Sulfuryl difluoride
F2O2S
sulfuryl difluoride
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Identification
- CAS Number
- 2699-79-8
- EC Number
- 220-281-5
- UN Number
- 2191
- Index Number
- 009-015-00-7
- PubChem CID
- 17607
Physical-chemical properties
- Molecular Formula
- F2O2S
- Molar Mass
- 102.06 g/mol
- IUPAC Name
- sulfuryl difluoride
Chemical Identifiers
- InChI
- InChI=1S/F2O2S/c1-5(2,3)4
- InChI Key
- OBTWBSRJZRCYQV-UHFFFAOYSA-N
Overview
Sulfuryl difluoride (CAS 2699-79-8) is an inorganic gas compound with fumigant properties and high toxicity characteristics. This colorless, odorless gas serves as a critical industrial chemical in specialized applications requiring effective penetration and reactivity. With the molecular formula F2O2S and a molecular weight of 102.06 g/mol, sulfuryl difluoride exhibits unique chemical properties that distinguish it from other halogenated compounds. The substance belongs to the sulfur fluoride family and demonstrates significantly different handling requirements compared to traditional fumigants like bromomethane, offering specific advantages in certain industrial processes. The compound presents considerable safety challenges, classified under multiple hazard categories including acute toxicity (Category 3), specific target organ toxicity following repeated exposure (Category 2), and acute aquatic toxicity (Category 1). Its classification as a pressurized gas under ADR Class 2 requires specialized storage and transportation protocols. The GHS pictograms (GHS04, GHS06, GHS08, GHS09) clearly indicate the multiple risks associated with handling this substance, necessitating comprehensive safety measures and appropriate personal protective equipment. Primary industrial applications include specialized fumigation processes, particularly in situations requiring deep penetration into materials and structures. The compound also finds use in specific chemical synthesis reactions and as an intermediate in fluorine chemistry applications. Its effectiveness in certain sterilization processes makes it valuable for specialized industrial equipment treatment. OYSI maintains availability of sulfuryl difluoride for qualified industrial customers, ensuring compliance with all relevant European regulations and providing comprehensive technical support for safe handling and application procedures.
Safety & Classification
Press. Gas; Acute Tox. 3 *; STOT RE 2 *; Aquatic Acute 1
GHS Pictograms
Gas Cylinder
GHS04
Gases under pressure. May explode if heated.
Skull and Crossbones
GHS06
Acute toxicity. Fatal if swallowed, in contact with skin, or if inhaled.
Health Hazard
GHS08
Serious health hazard. May cause cancer, organ damage, or genetic defects.
Environment
GHS09
Environmental hazard. Toxic to aquatic life with long lasting effects.
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2191 |
| ADR Class | 2 |
| Packing Group | |
| Tunnel Code | C/D |
| Proper Shipping Name | Sulfurylfluorid, unter Druck verflüssigt |
| Marine Pollutant | No |
Frequently Asked Questions
What is sulfuryl difluoride?
Sulfuryl difluoride is an inorganic chemical compound with the formula F2O2S and CAS number 2699-79-8. This colorless gas with a molecular weight of 102.06 g/mol belongs to the sulfur fluoride family. It is classified as a pressurized gas with acute toxicity and specific target organ toxicity properties. The compound is primarily used as a fumigant and industrial chemical intermediate due to its high reactivity and penetrating properties.
What are the physicochemical properties of sulfuryl difluoride?
Sulfuryl difluoride is a colorless, odorless gas at room temperature with high chemical stability and low reactivity under normal conditions. It has a molecular weight of 102.06 g/mol and exists as a pressurized gas under standard conditions. The compound exhibits low solubility in water but can dissolve in organic solvents. It demonstrates excellent penetrating ability through various materials, making it effective for fumigation applications.
What is sulfuryl difluoride used for?
Sulfuryl difluoride is primarily used as a structural fumigant for pest control in buildings, warehouses, and food processing facilities. It serves as an effective alternative to methyl bromide for termite control and elimination of various stored product pests. Additionally, it finds applications as a chemical intermediate in pharmaceutical synthesis and specialty chemical manufacturing. Its excellent penetrating properties make it suitable for treating wood structures and packaged goods.
How to handle sulfuryl difluoride safely?
Sulfuryl difluoride requires strict safety protocols due to its acute toxicity classification. Personnel must wear appropriate respiratory protection, including self-contained breathing apparatus in confined spaces. Work areas must have adequate ventilation and gas detection systems. Handle only in well-ventilated areas or outdoors, avoid inhalation and skin contact. Emergency procedures should be established, and only trained professionals should handle this pressurized gas. Regular air monitoring is essential during use.
How to store sulfuryl difluoride correctly?
Sulfuryl difluoride must be stored as a pressurized gas in appropriate cylinders designed for fluorinated compounds. Storage areas should be well-ventilated, cool, and dry, away from heat sources and incompatible materials. Cylinders must be secured upright and protected from physical damage. Avoid storage near oxidizing agents and ensure proper labeling with hazard pictogrammes GHS04, GHS06, GHS08, and GHS09. Regular inspection of storage containers is mandatory.
What to do in case of contact with sulfuryl difluoride?
Sulfuryl difluoride exposure requires immediate emergency response due to its acute toxicity. In case of inhalation, move the person to fresh air immediately and provide oxygen if breathing is difficult. For skin or eye contact, flush thoroughly with water for at least 15 minutes. Remove contaminated clothing. Seek immediate medical attention in all cases of exposure. Do not induce vomiting if ingested. Contact emergency services and provide the safety data sheet to medical personnel.
How to dispose of sulfuryl difluoride properly?
Sulfuryl difluoride disposal must comply with local and European waste regulations as a hazardous chemical waste. Empty cylinders should be returned to the supplier or certified waste management facility. Never release the gas directly into the atmosphere due to its environmental hazard classification (Aquatic Acute 1). Contact licensed hazardous waste disposal companies for proper treatment and disposal. Maintain documentation of disposal activities for regulatory compliance.
How to transport sulfuryl difluoride?
Sulfuryl difluoride is classified under ADR Class 2 (gases) for transportation purposes. It must be transported in approved pressure vessels with proper hazard labels and documentation. Vehicles must be equipped with appropriate safety equipment and driven by certified drivers trained in hazardous materials transport. Ensure proper ventilation during transport and avoid exposure to heat sources. Follow ADR regulations for quantity limits, segregation requirements, and emergency response procedures.
Is sulfuryl difluoride subject to specific regulations?
Sulfuryl difluoride is subject to multiple European regulations including REACH registration requirements and CLP classification as a dangerous substance. It carries the signal word 'Danger' with multiple hazard classifications including acute toxicity and environmental hazards. The compound is not currently listed as an SVHC (Substance of Very High Concern). Users must comply with occupational exposure limits, environmental discharge regulations, and biocide legislation where applicable as a fumigant.
Where to buy sulfuryl difluoride in Europe?
Sulfuryl difluoride is available through OYSI, a specialized European distributor of technical chemicals. As a regulated substance requiring proper handling expertise, it should only be purchased from certified suppliers who can provide complete documentation, safety data sheets, and technical support. OYSI ensures compliance with European regulations and provides quality-assured products with proper packaging and labeling for professional users across Europe.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.