Dibutyl(dichloro)stannane

C8H18Cl2Sn

dibutyl(dichloro)stannane

CAS683-18-1
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
683-18-1
EC Number
279-116-0
UN Number
2928
Index Number
050-022-00-X
PubChem CID
12688

Physical-chemical properties

Molecular Formula
C8H18Cl2Sn
Molar Mass
303.84 g/mol
IUPAC Name
dibutyl(dichloro)stannane

Chemical Identifiers

InChI
InChI=1S/2C4H9.2ClH.Sn/c2*1-3-4-2;;;/h2*1,3-4H2,2H3;2*1H;/q;;;;+2/p-2
InChI Key
RJGHQTVXGKYATR-UHFFFAOYSA-L

Overview

Dibutyl(dichloro)stannane (CAS 683-18-1) is an organotin compound with potent catalytic properties and significant toxicological hazards. This organotin chemical serves as a versatile intermediate and catalyst in various industrial applications, though its use requires stringent safety protocols due to its classification under multiple hazard categories. The compound features a tin center bonded to two butyl groups and two chlorine atoms, giving it unique reactivity patterns that make it valuable in specialized chemical processes. With a molecular weight of 303.84 g/mol and the molecular formula C8H18Cl2Sn, dibutyl(dichloro)stannane exhibits the characteristic properties of organotin compounds, including high reactivity and potential for bioaccumulation. The substance carries severe safety warnings with GHS pictograms indicating acute toxicity, corrosivity, mutagenicity, and environmental hazards. Its classification as Reproductive Category 1B and Mutagenic Category 2 necessitates extreme caution during handling and storage. The compound is classified under ADR transport class 6.1, reflecting its toxic nature. Unlike simpler compounds such as 2-chloroacetaldehyde, organotin derivatives like dibutyl(dichloro)stannane require specialized containment and disposal procedures due to their persistent environmental impact. Primary industrial applications include use as a catalyst in polyurethane synthesis, as an intermediate in organotin compound production, and in specialized coating formulations where its catalytic properties enhance cross-linking reactions. The compound also finds application in certain polymer stabilization processes, though environmental concerns have limited its broader commercial use. OYSI maintains availability of dibutyl(dichloro)stannane for qualified industrial customers with appropriate handling capabilities and regulatory compliance frameworks.

Safety & Classification

Danger
Classification:

Muta. 2; Repr. 1B; Acute Tox. 2 *; Acute Tox. 4 *; Acute Tox. 3 *; STOT RE 1; Skin Corr. 1B; Aqua...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H330

Fatal if inhaled.

H312

Harmful in contact with skin.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2928
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameDibutylzinndichlorid, fest
Marine PollutantNo

Frequently Asked Questions

What is dibutyl(dichloro)stannane?

Dibutyl(dichloro)stannane is an organotin compound with the molecular formula C8H18Cl2Sn and CAS number 683-18-1. This chemical substance has a molecular weight of 303.84 g/mol and belongs to the family of dialkyltin dichlorides. It is classified as a highly hazardous material with multiple danger classifications including mutagenic, reproductive toxic, and acutely toxic properties. The compound requires careful handling due to its significant health and environmental risks.

What are the physicochemical properties of dibutyl(dichloro)stannane?

Dibutyl(dichloro)stannane is typically a colorless to pale yellow liquid at room temperature with a characteristic organotin odor. The compound has a molecular weight of 303.84 g/mol and contains tin as its central metal atom bonded to two butyl groups and two chlorine atoms. It is generally insoluble in water but soluble in organic solvents. The substance is sensitive to moisture and can hydrolyze in the presence of water, forming corrosive byproducts.

What is dibutyl(dichloro)stannane used for?

Dibutyl(dichloro)stannane is primarily used as an intermediate in the synthesis of other organotin compounds and as a catalyst in various chemical reactions. It serves as a precursor for producing dibutyltin-based stabilizers used in PVC processing and other polymer applications. The compound is also utilized in specialized chemical synthesis processes within the pharmaceutical and fine chemical industries, where its unique reactivity properties are valuable for specific transformations.

How to handle dibutyl(dichloro)stannane safely?

Dibutyl(dichloro)stannane requires extensive personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection due to its acute toxicity. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Given its skin corrosive properties (Skin Corr. 1B), avoid all direct contact with skin and eyes. Handle containers carefully to prevent spills and ensure proper grounding to prevent static electricity buildup during transfer operations.

How to store dibutyl(dichloro)stannane correctly?

Dibutyl(dichloro)stannane should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers away from moisture as the compound can hydrolyze and form corrosive products. Store separately from oxidizing agents, strong bases, and food products. Ensure storage areas have appropriate spill containment measures and emergency equipment. Regular inspection of containers for signs of corrosion or leakage is essential for safe storage.

What to do in case of contact with dibutyl(dichloro)stannane?

Dibutyl(dichloro)stannane contact requires immediate emergency response due to its corrosive and toxic nature. For skin contact, immediately remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician after any exposure.

How to dispose of dibutyl(dichloro)stannane properly?

Dibutyl(dichloro)stannane disposal must comply with local and national hazardous waste regulations due to its toxic and environmental hazard classification. The substance cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal facilities. Containers should not be emptied or cleaned without proper authorization. Incineration at high temperatures in specialized facilities is typically the preferred disposal method. Always consult local environmental authorities for specific disposal requirements and approved facilities.

How to transport dibutyl(dichloro)stannane?

Dibutyl(dichloro)stannane is classified under ADR Class 6.1 (toxic substances), Packing Group II, indicating high toxicity during transport. Specialized packaging meeting UN specification requirements is mandatory, and vehicles must display appropriate hazard placards and carry emergency response documentation. Drivers require ADR certification for toxic substance transport. Shipping documentation must include proper shipping names, hazard classes, and emergency contact information. Transport should avoid extreme temperatures and ensure secure packaging to prevent leaks.

Is dibutyl(dichloro)stannane subject to specific regulations?

Dibutyl(dichloro)stannane is subject to extensive European chemical regulations under REACH and CLP due to its hazardous properties including mutagenicity (Muta. 2) and reproductive toxicity (Repr. 1B). The substance requires safety data sheets and hazard labeling with GHS pictograms GHS08, GHS06, GHS05, and GHS09. While not currently listed as an SVHC, its toxic properties mean it may face restrictions or authorization requirements. Users must comply with occupational exposure limits and environmental discharge restrictions under various national legislations.

Where to buy dibutyl(dichloro)stannane in Europe?

Dibutyl(dichloro)stannane is available through OYSI, a specialized European distributor of technical chemicals and hazardous substances. As an established chemical distributor, OYSI can provide proper documentation, safety data sheets, and regulatory compliance support required for this highly regulated substance. Due to the compound's classification as toxic and hazardous, purchases typically require verification of legitimate industrial use and appropriate handling capabilities. Contact OYSI directly for availability, specifications, and regulatory guidance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.