Arsane

AsH3

arsane

CAS7784-42-1
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7784-42-1
EC Number
232-066-3
UN Number
2188
Index Number
033-006-00-7
PubChem CID
23969

Physical-chemical properties

Molecular Formula
AsH3
Molar Mass
77.95 g/mol
IUPAC Name
arsane

Chemical Identifiers

InChI
InChI=1S/AsH3/h1H3
InChI Key
RBFQJDQYXXHULB-UHFFFAOYSA-N

Overview

Arsane (CAS 7784-42-1) is a highly toxic inorganic hydride gas with flammable properties and severe acute toxicity hazards. This colorless gas represents one of the most hazardous arsenic compounds encountered in industrial applications. Arsane exhibits exceptional toxicity, surpassing even carbon monoxide in its potential for acute poisoning, making it a substance requiring extreme caution in handling and storage. The compound exists as a pressurized gas under normal conditions and demonstrates significant instability, decomposing readily upon exposure to light, heat, or moisture. The primary safety concerns associated with arsane include its classification as an acute toxin category 2, presenting immediate life-threatening risks through inhalation exposure. Its flammable gas properties compound these dangers, as the substance can form explosive mixtures with air across a wide concentration range. Additionally, arsane poses specific target organ toxicity risks with repeated exposure, particularly affecting the nervous system and blood-forming organs. Environmental considerations are equally critical, as the compound exhibits acute and chronic aquatic toxicity. Industrial applications of arsane remain highly specialized due to its extreme toxicity profile. The semiconductor industry utilizes arsane as a dopant source in the production of gallium arsenide and other III-V semiconductor materials for electronic devices. Chemical synthesis applications employ arsane as a reducing agent and arsenic source in specialized reactions, though safer alternatives are increasingly preferred where technically feasible. OYSI maintains technical expertise in handling and distributing arsane while ensuring full compliance with European chemical safety regulations and transportation requirements for this highly regulated substance.

Safety & Classification

Danger
Classification:

Flam. Gas 1; Press. Gas; Acute Tox. 2 *; STOT RE 2 *; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H220

Extremely flammable gas.

H330

Fatal if inhaled.

H373

May cause damage to organs through prolonged or repeated exposure.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2188
ADR Class2
Packing Group
Tunnel CodeD
Proper Shipping NameArsenwasserstoff, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is arsane?

Arsane is a highly toxic inorganic gas with the chemical formula AsH3 and CAS number 7784-42-1. This colorless compound has a molecular weight of 77.946 g/mol and belongs to the family of hydrides. Arsane is classified as an extremely hazardous substance due to its acute toxicity, flammability, and environmental impact. It poses significant risks through inhalation and can cause severe health effects including organ damage with repeated exposure.

What are the physicochemical properties of arsane?

Arsane is a colorless gas at room temperature with a characteristic garlic-like odor. It has a molecular weight of 77.946 g/mol and exists as a pressurized gas under normal storage conditions. The compound is highly flammable and forms explosive mixtures with air. Arsane has limited solubility in water but can decompose in aqueous solutions. Its physical state and high reactivity make it particularly hazardous to handle and require specialized equipment.

What is arsane used for?

Arsane is primarily used in the semiconductor industry as a dopant gas for manufacturing electronic components and integrated circuits. It serves as an arsenic source in chemical vapor deposition processes and molecular beam epitaxy. Additionally, arsane finds applications in specialized chemical synthesis reactions and research laboratories. Due to its extreme toxicity and handling requirements, its use is restricted to highly controlled industrial environments with appropriate safety infrastructure and expertise.

How to handle arsane safely?

Arsane requires extreme safety precautions due to its acute toxicity and flammability. Personnel must use appropriate respiratory protection, including supplied-air systems, and work in well-ventilated areas or fume hoods. Fire-resistant clothing and chemical-resistant gloves are essential. Gas detection systems should monitor atmospheric concentrations continuously. Only trained personnel should handle arsane, and emergency response procedures must be established. All equipment must be grounded to prevent static electricity buildup due to flammability risks.

How to store arsane correctly?

Arsane must be stored in specialized gas cylinders designed for toxic and flammable gases in well-ventilated, temperature-controlled areas. Storage areas should be equipped with gas detection systems and emergency ventilation. The compound should be kept away from ignition sources, oxidizing agents, and incompatible materials. Access must be restricted to authorized personnel only. Storage facilities require compliance with local regulations for toxic gas storage and appropriate emergency response equipment readily available.

What to do in case of contact with arsane?

Arsane exposure primarily occurs through inhalation and requires immediate medical attention. Move the affected person to fresh air immediately and provide oxygen if breathing is difficult. Contact emergency medical services without delay as arsane poisoning can be life-threatening. Remove contaminated clothing and flush skin with water if contact occurs. Do not induce vomiting if ingested. Trained emergency responders should handle rescue operations due to the extreme toxicity and potential for secondary exposure.

How to dispose of arsane properly?

Arsane disposal must comply with hazardous waste regulations due to its classification as acute toxic, flammable, and environmentally hazardous material. Empty cylinders should be returned to the supplier or handled by licensed waste management companies. Never attempt to dispose of arsane through normal waste streams or release it into the environment. Specialized treatment facilities equipped to handle toxic gases are required. Documentation of disposal must meet regulatory requirements for hazardous chemical waste tracking.

How to transport arsane?

Arsane is classified under ADR Class 2 (Gases) for transportation purposes, requiring specialized handling as a dangerous good. Transport must use approved cylinders and vehicles equipped for toxic gas transport. Proper shipping documentation, emergency response information, and placarding are mandatory. Only certified carriers experienced in hazardous gas transport should handle shipments. Emergency response procedures and contact information must accompany all shipments to ensure rapid response capability during transport incidents.

Is arsane subject to specific regulations?

Arsane is subject to extensive regulatory oversight under REACH, CLP, and national chemical safety regulations across Europe. It requires safety data sheets and classification as acute toxic, flammable gas with specific labeling requirements including GHS pictograms 02, 04, 06, 08, and 09. Although not currently listed as SVHC, its use may be restricted or require permits in many jurisdictions. Workplace exposure limits and environmental discharge restrictions apply in most countries.

Where to buy arsane in Europe?

Arsane is available through OYSI, a European distributor specializing in technical chemicals and industrial gases. Due to its extreme hazards classification and regulatory requirements, purchase is restricted to qualified industrial users with appropriate safety infrastructure and permits. OYSI provides technical support and ensures compliance with transportation and safety regulations. Customers must demonstrate proper handling capabilities and regulatory compliance before purchase approval. Contact OYSI directly for availability and technical specifications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.