Carbon monoxide

CO

carbon monoxide

CAS630-08-0
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
Danger

Consulting for Carbon monoxide

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Identification

CAS Number
630-08-0
EC Number
211-128-3
UN Number
1016
Index Number
006-001-00-2
PubChem CID
281

Physical-chemical properties

Molecular Formula
CO
Molar Mass
28.01 g/mol
IUPAC Name
carbon monoxide

Chemical Identifiers

InChI
InChI=1S/CO/c1-2
InChI Key
UGFAIRIUMAVXCW-UHFFFAOYSA-N

Overview

Carbon monoxide (CAS 630-08-0) is a toxic flammable gas with colorless and odorless properties that poses significant industrial safety hazards. This simple diatomic molecule, consisting of one carbon atom covalently bonded to one oxygen atom, represents one of the most hazardous industrial gases encountered in chemical processes. With its molecular formula CO and molar mass of 28.01 g/mol, carbon monoxide exhibits properties that make it both valuable for industrial applications and extremely dangerous for human health. The gas burns with a characteristic blue flame and has a density slightly lower than air, which can lead to accumulation in enclosed spaces. The primary safety concern with carbon monoxide stems from its ability to bind to hemoglobin with an affinity approximately 200 times greater than oxygen, leading to carbon monoxide poisoning. This colorless, odorless gas can be lethal even at relatively low concentrations, earning it classification under multiple GHS hazard categories including acute toxicity, reproductive toxicity, and specific target organ toxicity. Unlike other toxic industrial gases such as arsane, carbon monoxide's lack of warning properties makes detection equipment essential in any facility handling this substance. Industrial applications of carbon monoxide include its use as a reducing agent in metallurgical processes, particularly in steel production where it reduces iron ore to metallic iron. The gas also serves as a key component in syngas production for chemical synthesis and as a precursor in the manufacture of methanol and other organic compounds. In the petrochemical industry, carbon monoxide plays a crucial role in hydroformylation reactions and Fischer-Tropsch synthesis. OYSI provides technical-grade carbon monoxide with comprehensive safety documentation and regulatory compliance support for European industrial customers.

Safety & Classification

Danger
Classification:

Flam. Gas 1; Press. Gas; Repr. 1A; Acute Tox. 3 *; STOT RE 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H220

Extremely flammable gas.

H331

Toxic if inhaled.

H372

Causes damage to organs through prolonged or repeated exposure.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1016
ADR Class2
Tunnel CodeB/D
Proper Shipping NameKohlenmonoxid, verdichtet
Marine PollutantNo

Frequently Asked Questions

What is carbon monoxide?

Carbon monoxide is a colorless, odorless, and highly toxic gas with the chemical formula CO and molecular weight of 28.01 g/mol. It is classified as a flammable gas, pressurized gas, reproductive toxicant category 1A, acute toxicant category 3, and specific target organ toxicant (repeated exposure) category 1. This dangerous substance is produced by incomplete combustion of carbon-containing materials and poses severe health risks including death by asphyxiation.

What are the physicochemical properties of carbon monoxide?

Carbon monoxide is a colorless and odorless gas at room temperature and atmospheric pressure. It has a density slightly lower than air (0.97 relative to air), making it slightly lighter than the surrounding atmosphere. CO is poorly soluble in water and burns with a characteristic blue flame. Its boiling point is -191.5°C and melting point is -205°C. The gas is chemically stable under normal conditions but highly reactive with hemoglobin in blood.

What is carbon monoxide used for?

Carbon monoxide is primarily used as a reducing agent in metallurgical processes, particularly in steel production and metal refining. It serves as a key component in synthesis gas (syngas) for producing methanol, ammonia, and other chemicals. CO is utilized in the Fischer-Tropsch process for synthetic fuel production and as a fuel gas in industrial heating applications. It also plays a role in carbonyl chemistry for producing metal carbonyls and various organic compounds.

How to handle carbon monoxide safely?

Carbon monoxide handling requires strict safety protocols including proper ventilation systems, continuous gas detection monitors, and emergency response procedures. Personnel must use appropriate respiratory protection equipment and work in well-ventilated areas or enclosed systems. Regular air monitoring is essential, and workers should be trained in CO poisoning symptoms recognition. Emergency evacuation procedures and fresh air access routes must be established. All equipment should be regularly maintained and leak-tested to prevent accidental exposure.

How to store carbon monoxide correctly?

Carbon monoxide must be stored in properly designed pressure vessels in well-ventilated areas away from ignition sources, oxidizing agents, and incompatible materials. Storage areas should have continuous gas detection systems and emergency ventilation. Cylinders must be secured upright, protected from physical damage, and kept at temperatures below 50°C. Storage facilities should be separated from work areas and equipped with appropriate fire suppression systems. Regular inspection of storage containers is mandatory.

What to do in case of contact with carbon monoxide?

Carbon monoxide exposure requires immediate removal of the affected person to fresh air and emergency medical attention. If the person is unconscious or showing signs of CO poisoning (headache, dizziness, nausea), call emergency services immediately and administer oxygen if available and trained to do so. Do not enter contaminated areas without proper respiratory protection. Monitor vital signs and be prepared to perform CPR if necessary. Hyperbaric oxygen therapy may be required for severe poisoning cases.

How to dispose of carbon monoxide appropriately?

Carbon monoxide disposal must comply with local environmental regulations and waste management laws. Small quantities can be safely burned off through controlled flaring in appropriate facilities with proper permits. Larger quantities require specialized waste management companies experienced in hazardous gas disposal. Empty cylinders should be returned to suppliers or certified recycling facilities. Never release CO directly into the atmosphere, and always consult with environmental authorities and waste management specialists for proper disposal methods.

How to transport carbon monoxide?

Carbon monoxide is classified under ADR Class 2 (gases) and requires compliance with dangerous goods transportation regulations. It must be transported in approved pressure vessels with proper labeling, documentation, and placarding. Vehicles must be equipped with appropriate safety equipment and ventilation systems. Drivers require specialized dangerous goods training and certification. Transport routes should avoid densely populated areas when possible, and emergency response information must be readily available during transit.

Is carbon monoxide subject to specific regulations?

Carbon monoxide is subject to extensive regulations under REACH, CLP, and various national safety standards due to its extreme toxicity and environmental impact. It requires classification as a reproductive toxicant category 1A and carries multiple hazard classifications. Workplace exposure limits are strictly regulated, and industrial users must implement comprehensive risk management measures. Special permits may be required for handling and storage, and regular reporting to authorities is often mandatory for commercial users.

Where to buy carbon monoxide in Europe?

Carbon monoxide is available through specialized industrial gas suppliers and chemical distributors across Europe, including OYSI, a European chemical distributor. Due to its extreme hazard classification and regulatory requirements, purchases typically require documentation of legitimate industrial use, appropriate safety infrastructure, and qualified personnel. Suppliers must verify customer credentials and intended applications before sales. Contact OYSI or other certified distributors for availability, technical specifications, and regulatory compliance support for your specific industrial requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.