Sodium 2,3,4,5,6-pentachlorophenolate

C6Cl5NaO

sodium 2,3,4,5,6-pentachlorophenolate

CAS131-52-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
131-52-2
EC Number
205-025-2
UN Number
2567
Index Number
604-003-00-3
PubChem CID
23663539

Physical-chemical properties

Molecular Formula
C6Cl5NaO
Molar Mass
288.30 g/mol
IUPAC Name
sodium 2,3,4,5,6-pentachlorophenolate

Chemical Identifiers

InChI
InChI=1S/C6HCl5O.Na/c7-1-2(8)4(10)6(12)5(11)3(1)9;/h12H;/q;+1/p-1
InChI Key
HCJLVWUMMKIQIM-UHFFFAOYSA-M

Overview

Sodium 2,3,4,5,6-pentachlorophenolate (CAS 131-52-2) is a highly chlorinated phenolic sodium salt with potent biocidal and antimicrobial properties. This organochlorine compound represents the sodium salt form of pentachlorophenol, one of the most heavily chlorinated phenolic compounds used in industrial applications. With its molecular formula C6Cl5NaO and molecular weight of 288.3 g/mol, sodium pentachlorophenolate exhibits enhanced water solubility compared to its parent compound 2,3,4,5,6-pentachlorophenol, making it particularly valuable for aqueous-based formulations and treatments. The extensive chlorination pattern of this compound confers exceptional resistance to microbial degradation and provides broad-spectrum antimicrobial activity. However, these same characteristics contribute to its significant toxicological profile, as evidenced by its classification under multiple hazard categories including carcinogenicity (Category 2), acute toxicity, and environmental hazard classifications. The compound requires careful handling protocols due to its GHS08, GHS06, and GHS09 pictogram classifications and ADR Class 6.1 designation for toxic substances. Industrial applications of sodium pentachlorophenolate primarily focus on wood preservation systems, where its fungicidal and insecticidal properties provide long-term protection against biological deterioration. The compound also finds specialized use in industrial water treatment applications and as an intermediate in organic synthesis processes. Its enhanced solubility profile compared to related phenolic compounds makes it particularly suitable for liquid formulation systems. Due to increasing regulatory restrictions on chlorinated phenolic compounds, applications are becoming more specialized and regulated. OYSI maintains technical expertise and supply capabilities for sodium 2,3,4,5,6-pentachlorophenolate to serve qualified industrial customers with appropriate handling and application requirements.

Safety & Classification

Danger
Classification:

Carc. 2; Acute Tox. 2 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; ...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H330

Fatal if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2567
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameNatriumpentachlorphenolat
Marine PollutantNo

Frequently Asked Questions

What is sodium 2,3,4,5,6-pentachlorophenolate?

Sodium 2,3,4,5,6-pentachlorophenolate is the sodium salt of pentachlorophenol, a highly chlorinated phenolic compound with the chemical formula C6Cl5NaO. This white to light-colored crystalline substance has a molecular weight of 288.3 g/mol and is classified as a hazardous chemical with multiple health and environmental risks. It is primarily used as a biocide and wood preservative, though its applications have become increasingly restricted due to safety concerns.

What are the physicochemical properties of sodium 2,3,4,5,6-pentachlorophenolate?

Sodium 2,3,4,5,6-pentachlorophenolate appears as a white to light-colored crystalline powder or granular solid at room temperature. The compound is moderately soluble in water due to its ionic nature, forming alkaline solutions. It has a characteristic phenolic odor and is stable under normal conditions but may decompose when heated, releasing toxic chlorinated compounds and other hazardous decomposition products.

What is sodium 2,3,4,5,6-pentachlorophenolate used for?

Sodium 2,3,4,5,6-pentachlorophenolate is primarily used as a wood preservative and biocide in industrial applications. It serves as an effective fungicide and bactericide for treating timber and wooden structures. The compound may also be used in certain specialized industrial processes as an antimicrobial agent. However, its use has been significantly restricted or banned in many applications due to health and environmental concerns, particularly its potential carcinogenic properties.

How to handle sodium 2,3,4,5,6-pentachlorophenolate safely?

Sodium 2,3,4,5,6-pentachlorophenolate must be handled with extreme caution due to its high toxicity and carcinogenic potential. Personnel should wear appropriate PPE including chemical-resistant gloves, protective clothing, eye protection, and respiratory protection. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid skin and eye contact, inhalation, and ingestion. Implement strict hygiene measures and ensure proper training for all handling personnel.

How to store sodium 2,3,4,5,6-pentachlorophenolate correctly?

Sodium 2,3,4,5,6-pentachlorophenolate should be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and incompatible materials. Keep containers tightly sealed and in original packaging. Store separately from food, feed, and drinking water. The storage area should be secured with restricted access and appropriate warning signage. Ensure proper containment measures are in place to prevent environmental contamination in case of spills.

What to do in case of contact with sodium 2,3,4,5,6-pentachlorophenolate?

In case of skin contact with sodium 2,3,4,5,6-pentachlorophenolate, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for 15-20 minutes. If inhaled, move the person to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician and provide the safety data sheet.

How to dispose of sodium 2,3,4,5,6-pentachlorophenolate properly?

Sodium 2,3,4,5,6-pentachlorophenolate must be disposed of as hazardous waste through licensed waste management companies specialized in handling toxic chemicals. The substance cannot be disposed of in regular waste streams or sewage systems. Disposal must comply with local, national, and EU waste regulations. Contaminated packaging should also be treated as hazardous waste. Consult local environmental authorities for specific disposal requirements and authorized waste treatment facilities in your region.

How to transport sodium 2,3,4,5,6-pentachlorophenolate?

Sodium 2,3,4,5,6-pentachlorophenolate is classified as ADR Class 6.1 (toxic substances), Packing Group II, indicating high toxicity requiring strict transport regulations. Transportation must comply with ADR/RID requirements including proper packaging, labeling with appropriate hazard labels, and documentation. Only authorized carriers trained in hazardous materials transport should handle shipments. The substance requires specific packaging specifications and emergency response information during transport.

Is sodium 2,3,4,5,6-pentachlorophenolate subject to specific regulations?

Sodium 2,3,4,5,6-pentachlorophenolate is subject to strict regulations under REACH, CLP, and other EU chemical legislation due to its hazardous properties. The substance is classified as Category 2 carcinogen and highly toxic, requiring compliance with notification, authorization, and restriction procedures. Users must follow occupational exposure limits, implement risk management measures, and maintain detailed records. Some applications may be restricted or prohibited depending on local regulations.

Where to buy sodium 2,3,4,5,6-pentachlorophenolate in Europe?

Sodium 2,3,4,5,6-pentachlorophenolate can be purchased from OYSI, a specialized European distributor of technical chemicals. As this substance is highly regulated and restricted, procurement requires proper documentation, end-use declarations, and compliance with applicable regulations. OYSI provides technical support and regulatory guidance to ensure compliant purchasing and handling. Contact OYSI directly for availability, specifications, and regulatory requirements for your specific application and location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.