Zinc bis(N,N-dimethylcarbamodithioate)

C6H12N2S4Zn

zinc bis(N,N-dimethylcarbamodithioate)

CAS137-30-4
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
137-30-4
EC Number
205-288-3
UN Number
2771
Index Number
006-012-00-2
PubChem CID
8722

Physical-chemical properties

Molecular Formula
C6H12N2S4Zn
Molar Mass
305.80 g/mol
IUPAC Name
zinc bis(N,N-dimethylcarbamodithioate)

Chemical Identifiers

InChI
InChI=1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2
InChI Key
DUBNHZYBDBBJHD-UHFFFAOYSA-L

Overview

Zinc bis(N,N-dimethylcarbamodithioate) (CAS 137-30-4) is an organosulfur zinc complex with potent biocidal and antimicrobial properties widely used in industrial applications. This dithiocarbamate compound, with molecular formula C6H12N2S4Zn and molecular weight 305.8 g/mol, represents a critical chemical intermediate in various industrial processes. The substance belongs to the family of metal dithiocarbamates, which are characterized by their sulfur-nitrogen coordination bonds with metal centers. Its chemical structure features two dimethylcarbamodithioate ligands coordinated to a central zinc atom, creating a stable organometallic complex with distinct antimicrobial and preservative properties. The compound exhibits significant toxicological properties, classified under multiple hazard categories including Acute Toxicity Category 2 and 4, Eye Damage Category 1, and Skin Sensitization Category 1. The presence of GHS06, GHS08, GHS05, and GHS09 pictograms indicates serious health hazards, organ toxicity potential, corrosive effects, and environmental dangers respectively. Its ADR Class 6.1 classification requires specialized handling and transport protocols for toxic substances. Primary industrial applications include its use as a biocide in water treatment systems, as an antimicrobial agent in industrial preservation, and as a chemical intermediate in the synthesis of specialized compounds. Unlike simpler biocides such as 2,2-dibromo-2-cyanoacetamide, this zinc-based dithiocarbamate offers enhanced stability and prolonged antimicrobial activity in aqueous environments. The compound's effectiveness stems from its ability to interfere with cellular metabolism through sulfur-metal interactions. OYSI maintains reliable supply chains for zinc bis(N,N-dimethylcarbamodithioate), ensuring consistent availability for European industrial customers requiring this specialized organometallic compound.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Acute Tox. 4 *; STOT SE 3; STOT RE 2 *; Eye Dam. 1; Skin Sens. 1; Aquatic Acute 1...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H373

May cause damage to organs through prolonged or repeated exposure.

H318

Causes serious eye damage.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2771
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameZiram (ISO)
Marine PollutantNo

Frequently Asked Questions

What is zinc bis(N,N-dimethylcarbamodithioate)?

Zinc bis(N,N-dimethylcarbamodithioate) is an organometallic compound with the molecular formula C6H12N2S4Zn and CAS number 137-30-4. This chemical substance has a molecular weight of 305.8 g/mol and belongs to the carbamodithioate family. It is classified as a hazardous substance with multiple danger classifications including acute toxicity, eye damage, skin sensitization, and aquatic toxicity, requiring careful handling and appropriate safety measures.

What are the physicochemical properties of zinc bis(N,N-dimethylcarbamodithioate)?

Zinc bis(N,N-dimethylcarbamodithioate) is a solid compound at room temperature with the molecular formula C6H12N2S4Zn. It typically appears as a white to off-white crystalline powder with a characteristic sulfur-like odor. The compound has limited water solubility but may dissolve in organic solvents. Its molecular weight is 305.8 g/mol, and it contains zinc coordinated with two dimethylcarbamodithioate ligands, giving it its distinctive chemical and physical properties.

What is zinc bis(N,N-dimethylcarbamodithioate) used for?

Zinc bis(N,N-dimethylcarbamodithioate) is primarily used as a rubber accelerator in the vulcanization process of rubber and latex products. It serves as an ultra-fast curing agent that enhances the cross-linking of rubber polymers, improving elasticity and durability. The compound is also utilized in the production of rubber gloves, tires, and various industrial rubber components. Additionally, it may be used as an intermediate in chemical synthesis and as a component in specialized industrial applications.

How to handle zinc bis(N,N-dimethylcarbamodithioate) safely?

Zinc bis(N,N-dimethylcarbamodithioate) requires careful handling due to its acute toxicity and skin sensitization properties. Personal protective equipment must include nitrile gloves, safety goggles, and respiratory protection to prevent inhalation. Work should be conducted in well-ventilated areas or under fume hoods. Avoid skin and eye contact, and prevent dust formation during handling. Emergency eyewash stations and safety showers should be readily accessible when working with this substance.

How to store zinc bis(N,N-dimethylcarbamodithioate) correctly?

Zinc bis(N,N-dimethylcarbamodithioate) should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly sealed to prevent moisture absorption and contamination. Store separately from incompatible materials such as strong acids, bases, and oxidizing agents. The storage area should be equipped with appropriate spill containment measures and restricted access. Maintain storage temperatures below 25°C and ensure containers are properly labeled with hazard information.

What to do in case of contact with zinc bis(N,N-dimethylcarbamodithioate)?

Immediate action is required upon contact with zinc bis(N,N-dimethylcarbamodithioate) due to its toxicity and eye damage potential. For skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air and seek medical help if breathing difficulties occur. For ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of zinc bis(N,N-dimethylcarbamodithioate) properly?

Zinc bis(N,N-dimethylcarbamodithioate) must be disposed of as hazardous waste in accordance with local and European regulations. The substance cannot be disposed of in regular waste streams due to its toxicity and environmental hazards. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Contaminated packaging should also be treated as hazardous waste. Ensure proper documentation and tracking of waste disposal activities as required by applicable environmental regulations.

How to transport zinc bis(N,N-dimethylcarbamodithioate)?

Zinc bis(N,N-dimethylcarbamodithioate) is classified under ADR Class 6.1 (toxic substances) with Packing Group II, indicating significant transport restrictions. It requires appropriate UN-specification packaging, proper labeling with GHS pictograms (GHS06, GHS08, GHS05, GHS09), and transport documentation. Vehicles must carry appropriate emergency equipment and drivers need hazardous goods training. The substance must be segregated from incompatible materials during transport and shipped according to dangerous goods regulations.

Is zinc bis(N,N-dimethylcarbamodithioate) subject to specific regulations?

Zinc bis(N,N-dimethylcarbamodithioate) is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification obligations. The substance carries multiple hazard classifications requiring safety data sheets, appropriate labeling, and risk management measures. While not currently listed as an SVHC (Substance of Very High Concern), it requires compliance with occupational exposure limits and environmental protection measures. Companies handling this substance must ensure regulatory compliance and worker protection protocols.

Where to buy zinc bis(N,N-dimethylcarbamodithioate) in Europe?

Zinc bis(N,N-dimethylcarbamodithioate) is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this compound with full regulatory compliance documentation, including safety data sheets and certificates of analysis. As a professional chemical distributor, OYSI ensures proper packaging, labeling, and transport according to ADR regulations. Contact OYSI directly for availability, technical specifications, and regulatory support for your zinc bis(N,N-dimethylcarbamodithioate) requirements across European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.