration requirements and CLP classification as Acute Tox. 4 and Ozone 1. It is regulated under the Montreal Protocol as an ozone-depleting substance, significantly restricting its production and use. The substance requires safety data sheets and appropriate hazard labeling with GHS07 pictogram and warning signal word. Industrial users must comply with emission limits and reporting requirements.
Where to buy 1,1,1-trichloroethane in Europe?
1,1,1-trichloroethane can be purchased from OYSI, a specialized European distributor of chemical products serving industrial customers across the continent. As a professional chemical supplier, OYSI provides quality products with proper documentation, safety data sheets, and regulatory compliance support. Due to the substance's regulatory restrictions as an ozone-depleting compound, availability may be limited and subject to specific authorization requirements depending on the intended application and jurisdiction.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.