Trioxochromium

CrO3

trioxochromium

CAS1333-82-0
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
1333-82-0
EC Number
215-607-8
UN Number
1463
Index Number
024-001-00-0
PubChem CID
14915

Physical-chemical properties

Molecular Formula
CrO3
Molar Mass
99.99 g/mol
IUPAC Name
trioxochromium

Chemical Identifiers

InChI
InChI=1S/Cr.3O
InChI Key
WGLPBDUCMAPZCE-UHFFFAOYSA-N

Overview

Trioxochromium (CAS 1333-82-0) is a highly reactive chromium oxide compound with strong oxidizing properties and significant toxicological hazards. This inorganic compound, also known by its IUPAC name trioxochromium, represents one of the most important industrial chromium compounds with the molecular formula CrO3 and a molecular weight of 99.994 g/mol. The dark red crystalline solid exhibits exceptional oxidizing capabilities, making it valuable across various industrial applications while requiring stringent safety protocols due to its classification under multiple hazard categories including carcinogenic (1A), mutagenic (1B), and acute toxicity classifications. The compound's chemical reactivity stems from chromium in its highest oxidation state (+6), which readily participates in electron transfer reactions. This characteristic makes trioxochromium particularly effective in oxidation processes but also contributes to its biological hazards. The substance displays high solubility in water, forming strongly acidic solutions that can cause severe corrosion to metals, skin, and mucous membranes. Safety considerations are paramount when handling this material, as indicated by its danger signal word and comprehensive GHS pictogram requirements covering oxidizing agents, health hazards, toxicity, corrosion, and environmental concerns. Industrial applications include metal surface treatment processes, chromium plating operations, and specialized chemical synthesis where controlled oxidation is required. The compound shares chemical relationships with other chromium-based oxidizing agents such as disodium;oxido-(oxido(dioxo)chromio)oxy-dioxochromium and dipotassium;oxido-(oxido(dioxo)chromio)oxy-dioxochromium, though each exhibits distinct reactivity profiles and application suitabilities. OYSI maintains availability of high-quality trioxochromium for qualified industrial customers with appropriate handling capabilities and regulatory compliance.

Safety & Classification

Danger
Classification:

Ox. Sol. 1; Carc. 1A; Muta. 1B; Repr. 2; Acute Tox. 2 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT RE ...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H271

May cause fire or explosion; strong oxidiser.

H350

May cause cancer.

H340

May cause genetic defects.

H330

Fatal if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H314

Causes severe skin burns and eye damage.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1463
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameChromtrioxid, wasserfrei
Marine PollutantNo

Frequently Asked Questions

What is trioxochromium?

Trioxochromium is a highly hazardous inorganic chemical compound with the molecular formula CrO3 and CAS number 1333-82-0. This chromium oxide has a molecular weight of 99.994 g/mol and appears as dark red crystalline flakes or powder. It is classified as a Category 1A carcinogen, Category 1B mutagen, and Category 2 reproductive toxin, making it one of the most dangerous chromium compounds used in industrial applications.

What are the physicochemical properties of trioxochromium?

Trioxochromium is a dark red to orange crystalline solid that is highly soluble in water, forming strongly acidic solutions. It has a high melting point and is hygroscopic, readily absorbing moisture from air. The compound is a powerful oxidizing agent that can react violently with organic materials and reducing substances. It decomposes at elevated temperatures, releasing toxic chromium vapors and oxygen gas.

What is trioxochromium used for?

Trioxochromium is primarily used in metal finishing operations, particularly for chromium plating and anodizing processes. It serves as an oxidizing agent in organic synthesis and is utilized in wood preservation treatments. The compound is also employed in the production of other chromium compounds and as a catalyst in certain chemical reactions. Due to its extreme toxicity, its use is heavily regulated and restricted in many applications.

How to handle trioxochromium safely?

Trioxochromium requires extreme safety precautions due to its carcinogenic and toxic properties. Personnel must wear full respiratory protection, chemical-resistant gloves, and protective clothing covering all skin. Work should be conducted in well-ventilated areas or fume hoods to prevent inhalation exposure. Avoid contact with combustible materials and reducing agents. Regular health monitoring and specialized training are essential for anyone handling this substance professionally.

How to store trioxochromium correctly?

Trioxochromium must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from heat sources and incompatible materials. Keep separated from organic compounds, alcohols, reducing agents, and flammable substances to prevent violent reactions. Storage areas should be secure, clearly labeled, and accessible only to trained personnel. Containers should be regularly inspected for corrosion or damage, and emergency response equipment must be readily available.

What to do in case of contact with trioxochromium?

Trioxochromium exposure requires immediate emergency response due to its extreme toxicity. For skin contact, immediately flush with copious amounts of water for at least 20 minutes and remove contaminated clothing. If inhaled, move the person to fresh air and seek immediate medical attention. For eye contact, rinse continuously with water and get emergency medical care. Never induce vomiting if ingested. Contact poison control and emergency medical services immediately for any exposure.

How to dispose of trioxochromium appropriately?

Trioxochromium disposal must comply with strict hazardous waste regulations due to its carcinogenic properties and environmental toxicity. The substance requires treatment at licensed hazardous waste facilities capable of handling chromium VI compounds. Never dispose of it in regular waste streams or pour down drains. Waste containers must be properly labeled and transported by authorized hazardous waste carriers. Neutralization or reduction treatments may be required before final disposal.

How to transport trioxochromium?

Trioxochromium is classified under ADR Class 5.1 (oxidizing substances) Packing Group II, requiring specialized dangerous goods packaging and labeling. Transportation must comply with international dangerous goods regulations, using UN-approved containers with proper hazard labels including oxidizing agent and toxicity warnings. Only certified dangerous goods transporters should handle shipments, and proper documentation including safety data sheets must accompany all consignments.

Is trioxochromium subject to specific regulations?

Trioxochromium is subject to extensive regulatory controls under REACH, CLP, and occupational safety legislation due to its classification as a Category 1A carcinogen and mutagen. It requires authorization for many uses under REACH Annex XIV and is subject to strict occupational exposure limits. The substance falls under chromium VI regulations, requiring comprehensive risk assessments, worker health surveillance, and specialized handling procedures in industrial applications.

Where to buy trioxochromium in Europe?

Trioxochromium is available through OYSI, a European distributor specializing in technical chemicals for industrial applications. Due to its hazardous classification and regulatory restrictions, purchases require proper authorization, end-use declarations, and compliance with safety regulations. OYSI provides technical support and ensures proper packaging and transportation according to dangerous goods requirements. Only qualified industrial users with appropriate safety measures should procure this substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.