Sulfane

S

sulfane

CAS7704-34-9
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Warning

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Identification

CAS Number
7704-34-9
EC Number
231-722-6
UN Number
1350
Index Number
016-094-00-1
PubChem CID
5362487

Physical-chemical properties

Molecular Formula
S
Molar Mass
32.07 g/mol
IUPAC Name
sulfane

Chemical Identifiers

InChI
InChI=1S/S
InChI Key
NINIDFKCEFEMDL-UHFFFAOYSA-N

Overview

Sulfane (CAS 7704-34-9) is an elemental sulfur compound with distinctive chemical reactivity and industrial versatility. Sulfane represents one of the most fundamental forms of sulfur, existing as a pure elemental substance with significant commercial importance across multiple industries. This yellow crystalline solid demonstrates remarkable chemical properties that make it essential for numerous manufacturing processes and chemical syntheses. As a basic building block in sulfur chemistry, sulfane serves as a precursor for countless sulfur-containing compounds used in modern industrial applications. The substance exhibits notable chemical reactivity, particularly in oxidation and vulcanization reactions. Under standard conditions, sulfane appears as a bright yellow solid with low solubility in water but good solubility in carbon disulfide and other organic solvents. Its molecular structure allows for various allotropic forms, with the most stable being the orthorhombic crystal form at room temperature. From a safety perspective, sulfane is classified as Skin Irritant Category 2 with the warning signal word, requiring appropriate handling precautions. The GHS07 pictogram indicates the need for standard protective equipment during handling and processing. Transportation falls under ADR Class 4.1, designating it as a flammable solid requiring specific shipping protocols. Industrial applications include rubber vulcanization, where sulfane creates cross-links in polymer chains, pharmaceutical synthesis as a key intermediate, and agricultural chemical production. The compound also finds use in the manufacture of sulfuric acid and various sulfur-containing specialty chemicals. Unlike complex nitrogen-containing compounds such as 1,3,5,7-tetrazatricyclo[3.3.1.13,7]decane, sulfane's elemental nature provides straightforward reactivity patterns. OYSI maintains reliable European distribution channels for technical-grade sulfane, supporting diverse industrial requirements across the continent.

Safety & Classification

Warning
Classification:

Skin Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H315

Causes skin irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1350
ADR Class4.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameSchwefel, Brocken oder grobkörniges Pulver
Marine PollutantNo

Frequently Asked Questions

What is sulfane?

Sulfane is elemental sulfur (S) with CAS number 7704-34-9, representing the pure form of the chemical element sulfur. It has a molecular weight of 32.07 g/mol and appears as a yellow crystalline solid at room temperature. Sulfane is classified as a skin irritant (Skin Irrit. 2) under GHS regulations and requires careful handling in industrial applications.

What are the physicochemical properties of sulfane?

Sulfane is a yellow crystalline solid at room temperature with a characteristic odor. It is insoluble in water but soluble in organic solvents like carbon disulfide. Sulfane has a melting point of 115°C and a boiling point of 445°C. It exists in several allotropic forms, with rhombic sulfur being the most stable at room temperature.

What is sulfane used for?

Sulfane is used extensively in the chemical industry for producing sulfuric acid, one of the most important industrial chemicals. It serves as a raw material for manufacturing rubber vulcanization agents, fungicides, and pharmaceutical compounds. Additionally, sulfane is utilized in the production of sulfur dioxide, matches, gunpowder, and various sulfur-containing organic compounds in petrochemical processes.

How to handle sulfane safely?

Sulfane requires careful handling due to its skin irritant properties (GHS07 pictogram, Warning signal word). Wear appropriate personal protective equipment including gloves, safety goggles, and protective clothing to prevent skin contact. Ensure adequate ventilation in work areas and avoid generating dust. Handle in a well-ventilated area away from heat sources and incompatible materials.

How to store sulfane correctly?

Sulfane should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials such as strong oxidizing agents. Keep containers tightly closed and protected from moisture. Store away from metals and organic materials that could react with sulfur. Maintain storage temperatures below 30°C to prevent softening and ensure proper container integrity.

What to do in case of contact with sulfane?

In case of skin contact with sulfane, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If eye contact occurs, rinse eyes with clean water for 15 minutes and seek medical attention. In case of inhalation of sulfur dust, move to fresh air immediately and seek medical advice if respiratory irritation persists.

How to dispose of sulfane appropriately?

Sulfane disposal must comply with local and national waste regulations as it is classified as a chemical waste. Contact licensed waste disposal companies for proper handling and treatment. Small quantities can often be recycled through chemical recovery processes. Never dispose of sulfane in regular household waste or down drains, as it requires specialized treatment facilities.

How to transport sulfane?

Sulfane is classified under ADR as Class 4.1 (Flammable solids), Packing Group III, indicating it requires specific transport regulations. Use appropriate UN-approved packaging and ensure proper labeling with hazard diamonds. Transport vehicles must comply with ADR requirements including proper documentation, emergency equipment, and driver training for handling flammable solid materials.

Is sulfane subject to particular regulations?

Sulfane is regulated under CLP regulation with classification as Skin Irrit. 2, requiring GHS07 pictogram and Warning signal word. It falls under REACH regulation for chemical registration and safety data requirements. While not classified as SVHC (Substance of Very High Concern), it must comply with standard chemical safety protocols and workplace exposure limits established by national authorities.

Where to buy sulfane in Europe?

Sulfane is available through OYSI, a European distributor specializing in technical chemicals and industrial raw materials. OYSI provides high-quality sulfane with proper documentation, safety data sheets, and regulatory compliance for European markets. As a professional chemical distributor, OYSI ensures reliable supply chains and technical support for industrial customers across Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.