Sulfurous acid
H2O3S
sulfurous acid
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Identification
- CAS Number
- 7782-99-2
- EC Number
- 231-973-1
- UN Number
- 1833
- PubChem CID
- 1100
Physical-chemical properties
- Molecular Formula
- H2O3S
- Molar Mass
- 82.08 g/mol
- IUPAC Name
- sulfurous acid
Chemical Identifiers
- InChI
- InChI=1S/H2O3S/c1-4(2)3/h(H2,1,2,3)
- InChI Key
- LSNNMFCWUKXFEE-UHFFFAOYSA-N
Overview
Sulfurous acid (CAS 7782-99-2) is an inorganic acid with the molecular formula H2O3S, existing primarily in aqueous solution as an unstable intermediate compound. This weak diprotic acid forms when sulfur dioxide dissolves in water, creating an equilibrium mixture that plays a crucial role in various industrial and environmental processes. Unlike its more stable counterpart sulfuric acid, sulfurous acid cannot be isolated in pure form due to its tendency to decompose rapidly into sulfur dioxide and water. The compound exhibits reducing properties and readily undergoes oxidation reactions, making it valuable in specific chemical applications where controlled reduction is required. Sulfurous acid demonstrates moderate acidity with a molecular weight of 82.08 g/mol and exists predominantly as hydrated sulfur dioxide rather than the true H2O3S structure in aqueous solutions. Its chemical behavior differs significantly from other acid chlorides used in organic synthesis, such as 4-methoxybenzoyl chloride, which serves different industrial purposes despite both being reactive intermediates. The compound's instability necessitates careful handling and storage considerations, though it presents relatively low direct toxicity risks under normal conditions. Primary industrial applications include its use as a reducing agent in chemical synthesis, as an intermediate in sulfur chemistry processes, and in certain bleaching operations where temporary color removal is desired. The compound also finds application in analytical chemistry for specific reduction reactions and in environmental chemistry for sulfur dioxide scrubbing processes. OYSI provides sulfurous acid solutions for industrial applications, ensuring reliable supply for European chemical processing operations requiring this specialized reducing agent.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 1833 |
| ADR Class | 8 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Schwefelige Säure |
| Marine Pollutant | No |
Frequently Asked Questions
What is sulfurous acid?
Sulfurous acid is an inorganic compound with the molecular formula H2O3S and CAS number 7782-99-2. This chemical species has a molecular weight of 82.08 g/mol and exists primarily in aqueous solution rather than as a pure compound. It is formed when sulfur dioxide dissolves in water and acts as a weak diprotic acid. Sulfurous acid is an important intermediate in various chemical processes and industrial applications.
What are the physicochemical properties of sulfurous acid?
Sulfurous acid is a colorless aqueous solution that exists only in dilute form, as the pure compound is unstable and decomposes readily. It has a characteristic pungent, sulfur-like odor and is highly soluble in water by definition. The compound is a weak acid with reducing properties and tends to decompose into sulfur dioxide and water upon concentration or heating. It exhibits typical acid behavior in aqueous solutions.
What is sulfurous acid used for?
Sulfurous acid is primarily used as a reducing agent in chemical synthesis and analytical chemistry applications. It serves as an intermediate in the production of sulfur compounds and is utilized in bleaching processes for organic materials like wool and silk. The compound finds application in food preservation as an antimicrobial agent and in water treatment processes. It is also used in laboratory settings for various analytical procedures and chemical reactions.
How to handle sulfurous acid safely?
Sulfurous acid should be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation of vapors. Avoid contact with skin, eyes, and clothing. Use non-sparking tools and ensure proper grounding when transferring the solution. Always have emergency eyewash and safety shower facilities readily available in the work area.
How to store sulfurous acid correctly?
Sulfurous acid should be stored in tightly sealed, corrosion-resistant containers in a cool, dry, and well-ventilated area away from direct sunlight. Keep containers away from heat sources and incompatible materials such as strong oxidizing agents and bases. Storage areas should be equipped with appropriate spill containment measures and emergency equipment. Regularly inspect containers for signs of corrosion or leakage and maintain proper inventory rotation.
What to do in case of contact with sulfurous acid?
In case of skin contact with sulfurous acid, immediately flush the affected area with plenty of water for at least 15 minutes and remove contaminated clothing. For eye contact, rinse thoroughly with water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. For ingestion, rinse mouth with water but do not induce vomiting. Seek immediate medical attention in all cases of exposure.
How to dispose of sulfurous acid appropriately?
Sulfurous acid must be disposed of in accordance with local, national, and international waste regulations as a chemical waste. The solution should be neutralized carefully with appropriate alkaline materials under controlled conditions before disposal. Contact licensed waste disposal companies for proper treatment and disposal. Never discharge untreated sulfurous acid into sewers, waterways, or soil. Maintain proper documentation of waste disposal activities as required by regulations.
How to transport sulfurous acid?
Sulfurous acid is classified under ADR Class 8 (corrosive substances), Packing Group II, indicating it requires specific transport regulations for corrosive materials. Packages must meet UN specification requirements and be properly labeled with appropriate hazard markings. Transport vehicles should carry emergency response information and appropriate spill cleanup materials. Drivers must hold valid ADR certification and follow specific routing and handling procedures for corrosive substances.
Is sulfurous acid subject to specific regulations?
Sulfurous acid is subject to standard chemical regulations including REACH registration requirements in Europe and CLP classification rules. While not currently listed as a Substance of Very High Concern (SVHC), it must comply with general chemical safety regulations for handling, storage, and workplace exposure limits. Users must maintain safety data sheets and implement appropriate risk management measures. Regular monitoring of regulatory updates is recommended for compliance.
Where to buy sulfurous acid in Europe?
Sulfurous acid is available through OYSI, a leading European distributor of technical chemicals serving industrial and professional customers across Europe. OYSI provides reliable supply chains and technical support for sulfurous acid procurement. As a specialized chemical distributor, OYSI ensures proper documentation, regulatory compliance, and quality assurance for chemical products. Contact OYSI directly for availability, specifications, and delivery options in your specific European location.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.