1,1,2-trichloroethane

C2H3Cl3

CAS79-00-5
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
79-00-5
EC Number
201-166-9
UN Number
2810
Index Number
602-014-00-8
PubChem CID
6574

Physical-chemical properties

Molecular Formula
C2H3Cl3
Molar Mass
133.40 g/mol
IUPAC Name
1,1,2-trichloroethane

Chemical Identifiers

InChI
InChI=1S/C2H3Cl3/c3-1-2(4)5/h2H,1H2
InChI Key
UBOXGVDOUJQMTN-UHFFFAOYSA-N

Overview

1,1,2-Trichloroethane (CAS 79-00-5) is a chlorinated hydrocarbon solvent with excellent degreasing properties and moderate volatility. This organochlorine compound belongs to the family of halogenated aliphatic hydrocarbons and serves as an important industrial solvent in various technical applications. With its molecular formula C2H3Cl3 and molecular weight of 133.4 g/mol, 1,1,2-trichloroethane exhibits distinct chemical properties that make it valuable for specialized industrial processes. The compound is characterized by its colorless liquid appearance and relatively high density compared to water. From a safety perspective, 1,1,2-trichloroethane requires careful handling due to its classification as a Category 2 carcinogen and Category 4 acute toxin across multiple exposure routes. The substance displays GHS08 and GHS07 pictograms with a "Warning" signal word, indicating potential health hazards that necessitate appropriate protective measures during use. Its ADR classification of 6.1 reflects its toxic nature for transportation purposes. The compound finds primary applications in metal degreasing operations, where its solvent properties effectively remove oils and greases from metal surfaces. It also serves as an intermediate in chemical synthesis processes and as a specialized cleaning agent in electronics manufacturing. Unlike related compounds such as 4-nitrophenol which is used in indicator applications, 1,1,2-trichloroethane's halogenated structure provides superior degreasing capabilities for industrial cleaning applications. Industrial users appreciate its controlled evaporation rate and effectiveness in removing stubborn contaminants from precision components. OYSI maintains reliable supply chains for 1,1,2-trichloroethane to support European industrial customers requiring consistent quality and technical support.

Safety & Classification

Warning
Classification:

Carc. 2; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2810
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping Name1,1,2-Trichlorethan
Marine PollutantNo

Frequently Asked Questions

What is 1,1,2-trichloroethane?

1,1,2-trichloroethane is a chlorinated hydrocarbon with the molecular formula C2H3Cl3 and CAS number 79-00-5. This organic compound has a molecular weight of 133.4 g/mol and belongs to the family of chloroalkanes. It is classified as a hazardous substance with carcinogenic properties (Category 2) and acute toxicity effects. The compound is regulated under various chemical safety frameworks due to its potential health risks.

What are the physicochemical properties of 1,1,2-trichloroethane?

1,1,2-trichloroethane is typically a colorless liquid at room temperature with a sweet, chloroform-like odor. It has limited solubility in water but is miscible with many organic solvents including alcohols and ethers. The compound exhibits moderate volatility and has a density greater than water. Its chlorinated structure makes it relatively stable under normal conditions but susceptible to hydrolysis in the presence of bases or at elevated temperatures.

What is 1,1,2-trichloroethane used for?

1,1,2-trichloroethane is primarily used as an industrial solvent and chemical intermediate in organic synthesis. It serves as a degreasing agent for metal cleaning operations and as a solvent in various chemical processes. The compound is also utilized in the production of other chlorinated compounds and as a laboratory reagent. However, its applications have become increasingly restricted due to environmental and health concerns, leading to the adoption of safer alternatives in many industries.

How to handle 1,1,2-trichloroethane safely?

1,1,2-trichloroethane must be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection when necessary. Work should be conducted in well-ventilated areas or under fume extraction systems to minimize inhalation exposure. Given its carcinogenic classification (Category 2) and acute toxicity, operators should follow strict hygiene protocols, avoid skin contact, and never eat, drink, or smoke in work areas. Emergency shower and eyewash facilities should be readily accessible.

How to store 1,1,2-trichloroethane correctly?

1,1,2-trichloroethane should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Storage areas must be equipped with appropriate containment systems to prevent spills from reaching drains or waterways. The substance should be kept away from strong bases, metals, and oxidizing agents to prevent unwanted reactions. Temperature control is important to minimize vapor formation, and storage facilities should comply with local fire and safety regulations.

What to do in case of contact with 1,1,2-trichloroethane?

Immediate removal from exposure is essential in case of contact with 1,1,2-trichloroethane. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes while holding eyelids open. If inhaled, move the person to fresh air and monitor breathing. For ingestion, do not induce vomiting and seek immediate medical attention, providing the safety data sheet to healthcare professionals.

How to dispose of 1,1,2-trichloroethane properly?

1,1,2-trichloroethane must be disposed of as hazardous waste through licensed waste management companies authorized to handle chlorinated solvents. The substance cannot be disposed of in regular waste streams or poured down drains due to its toxicity and environmental persistence. Disposal must comply with local, national, and EU waste regulations including the Waste Framework Directive. Incineration at high temperatures in specialized facilities is typically the preferred treatment method, ensuring complete destruction of the compound.

How to transport 1,1,2-trichloroethane?

1,1,2-trichloroethane is classified under ADR as Class 6.1 (Toxic substances), Packing Group III for transportation purposes. It must be packaged in approved containers meeting UN specification requirements and properly labeled with hazard placards and marking. Transportation documents must include the proper shipping name and UN identification number. Drivers must hold appropriate ADR training certificates, and vehicles should carry emergency response information. Special handling procedures apply for loading, unloading, and emergency situations during transport.

Is 1,1,2-trichloroethane subject to specific regulations?

1,1,2-trichloroethane is subject to comprehensive regulation under EU REACH and CLP regulations, requiring registration and classification as a carcinogenic substance. While not currently listed as an SVHC (Substance of Very High Concern), its carcinogenic properties subject it to strict workplace exposure limits and risk management measures. Industrial users must implement appropriate risk assessment and management strategies. The substance may also be subject to national restrictions and international protocols governing chlorinated compounds.

Where to buy 1,1,2-trichloroethane in Europe?

1,1,2-trichloroethane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the region. As an established chemical distributor, OYSI can provide the necessary documentation including safety data sheets, certificates of analysis, and regulatory compliance information required for professional use. Due to the substance's hazardous classification, purchases are typically restricted to qualified industrial users with appropriate handling capabilities and regulatory authorizations.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.