Dibutyl(dichloro)stannane

C8H18Cl2Sn

dibutyl(dichloro)stannane

CAS683-18-1
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
683-18-1
EC Number
279-116-0
UN Number
2928
Index Number
050-022-00-X
PubChem CID
12688

Physical-chemical properties

Molecular Formula
C8H18Cl2Sn
Molar Mass
303.84 g/mol
IUPAC Name
dibutyl(dichloro)stannane

Chemical Identifiers

InChI
InChI=1S/2C4H9.2ClH.Sn/c2*1-3-4-2;;;/h2*1,3-4H2,2H3;2*1H;/q;;;;+2/p-2
InChI Key
RJGHQTVXGKYATR-UHFFFAOYSA-L

Overview

Dibutyl(dichloro)stannane (CAS 683-18-1) is an organotin compound with significant toxicity and corrosive properties, classified as a dangerous chemical requiring strict handling protocols. This organotin chemical, also known by its IUPAC name dibutyl(dichloro)stannane, represents a critical intermediate in various industrial processes where tin-based chemistry is essential. With a molecular formula of C8H18Cl2Sn and molecular weight of 303.84 g/mol, this compound exhibits the characteristic properties of organotin derivatives, combining organic butyl groups with inorganic tin-chlorine bonds. The substance carries EC number 279-116-0 and is subject to stringent regulatory oversight due to its hazard profile. The compound's safety classification reflects its serious health and environmental risks. Classified as Muta. 2, Repr. 1B, and Acute Tox. 2-4 depending on exposure route, dibutyl(dichloro)stannane requires extreme caution during handling and storage. The substance exhibits skin corrosive properties (Skin Corr. 1B) and specific target organ toxicity (STOT RE 1), necessitating comprehensive personal protective equipment and engineered controls. Its ADR classification of 6.1 designates it as a toxic substance for transportation purposes, while GHS pictograms GHS08, GHS06, GHS05, and GHS09 clearly communicate its multiple hazards. Industrial applications of dibutyl(dichloro)stannane primarily focus on its role as a catalyst and chemical intermediate in polymer production and organic synthesis. The compound serves as a precursor for other organotin compounds and finds application in specialized chemical manufacturing processes. Unlike simpler halogenated compounds such as 2-chloroacetaldehyde, organotin derivatives offer unique catalytic properties that make them valuable despite their hazardous nature. OYSI maintains availability of dibutyl(dichloro)stannane for qualified industrial customers with appropriate handling capabilities and regulatory compliance frameworks.

Safety & Classification

Danger
Classification:

Muta. 2; Repr. 1B; Acute Tox. 2 *; Acute Tox. 4 *; Acute Tox. 3 *; STOT RE 1; Skin Corr. 1B; Aqua...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H330

Fatal if inhaled.

H312

Harmful in contact with skin.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2928
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameDibutylzinndichlorid, fest
Marine PollutantNo

Frequently Asked Questions

What is dibutyl(dichloro)stannane?

Dibutyl(dichloro)stannane is an organotin compound with the molecular formula C8H18Cl2Sn and CAS number 683-18-1. This chemical substance has a molecular weight of 303.84 g/mol and belongs to the class of dialkyltin dichlorides. It is classified as highly hazardous with multiple danger classifications including mutagenicity, reproductive toxicity, and acute toxicity. The compound requires careful handling due to its significant health and environmental risks.

What are the physicochemical properties of dibutyl(dichloro)stannane?

Dibutyl(dichloro)stannane is typically a colorless to pale yellow liquid at room temperature with a characteristic organotin odor. The compound has limited solubility in water but dissolves well in organic solvents such as alcohols and hydrocarbons. It is sensitive to moisture and can hydrolyze in the presence of water, forming corresponding tin oxides and hydrochloric acid. The substance should be protected from light and stored under inert conditions.

What is dibutyl(dichloro)stannane used for?

Dibutyl(dichloro)stannane is primarily used as an intermediate in the synthesis of other organotin compounds and as a catalyst in various chemical reactions. It serves as a precursor for producing dibutyltin-based stabilizers used in PVC processing and other polymer applications. The compound is also utilized in organic synthesis reactions, particularly in cross-coupling reactions and as a Lewis acid catalyst in specialized industrial processes requiring tin-based chemistry.

How to handle dibutyl(dichloro)stannane safely?

Dibutyl(dichloro)stannane requires extensive personal protective equipment including chemical-resistant gloves, safety goggles, face shield, and respiratory protection. Work must be conducted in a well-ventilated area or under fume hood due to its acute toxicity and corrosive properties. Avoid skin contact, inhalation, and ingestion completely. Use appropriate chemical-resistant clothing and ensure emergency shower and eyewash stations are readily accessible. Only trained personnel should handle this substance.

How to store dibutyl(dichloro)stannane correctly?

Dibutyl(dichloro)stannane must be stored in tightly sealed, chemically compatible containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers away from moisture, strong bases, and oxidizing agents to prevent dangerous reactions. Storage areas should be equipped with appropriate containment systems and restricted to authorized personnel only. Maintain storage temperatures as recommended by the manufacturer and ensure proper labeling.

What to do in case of contact with dibutyl(dichloro)stannane?

Dibutyl(dichloro)stannane contact requires immediate emergency response due to its corrosive and toxic nature. For skin contact, immediately remove contaminated clothing and flush with copious amounts of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water for at least 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek immediate medical attention for all exposure routes and provide safety data sheet to medical personnel.

How to dispose of dibutyl(dichloro)stannane properly?

Dibutyl(dichloro)stannane disposal must comply with local, national, and EU hazardous waste regulations due to its classification as dangerous substance. The waste should be collected in appropriate containers and disposed of through licensed hazardous waste disposal companies. Incineration at high temperatures in specialized facilities is typically required. Never dispose of this substance through normal waste streams, sewerage systems, or by pouring onto the ground. Consult local environmental authorities for specific disposal requirements.

How to transport dibutyl(dichloro)stannane?

Dibutyl(dichloro)stannane is classified under ADR Class 6.1 (Toxic substances) Packing Group II, requiring specialized dangerous goods transportation procedures. Packages must comply with ADR packaging instructions and bear appropriate hazard labels and markings. Transportation requires proper documentation, trained drivers with ADR certification, and emergency response information. Vehicles must be equipped with appropriate safety equipment and follow designated dangerous goods routes according to European transport regulations.

Is dibutyl(dichloro)stannane subject to particular regulations?

Dibutyl(dichloro)stannane is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification obligations. As a reproductive toxin Category 1B and mutagen Category 2, it faces strict handling and use restrictions. The substance requires safety data sheets, proper labeling with danger pictograms (GHS05, GHS06, GHS08, GHS09), and compliance with occupational exposure limits. Users must implement risk management measures and report downstream use according to REACH requirements.

Where to buy dibutyl(dichloro)stannane in Europe?

Dibutyl(dichloro)stannane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. As a regulated dangerous substance, it requires proper authorization and qualification verification before purchase. OYSI provides comprehensive technical support, regulatory compliance documentation, and safe packaging solutions. Contact OYSI directly to discuss availability, technical specifications, regulatory requirements, and delivery options for your specific industrial application needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.