Triphenylstannanylium hydroxide

C18H16OSn

triphenylstannanylium hydroxide

CAS76-87-9
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
76-87-9
EC Number
200-990-6
UN Number
2786
Index Number
050-004-00-1
PubChem CID
9907219

Physical-chemical properties

Molecular Formula
C18H16OSn
Molar Mass
367.00 g/mol
IUPAC Name
triphenylstannanylium hydroxide

Chemical Identifiers

InChI
InChI=1S/3C6H5.H2O.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H2;/q;;;;+1/p-1
InChI Key
BFWMWWXRWVJXSE-UHFFFAOYSA-M

Overview

Triphenylstannanylium hydroxide (CAS 76-87-9) is an organotin compound with significant toxicity and multiple industrial applications requiring careful handling protocols. This organotin chemical represents a critical component in various industrial processes, characterized by its molecular formula C18H16OSn and molecular weight of 367 g/mol. The compound belongs to the triphenyltin family, which includes related substances such as triphenylstannyl acetate, sharing similar structural characteristics and applications in chemical manufacturing. As an organotin derivative, triphenylstannanylium hydroxide exhibits the typical properties associated with tin-carbon bonds, making it valuable for specific catalytic and synthetic applications. The safety profile of this substance demands particular attention, as indicated by its classification under multiple hazard categories including carcinogenicity (Category 2), reproductive toxicity (Category 2), and acute toxicity with various exposure routes. The presence of GHS pictograms GHS08, GHS06, GHS05, and GHS09 emphasizes the need for comprehensive safety measures during handling, storage, and transportation. Its ADR classification as Class 6.1 further reinforces the toxic nature requiring specialized logistics protocols. Primary industrial applications include its use as a catalyst in polymerization reactions, as an intermediate in organometallic synthesis, and in specialized coating formulations where its unique chemical properties provide specific performance benefits. The compound also finds application in research and development settings for advanced material synthesis. OYSI maintains professional-grade triphenylstannanylium hydroxide in compliance with European chemical distribution standards, ensuring proper documentation and safety protocols for qualified industrial customers requiring this specialized organotin compound.

Safety & Classification

Danger
Classification:

Carc. 2; Repr. 2; Acute Tox. 2 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 3; STOT RE 1; Skin Irri...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H330

Fatal if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H335

May cause respiratory irritation.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2786
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameFentinhydroxid (ISO)
Marine PollutantNo

Frequently Asked Questions

What is triphenylstannanylium hydroxide?

Triphenylstannanylium hydroxide is an organotin compound with the molecular formula C18H16OSn and CAS number 76-87-9. This chemical substance has a molecular weight of 367 g/mol and belongs to the family of organometallic compounds containing tin. It is classified as a highly hazardous substance with multiple health risks including carcinogenic and reproductive toxicity properties, requiring strict safety measures during handling and use.

What are the physicochemical properties of triphenylstannanylium hydroxide?

Triphenylstannanylium hydroxide is an organotin compound that typically appears as a solid at room temperature. Due to its organometallic nature containing tin and phenyl groups, it exhibits specific chemical reactivity patterns. The compound has a molecular weight of 367 g/mol and contains both organic aromatic components and a tin-oxygen bond, which influences its stability and reactivity characteristics in various chemical environments.

What is triphenylstannanylium hydroxide used for?

Triphenylstannanylium hydroxide is primarily used as a specialized reagent in organic synthesis and chemical research applications. Its organotin structure makes it valuable in certain catalytic processes and as an intermediate in the preparation of other organotin compounds. Due to its high toxicity profile, its use is typically restricted to controlled laboratory environments and specific industrial applications where proper safety protocols can be maintained.

How to handle triphenylstannanylium hydroxide safely?

Triphenylstannanylium hydroxide must be handled with extreme caution due to its high toxicity classification (Acute Tox. 2-3). Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in a well-ventilated area or fume hood to prevent inhalation exposure. Avoid skin contact and ingestion. Follow strict hygiene protocols including thorough hand washing after handling, even when wearing gloves.

How to store triphenylstannanylium hydroxide correctly?

Triphenylstannanylium hydroxide should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Due to its organotin nature, protect from moisture and air exposure which may cause degradation. Store separately from food, beverages, and animal feed. Ensure storage area is equipped with appropriate spill containment measures and access is restricted to authorized personnel only.

What to do in case of contact with triphenylstannanylium hydroxide?

Immediate action is required for any contact with triphenylstannanylium hydroxide due to its high acute toxicity. For skin contact, immediately remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. For eye contact, rinse thoroughly with water for at least 15 minutes. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting. Seek immediate medical attention in all cases.

How to dispose of triphenylstannanylium hydroxide appropriately?

Triphenylstannanylium hydroxide must be disposed of as hazardous waste according to local, national, and European regulations. Contact licensed hazardous waste disposal companies for proper treatment. Never dispose of this substance through regular waste streams, sewers, or water systems due to its high toxicity and environmental persistence. Ensure all contaminated materials including containers, protective equipment, and cleaning materials are also treated as hazardous waste.

How to transport triphenylstannanylium hydroxide?

Triphenylstannanylium hydroxide is classified under ADR Class 6.1 (toxic substances), Packing Group II, indicating high toxicity requiring special transport precautions. Transportation must comply with dangerous goods regulations including proper packaging, labeling with appropriate hazard pictogrammes (GHS06, GHS08, GHS05, GHS09), and documentation. Only trained personnel and certified carriers should handle transportation. Emergency response information must accompany all shipments.

Is triphenylstannanylium hydroxide subject to specific regulations?

Triphenylstannanylium hydroxide is subject to strict European regulations including REACH registration requirements and CLP classification as a Category 2 carcinogen and reproductive toxicant. While not currently listed as an SVHC (Substance of Very High Concern), its hazard profile requires compliance with occupational exposure limits, worker protection measures, and environmental release controls. Users must maintain safety data sheets and implement appropriate risk management measures.

Where to buy triphenylstannanylium hydroxide in Europe?

Triphenylstannanylium hydroxide is available through OYSI, a specialized European distributor of chemical products. As a professional chemical supplier, OYSI can provide this highly regulated substance to qualified industrial and research customers with proper documentation and safety requirements. Due to the substance's high toxicity classification, purchase is typically restricted to legitimate industrial users with appropriate handling capabilities and regulatory compliance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.