Bromomethane
CH3Br
bromomethane
Consulting for Bromomethane
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Identification
- CAS Number
- 74-83-9
- EC Number
- 200-813-2
- UN Number
- 1062
- Index Number
- 602-002-00-2
- PubChem CID
- 6323
Physical-chemical properties
- Molecular Formula
- CH3Br
- Molar Mass
- 94.94 g/mol
- IUPAC Name
- bromomethane
Chemical Identifiers
- InChI
- InChI=1S/CH3Br/c1-2/h1H3
- InChI Key
- GZUXJHMPEANEGY-UHFFFAOYSA-N
Overview
Bromomethane (CAS 74-83-9) is a halogenated hydrocarbon compound characterized by its gaseous state at room temperature and high toxicity profile. This single-carbon organobromine compound, with the molecular formula CH3Br and molecular weight of 94.94 g/mol, represents one of the simplest alkyl bromides used in industrial applications. Also known as methyl bromide, bromomethane exists as a colorless gas under standard conditions and exhibits significant biological activity that has led to its classification under multiple hazard categories including mutagenicity, acute toxicity, and specific target organ toxicity. The compound's hazard profile requires careful handling protocols, as indicated by its GHS danger signal word and multiple pictograms including GHS04 (pressurized gas), GHS06 (acute toxicity), GHS08 (health hazard), and GHS09 (environmental hazard). Its classification as ADR Class 2 substance reflects its gaseous nature and associated transport considerations. The substance demonstrates acute toxicity through multiple exposure routes and can cause skin irritation, eye irritation, and specific organ damage following repeated exposure. Industrially, bromomethane serves primarily as a methylating agent in organic synthesis reactions and as an intermediate in pharmaceutical manufacturing. The compound also finds application in specialized fumigation processes, though regulatory restrictions have significantly limited this use due to environmental and health concerns. Like other toxic gases such as arsane, bromomethane requires specialized handling equipment and extensive safety measures during storage and use. The chemical's reactivity profile makes it valuable for producing various methylated compounds in controlled industrial settings, where its effectiveness as a methylating agent can be utilized while maintaining appropriate safety protocols. OYSI provides bromomethane to qualified industrial customers with comprehensive safety documentation and regulatory compliance support.
Safety & Classification
Press. Gas; Muta. 2; Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 3; STOT RE 2 *; Skin Irrit. 2; Eye I...
GHS Pictograms
Gas Cylinder
GHS04
Gases under pressure. May explode if heated.
Health Hazard
GHS08
Serious health hazard. May cause cancer, organ damage, or genetic defects.
Skull and Crossbones
GHS06
Acute toxicity. Fatal if swallowed, in contact with skin, or if inhaled.
Environment
GHS09
Environmental hazard. Toxic to aquatic life with long lasting effects.
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing genetic defects.
Toxic if inhaled.
Toxic if swallowed.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Causes skin irritation.
Causes serious eye irritation.
Very toxic to aquatic life.
Harms public health and the environment by destroying ozone in the upper atmosphere.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1062 |
| ADR Class | 2 |
| Packing Group | |
| Tunnel Code | C/D |
| Proper Shipping Name | Methylbromid, unter Druck verflüssigt, Chlorpikrin <= 2 % |
| Marine Pollutant | No |
Frequently Asked Questions
What is bromomethane?
Bromomethane is an organobromine compound with the molecular formula CH3Br and CAS number 74-83-9. This chemical substance has a molecular weight of 94.94 g/mol and exists as a pressurized gas under normal conditions. Bromomethane is classified as a hazardous substance with multiple danger classifications including acute toxicity, mutagenicity, and potential for causing organ damage. It requires careful handling due to its toxic properties and environmental concerns.
What are the physical and chemical properties of bromomethane?
Bromomethane is a colorless gas at room temperature with a sweet, chloroform-like odor. As a pressurized gas (GHS04 pictogram), it has a low boiling point and can easily transition between gas and liquid phases. The compound is slightly soluble in water but readily dissolves in organic solvents. Its molecular structure consists of a methyl group bonded to a bromine atom, making it a simple halomethane with relatively high volatility.
What is bromomethane used for?
Bromomethane serves primarily as a fumigant and pesticide in agricultural applications, particularly for soil sterilization and pest control in stored products. It is also used as a methylating agent in organic synthesis and as an intermediate in the production of other chemicals. Additionally, bromomethane finds application in pharmaceutical manufacturing and as a solvent in certain industrial processes, though its use has been restricted in many applications due to environmental and health concerns.
How to handle bromomethane safely?
Bromomethane requires strict safety measures including respiratory protection, chemical-resistant gloves, and eye protection due to its acute toxicity and skin irritation potential. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Personnel must be trained in emergency procedures and monitoring equipment should be used to detect gas leaks. Regular health surveillance is recommended for workers exposed to this mutagenic substance with potential for organ damage.
How to store bromomethane correctly?
Bromomethane must be stored in pressurized containers designed for gas storage, away from heat sources and ignition points. Storage areas should be well-ventilated, cool, and dry to prevent pressure buildup and potential container failure. The substance should be kept away from incompatible materials and stored in compliance with local regulations for hazardous gases. Regular inspection of storage containers and pressure relief systems is essential for safe storage.
What to do in case of contact with bromomethane?
Bromomethane exposure requires immediate action: for skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, flush immediately with plenty of water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention. For ingestion, do not induce vomiting and seek immediate medical care. Always consult emergency services for significant exposure incidents due to the substance's high toxicity.
How to dispose of bromomethane appropriately?
Bromomethane disposal must comply with hazardous waste regulations and should never be released into the environment due to its toxic and potentially ozone-depleting properties. The substance must be collected by licensed hazardous waste disposal companies who can handle pressurized gas containers safely. Incineration at high temperatures in specialized facilities is typically required. Empty containers should also be treated as hazardous waste and disposed of according to local environmental regulations.
How to transport bromomethane?
Bromomethane is classified as ADR Class 2 dangerous goods, requiring specialized transport procedures for pressurized gases. Transportation must comply with international dangerous goods regulations, using appropriate packaging, labeling, and documentation. Vehicles must be properly placarded and drivers must hold valid dangerous goods transport certifications. Temperature control and pressure monitoring may be necessary during transport to ensure container integrity and prevent accidental release.
Is bromomethane subject to specific regulations?
Bromomethane is subject to extensive regulations under REACH, CLP, and various environmental protection laws. It is classified with multiple hazard categories including mutagenicity and acute toxicity, requiring comprehensive safety data sheets and risk assessments. Many countries have restricted or banned its use due to ozone depletion concerns under the Montreal Protocol. Industrial users must comply with emission limits, worker protection standards, and environmental monitoring requirements.
Where to buy bromomethane in Europe?
Bromomethane is available through OYSI, a European distributor of technical chemicals specializing in hazardous substances. As a regulated chemical with strict handling requirements, purchase is typically limited to qualified industrial users with proper licensing and safety infrastructure. OYSI provides technical support and regulatory guidance to ensure compliant procurement and use. Contact OYSI directly to discuss availability, regulatory requirements, and technical specifications for your specific application needs.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.