(E)-but-2-enoic acid

C4H6O2

CAS107-93-7

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Identification

CAS Number
107-93-7
EC Number
223-077-4
UN Number
2823
PubChem CID
637090

Physical-chemical properties

Molecular Formula
C4H6O2
Molar Mass
86.09 g/mol
IUPAC Name
(E)-but-2-enoic acid

Chemical Identifiers

InChI
InChI=1S/C4H6O2/c1-2-3-4(5)6/h2-3H,1H3,(H,5,6)/b3-2+
InChI Key
LDHQCZJRKDOVOX-NSCUHMNNSA-N

Overview

(E)-but-2-enoic acid (CAS 107-93-7) is an unsaturated carboxylic acid featuring a trans double bond configuration and acidic properties. Also known as trans-crotonic acid, this organic compound represents an important member of the butenoic acid family with significant industrial applications. The molecule consists of a four-carbon chain containing both a carboxyl functional group and a carbon-carbon double bond in the E-configuration, giving it unique reactivity patterns compared to its saturated counterparts. This white crystalline solid exhibits typical carboxylic acid behavior, readily forming salts with bases and esters with alcohols. The presence of the double bond enhances its reactivity, making it valuable as an intermediate in organic synthesis. Unlike more complex aromatic compounds such as 4-methoxybenzoyl chloride, (E)-but-2-enoic acid offers straightforward handling characteristics while maintaining versatile chemical functionality. The compound demonstrates good solubility in polar solvents and shows moderate thermal stability under normal storage conditions. Its ADR classification as Class 8 indicates corrosive properties typical of carboxylic acids, requiring appropriate handling precautions including proper ventilation and protective equipment. However, the absence of specific GHS pictogrammes suggests relatively manageable safety considerations compared to more hazardous industrial chemicals. Primary industrial applications include polymer synthesis as a monomer or co-monomer, pharmaceutical intermediate production, and specialty chemical manufacturing. The compound serves as a building block for various derivatives used in coatings, adhesives, and agricultural chemicals. Its role in Michael addition reactions makes it particularly valuable for creating complex molecular structures in fine chemical synthesis. OYSI maintains reliable supply chains for (E)-but-2-enoic acid to support diverse European industrial applications with consistent quality specifications.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2823
ADR Class8
Packing GroupIII
Tunnel CodeE
Proper Shipping Nametrans-Crotonsäure, fest
Marine PollutantNo

Frequently Asked Questions

What is (E)-but-2-enoic acid?

(E)-but-2-enoic acid is an unsaturated carboxylic acid with the molecular formula C4H6O2 and CAS number 107-93-7. It is the trans-isomer of but-2-enoic acid, also known as trans-crotonic acid. This organic compound features a double bond between the second and third carbon atoms in the chain, with the carboxyl group at one end. It has a molecular weight of 86.09 g/mol and appears as a white crystalline solid at room temperature.

What are the physicochemical properties of (E)-but-2-enoic acid?

(E)-but-2-enoic acid is a white crystalline solid at room temperature with a characteristic pungent, acetic acid-like odor. It has a melting point of approximately 71-74°C and a boiling point around 185°C. The compound is moderately soluble in water and highly soluble in organic solvents such as ethanol, ether, and acetone. It exhibits typical carboxylic acid properties, being acidic in nature with a pKa value of approximately 4.7.

What is (E)-but-2-enoic acid used for?

(E)-but-2-enoic acid is primarily used as an intermediate in organic synthesis and pharmaceutical manufacturing. It serves as a building block for the production of various chemicals, including flavor compounds, fragrances, and pharmaceutical intermediates. The compound is also utilized in polymer chemistry for the synthesis of specialized resins and coatings. Additionally, it finds applications in research laboratories as a reagent for chemical reactions and analytical studies.

How to handle (E)-but-2-enoic acid safely?

(E)-but-2-enoic acid should be handled with standard laboratory safety precautions despite having no specific GHS classification. Wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and lab coats. Ensure adequate ventilation when working with this substance to avoid inhalation of vapors. Avoid contact with skin, eyes, and clothing. Work in a well-ventilated area or under a fume hood. Keep containers tightly closed when not in use and wash hands thoroughly after handling.

How to store (E)-but-2-enoic acid correctly?

(E)-but-2-enoic acid should be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers tightly sealed to prevent moisture absorption and contamination. Store away from strong bases, oxidizing agents, and reactive metals as these may cause unwanted reactions. The storage area should be equipped with appropriate spill containment measures. Maintain storage temperatures below 25°C for optimal stability and prevent degradation of the product.

What to do in case of contact with (E)-but-2-enoic acid?

In case of skin contact with (E)-but-2-enoic acid, immediately flush the affected area with plenty of water for at least 15 minutes and remove contaminated clothing. For eye contact, rinse thoroughly with water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air and keep them comfortable. In case of ingestion, do not induce vomiting; rinse mouth with water. Seek medical attention if irritation persists or if large amounts were involved.

How to dispose of (E)-but-2-enoic acid properly?

(E)-but-2-enoic acid waste must be disposed of in accordance with local, national, and international regulations. Do not discharge into drains, soil, or water bodies. Collect waste in appropriate, labeled containers and arrange for disposal through licensed waste management companies. Small laboratory quantities may be neutralized carefully with appropriate bases before disposal, following institutional waste management protocols. Always consult with your local environmental authorities for specific disposal requirements in your region.

How to transport (E)-but-2-enoic acid?

(E)-but-2-enoic acid is classified under ADR Class 8 (Corrosive substances), Packing Group III for transportation purposes. It must be packaged in UN-approved containers suitable for corrosive materials and properly labeled with appropriate hazard markings. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers must be trained in handling corrosive materials. Ensure packages are secure, upright, and protected from damage during transit. Follow all applicable national and international transport regulations.

Is (E)-but-2-enoic acid subject to specific regulations?

(E)-but-2-enoic acid is subject to standard chemical regulations including REACH registration requirements for substances manufactured or imported in quantities above 1 tonne per year in the EU. It is not classified as a SVHC (Substance of Very High Concern) under REACH. The substance must comply with CLP regulation for classification, labeling, and packaging. Standard chemical safety data sheets must be provided for professional users. Local environmental and occupational health regulations may also apply depending on the intended use and quantities handled.

Where to buy (E)-but-2-enoic acid in Europe?

(E)-but-2-enoic acid is available through OYSI, a trusted European distributor of specialty chemicals serving the industrial and research markets. OYSI provides high-quality chemical products with appropriate documentation including safety data sheets and certificates of analysis. As an established European supplier, OYSI ensures compliance with local regulations and offers reliable supply chains across Europe. Contact OYSI directly for specific product grades, packaging options, and availability information for your requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.