Sulfuryl difluoride

F2O2S

sulfuryl difluoride

CAS2699-79-8
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
2699-79-8
EC Number
220-281-5
UN Number
2191
Index Number
009-015-00-7
PubChem CID
17607

Physical-chemical properties

Molecular Formula
F2O2S
Molar Mass
102.06 g/mol
IUPAC Name
sulfuryl difluoride

Chemical Identifiers

InChI
InChI=1S/F2O2S/c1-5(2,3)4
InChI Key
OBTWBSRJZRCYQV-UHFFFAOYSA-N

Overview

Sulfuryl difluoride (CAS 2699-79-8) is an inorganic sulfur compound with fumigant properties and high toxicity requiring specialized handling protocols. This colorless, odorless gas represents a critical fumigant in industrial pest control applications, distinguished by its molecular formula F2O2S and molecular weight of 102.06 g/mol. The compound's structure features a sulfur atom bonded to two fluorine atoms and two oxygen atoms, creating a highly reactive gas that penetrates effectively through various materials. Unlike traditional fumigants such as bromomethane, sulfuryl difluoride offers distinct advantages in terms of material compatibility and residue characteristics, making it particularly valuable in specialized fumigation applications. The substance carries significant safety considerations, classified under GHS hazard classes including acute toxicity (category 3), specific target organ toxicity following repeated exposure, and aquatic environmental hazards. Its classification as a pressurized gas under ADR class 2 requires appropriate transport protocols and specialized storage equipment. The multiple GHS pictograms (GHS04, GHS06, GHS08, GHS09) reflect its comprehensive hazard profile encompassing physical, health, and environmental risks. Primary industrial applications include structural fumigation for pest control in buildings, commodity treatment in storage facilities, and specialized applications in quarantine treatments. The compound's penetrating properties and broad-spectrum efficacy make it particularly suitable for treating large volumes and complex structures where traditional fumigants may prove insufficient. OYSI maintains availability of sulfuryl difluoride for qualified industrial customers, ensuring proper regulatory compliance and technical support for safe handling procedures.

Safety & Classification

Danger
Classification:

Press. Gas; Acute Tox. 3 *; STOT RE 2 *; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H331

Toxic if inhaled.

H373

May cause damage to organs through prolonged or repeated exposure.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2191
ADR Class2
Packing Group
Tunnel CodeC/D
Proper Shipping NameSulfurylfluorid, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is sulfuryl difluoride?

Sulfuryl difluoride is an inorganic gas compound with the molecular formula F2O2S and CAS number 2699-79-8. It has a molecular weight of 102.06 g/mol and exists as a pressurized gas under normal conditions. This colorless, odorless gas is classified as acutely toxic and poses risks to specific target organs with repeated exposure. Due to its unique chemical properties, it serves as an important industrial chemical in various specialized applications requiring fluorine-containing compounds.

What are the physicochemical properties of sulfuryl difluoride?

Sulfuryl difluoride is a colorless, odorless gas at room temperature and atmospheric pressure. It has a molecular weight of 102.06 g/mol and contains two fluorine atoms bonded to a sulfur dioxide core. The compound is typically stored and handled under pressure as indicated by its classification as a pressurized gas. Its chemical structure makes it relatively stable under normal conditions, though it requires careful handling due to its toxic properties and potential environmental impact on aquatic systems.

What is sulfuryl difluoride used for?

Sulfuryl difluoride is primarily used as a fumigant for pest control in various industries, particularly for treating stored products, buildings, and shipping containers. It serves as an effective alternative to methyl bromide in structural fumigation applications. The compound is also utilized in specialized chemical synthesis processes where fluorine incorporation is required. Its gaseous nature and penetrating properties make it valuable for treating commodities and materials that require deep penetration for complete pest elimination while leaving minimal residues.

How to handle sulfuryl difluoride safely?

Sulfuryl difluoride requires strict safety protocols due to its acute toxicity and pressurized gas classification. Personnel must wear appropriate respiratory protection, chemical-resistant gloves, and protective clothing when handling this substance. Work areas should have adequate ventilation and gas detection systems. Emergency shower and eyewash facilities must be readily accessible. Only trained personnel should handle this material, and exposure monitoring is essential. The 'Danger' signal word and associated GHS pictograms (GHS04, GHS06, GHS08, GHS09) emphasize the serious safety precautions required.

How to store sulfuryl difluoride correctly?

Sulfuryl difluoride must be stored in appropriate pressure vessels designed for compressed gases in cool, well-ventilated areas away from heat sources and ignition points. Storage areas should be segregated from incompatible materials and equipped with gas leak detection systems. Cylinders must be secured upright and protected from physical damage. Temperature control is crucial to prevent excessive pressure buildup. Access should be restricted to authorized personnel only, and emergency response equipment must be readily available in storage areas.

What to do in case of contact with sulfuryl difluoride?

Sulfuryl difluoride exposure requires immediate emergency response due to its acute toxicity classification. In case of inhalation, move the person to fresh air immediately and seek medical attention. For skin or eye contact, flush thoroughly with water for at least 15 minutes and remove contaminated clothing. Do not induce vomiting if ingested. Contact emergency medical services immediately for any exposure. Evacuate the area if there's a gas leak and ensure proper ventilation. Always consult the safety data sheet for specific first aid measures and contact poison control centers when necessary.

How to dispose of sulfuryl difluoride appropriately?

Sulfuryl difluoride disposal must comply with local, national, and international environmental regulations due to its classification as aquatic acute toxic. Empty cylinders should be returned to the supplier or a licensed gas cylinder recycling facility. Any remaining product must be handled by authorized hazardous waste disposal companies. Do not release the gas into the atmosphere or water systems. Proper documentation and waste tracking are required throughout the disposal process. Consult environmental authorities for specific disposal requirements in your region and maintain records of all disposal activities.

How to transport sulfuryl difluoride?

Sulfuryl difluoride is classified as ADR Class 2 dangerous goods for transportation purposes, indicating it's a compressed gas requiring specialized handling during transport. It must be shipped in approved pressure vessels with proper labeling, documentation, and emergency response information. Vehicles must be appropriately equipped and drivers properly trained and certified for dangerous goods transport. Transportation must comply with ADR regulations including route restrictions, quantity limitations, and emergency procedures. Only authorized carriers with dangerous goods permits should handle the transportation of this pressurized toxic gas.

Is sulfuryl difluoride subject to specific regulations?

Sulfuryl difluoride is subject to comprehensive chemical regulations including REACH registration requirements in Europe and CLP classification obligations. It's not currently listed as a Substance of Very High Concern (SVHC), but its acute toxicity and environmental hazard classifications impose strict regulatory controls. Industrial users must comply with occupational exposure limits, emission controls, and worker protection requirements. The compound may be subject to pesticide regulations when used as a fumigant, requiring specific authorizations and usage restrictions in different jurisdictions.

Where to buy sulfuryl difluoride in Europe?

Sulfuryl difluoride is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous materials handling. OYSI provides compliant supply chains for dangerous goods including proper documentation, safety data sheets, and regulatory support. As a technical chemical requiring specialized handling and storage, it's essential to work with experienced suppliers who understand the regulatory requirements and safety protocols. Professional buyers should ensure their supplier maintains appropriate certifications and can provide technical support for safe handling and application of this pressurized toxic gas.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.