Tributyl(chloro)stannane

C12H27ClSn

tributyl(chloro)stannane

CAS1461-22-9
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
1461-22-9
EC Number
215-958-7
UN Number
2788
Index Number
050-008-00-3
PubChem CID
15096

Physical-chemical properties

Molecular Formula
C12H27ClSn
Molar Mass
325.50 g/mol
IUPAC Name
tributyl(chloro)stannane

Chemical Identifiers

InChI
InChI=1S/3C4H9.ClH.Sn/c3*1-3-4-2;;/h3*1,3-4H2,2H3;1H;/q;;;;+1/p-1
InChI Key
GCTFWCDSFPMHHS-UHFFFAOYSA-M

Overview

Tributyl(chloro)stannane (CAS 1461-22-9) is an organotin compound with significant industrial applications and notable toxicological properties requiring careful handling protocols. This organometallic compound, also known by its IUPAC name tributyl(chloro)stannane, represents a key member of the organotin family used extensively in industrial chemistry. With a molecular formula of C12H27ClSn and molecular weight of 325.5 g/mol, this tin-based compound exhibits unique chemical properties that make it valuable for specialized applications while requiring stringent safety measures due to its hazardous classification. The compound is classified under multiple danger categories, including reproductive toxicity (Repr. 1B), acute toxicity, and specific target organ toxicity with repeated exposure (STOT RE 1). Its GHS08, GHS06, and GHS09 pictograms indicate serious health hazards, acute toxicity, and environmental dangers respectively. The ADR classification 6.1 further emphasizes its toxic nature, necessitating specialized transport and storage conditions. Like other organometallic compounds such as dichlorocadmium, tributyl(chloro)stannane requires expert handling due to its potential for bioaccumulation and environmental persistence. Primary industrial applications include its use as a catalyst in polymerization reactions, as an intermediate in the synthesis of other organotin compounds, and in specialized coating formulations where its unique chemical properties provide enhanced performance characteristics. The compound's reactivity profile makes it particularly valuable in applications requiring controlled tin incorporation into organic matrices. OYSI maintains reliable supply chains for tributyl(chloro)stannane, ensuring consistent availability for qualified industrial customers who demonstrate appropriate handling capabilities and regulatory compliance for this controlled substance.

Safety & Classification

Danger
Classification:

Repr. 1B; Acute Tox. 4 *; Acute Tox. 3; STOT RE 1; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; ...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2788
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameTributylzinnchlorid
Marine PollutantNo

Frequently Asked Questions

What is tributyl(chloro)stannane?

Tributyl(chloro)stannane is an organotin compound with the molecular formula C12H27ClSn and CAS number 1461-22-9. This chemical substance has a molecular weight of 325.5 g/mol and belongs to the family of chlorostannanes. It is classified as a highly hazardous substance with reproductive toxicity, acute toxicity, and specific target organ toxicity properties. The compound requires careful handling due to its significant health and environmental risks.

What are the physicochemical properties of tributyl(chloro)stannane?

Tributyl(chloro)stannane is typically a colorless to pale yellow liquid at room temperature with a characteristic organotin odor. The compound is sensitive to moisture and may hydrolyze in the presence of water. It has limited solubility in water but is generally soluble in organic solvents such as alcohols, ethers, and hydrocarbons. The substance should be protected from air and moisture during storage and handling.

What is tributyl(chloro)stannane used for?

Tributyl(chloro)stannane is primarily used as an intermediate in organic synthesis and as a reagent in organometallic chemistry. It serves as a precursor for the preparation of other organotin compounds and is utilized in various catalytic processes. The compound finds applications in polymer chemistry, particularly in the synthesis of specialized materials. Its use is restricted to professional and industrial applications due to its hazardous nature.

How to handle tributyl(chloro)stannane safely?

Tributyl(chloro)stannane must be handled with extreme caution using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin and eye contact completely. Personnel should be trained in proper handling procedures and emergency response. Never eat, drink, or smoke while handling this substance, and wash hands thoroughly after use.

How to store tributyl(chloro)stannane correctly?

Tributyl(chloro)stannane should be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from heat sources and incompatible materials. Keep containers protected from moisture and air exposure. Store away from oxidizing agents, acids, and bases. The storage area should be equipped with appropriate containment measures and emergency equipment. Maintain proper labeling and ensure access is restricted to trained personnel only.

What to do in case of contact with tributyl(chloro)stannane?

Immediate medical attention is required for any exposure to tributyl(chloro)stannane. In case of skin contact, remove contaminated clothing and wash the affected area with plenty of soap and water. For eye contact, rinse immediately with clean water for at least 15 minutes and seek medical care. If inhaled, move the person to fresh air and monitor breathing. If ingested, do not induce vomiting and seek immediate medical attention.

How to dispose of tributyl(chloro)stannane appropriately?

Tributyl(chloro)stannane must be disposed of as hazardous waste through licensed waste management companies in accordance with local and EU regulations. The substance cannot be discharged into sewers, water bodies, or regular waste streams due to its toxic and environmentally harmful properties. Waste containers should be properly labeled and sealed. Consult local environmental authorities for specific disposal requirements and approved disposal facilities in your region.

How to transport tributyl(chloro)stannane?

Tributyl(chloro)stannane is classified under ADR Class 6.1 (toxic substances), Packing Group III for transportation purposes. Packages must be properly labeled with appropriate hazard labels and shipping documentation. Transport should be conducted by qualified carriers familiar with dangerous goods regulations. Vehicles must be equipped with appropriate safety equipment and emergency response materials. Ensure compliance with international transport regulations including IMDG for sea transport and IATA for air transport.

Is tributyl(chloro)stannane subject to specific regulations?

Tributyl(chloro)stannane is subject to strict regulatory controls under EU REACH and CLP regulations due to its classification as Repr. 1B and other serious health hazards. The substance requires safety data sheets and appropriate hazard communication. While not currently listed as SVHC, it may be subject to authorization or restriction measures. Users must comply with occupational exposure limits and environmental discharge restrictions. Consult current regulatory databases for the latest requirements.

Where to buy tributyl(chloro)stannane in Europe?

Tributyl(chloro)stannane is available through OYSI, a European distributor of specialty chemicals serving industrial and research customers. As a controlled substance, purchases require proper documentation and qualification as a professional user. OYSI provides technical support and regulatory compliance assistance to ensure safe handling and legal use. Contact OYSI directly to discuss availability, packaging options, and delivery arrangements for your specific requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.