Triphenylstannanylium hydroxide
C18H16OSn
triphenylstannanylium hydroxide
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Identification
- CAS Number
- 76-87-9
- EC Number
- 200-990-6
- UN Number
- 2786
- Index Number
- 050-004-00-1
- PubChem CID
- 9907219
Physical-chemical properties
- Molecular Formula
- C18H16OSn
- Molar Mass
- 367.00 g/mol
- IUPAC Name
- triphenylstannanylium hydroxide
Chemical Identifiers
- InChI
- InChI=1S/3C6H5.H2O.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H2;/q;;;;+1/p-1
- InChI Key
- BFWMWWXRWVJXSE-UHFFFAOYSA-M
Overview
Triphenylstannanylium hydroxide (CAS 76-87-9) is an organotin compound with significant toxicological properties and specialized industrial applications. This organotin chemical, with the molecular formula C18H16OSn and a molecular weight of 367 g/mol, represents a class of organometallic compounds where tin is covalently bonded to organic groups. The compound consists of three phenyl groups attached to a tin center, along with a hydroxide group, creating a structure that exhibits both organometallic and ionic characteristics. Its classification under multiple hazard categories, including carcinogenicity (Category 2), reproductive toxicity (Category 2), and acute toxicity, reflects the serious safety considerations associated with organotin compounds. The compound's hazard profile is extensive, displaying GHS pictograms for health hazards (GHS08), acute toxicity (GHS06), corrosivity (GHS05), and environmental dangers (GHS09). Its ADR transport classification as Class 6.1 indicates it falls under toxic substances requiring special handling protocols during shipment. The "Danger" signal word emphasizes the need for stringent safety measures during storage, handling, and application. In industrial applications, triphenylstannanylium hydroxide finds use primarily as a catalyst in polymerization reactions, as a biocide in specialized formulations, and in organic synthesis processes where organotin compounds serve as intermediates. Like related compounds such as triphenylstannyl acetate, it belongs to a family of organotin chemicals valued for their catalytic properties, though their use is increasingly regulated due to environmental and health concerns. OYSI maintains availability of triphenylstannanylium hydroxide for qualified industrial customers with appropriate safety handling capabilities and regulatory compliance requirements.
Safety & Classification
Carc. 2; Repr. 2; Acute Tox. 2 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 3; STOT RE 1; Skin Irri...
GHS Pictograms
Health Hazard
GHS08
Serious health hazard. May cause cancer, organ damage, or genetic defects.
Skull and Crossbones
GHS06
Acute toxicity. Fatal if swallowed, in contact with skin, or if inhaled.
Corrosion
GHS05
Corrosive. Causes severe skin burns and eye damage.
Environment
GHS09
Environmental hazard. Toxic to aquatic life with long lasting effects.
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing cancer.
Fatal if inhaled.
Toxic in contact with skin.
Toxic if swallowed.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure.
Causes skin irritation.
Causes serious eye damage.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2786 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Fentinhydroxid (ISO) |
| Marine Pollutant | No |
Frequently Asked Questions
What is triphenylstannanylium hydroxide?
Triphenylstannanylium hydroxide is an organotin compound with the molecular formula C18H16OSn and CAS number 76-87-9. This chemical substance has a molecular weight of 367 g/mol and belongs to the family of triphenyltin derivatives. It is classified as a highly hazardous substance with multiple health risks including carcinogenic and reproductive toxicity properties, requiring strict safety protocols for handling and use in industrial applications.
What are the physicochemical properties of triphenylstannanylium hydroxide?
Triphenylstannanylium hydroxide is an organotin compound that typically appears as a solid at room temperature. The substance contains tin as the central metal atom bonded to three phenyl groups and a hydroxide group. Due to its organotin structure, it exhibits moderate stability under normal conditions but can be sensitive to moisture and heat. Specific physical properties such as exact melting point, color, and solubility characteristics should be verified from technical datasheets for precise handling requirements.
What is triphenylstannanylium hydroxide used for?
Triphenylstannanylium hydroxide is primarily used in specialized industrial applications as an organotin reagent. Its main applications include use as a catalyst in certain organic synthesis reactions, as an intermediate in the production of other organotin compounds, and in specific research applications. Due to its high toxicity profile and regulatory restrictions, its commercial use is limited and typically confined to controlled industrial processes where proper safety measures can be implemented.
How to handle triphenylstannanylium hydroxide safely?
Triphenylstannanylium hydroxide requires extreme caution during handling due to its Acute Tox. 2 and 3 classifications. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas. Work should be conducted in fume hoods to prevent inhalation exposure. Skin and eye contact must be strictly avoided due to its irritating properties. Only trained personnel should handle this substance, following established safety protocols and emergency procedures.
How to store triphenylstannanylium hydroxide correctly?
Triphenylstannanylium hydroxide must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Storage areas should be equipped with appropriate containment measures and restricted access due to its high toxicity. The substance should be kept away from heat sources, moisture, and strong oxidizing agents. Storage facilities must comply with local regulations for toxic substances and include proper labeling with GHS pictograms and hazard warnings.
What to do in case of contact with triphenylstannanylium hydroxide?
Immediate action is critical due to the substance's high acute toxicity. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with water and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheets for specific first aid measures and contact poison control if exposure occurs.
How to dispose of triphenylstannanylium hydroxide appropriately?
Triphenylstannanylium hydroxide must be disposed of as hazardous waste through licensed waste management companies due to its high toxicity and environmental hazard classification (GHS09). Disposal must comply with local and European waste regulations including the Waste Framework Directive. The substance cannot be disposed of through normal waste streams and requires specialized treatment facilities. Proper waste classification codes must be used, and disposal documentation must be maintained for regulatory compliance.
How to transport triphenylstannanylium hydroxide?
Triphenylstannanylium hydroxide is classified under ADR Class 6.1 (toxic substances) Packing Group II, indicating high toxicity requiring strict transport regulations. Transportation must use appropriate UN specification packaging with proper hazard labels and documentation. Only certified dangerous goods transporters can handle shipments, and drivers must have ADR training certification. Transport vehicles require proper placarding and emergency equipment as specified in ADR regulations for Class 6.1 substances.
Is triphenylstannanylium hydroxide subject to specific regulations?
Triphenylstannanylium hydroxide is subject to extensive European regulations including REACH registration requirements and CLP classification showing multiple hazard categories. The substance requires safety data sheets and proper hazard communication due to its Carc. 2 and Repr. 2 classifications. Although not currently listed as SVHC, its high toxicity profile means it may face additional restrictions. Users must comply with occupational exposure limits and workplace safety regulations specific to carcinogenic and reproductive toxic substances.
Where to buy triphenylstannanylium hydroxide in Europe?
Triphenylstannanylium hydroxide is available through OYSI, a specialized European distributor of technical chemicals. Due to its high toxicity and regulatory requirements, this substance is only supplied to qualified industrial users with appropriate safety capabilities and regulatory compliance. OYSI provides proper documentation including safety data sheets and certificates of analysis. Customers must demonstrate legitimate use and proper handling capabilities when requesting quotes for this restricted chemical substance.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.