Sodium perchlorate

ClNaO4

sodium perchlorate

CAS7601-89-0
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
7601-89-0
EC Number
231-511-9
UN Number
1502
Index Number
017-010-00-6
PubChem CID
522606

Physical-chemical properties

Molecular Formula
ClNaO4
Molar Mass
122.44 g/mol
IUPAC Name
sodium perchlorate

Chemical Identifiers

InChI
InChI=1S/ClHO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI Key
BAZAXWOYCMUHIX-UHFFFAOYSA-M

Overview

Sodium perchlorate (CAS 7601-89-0) is an inorganic oxidizing salt with strong oxidizing properties and high solubility in water. This white crystalline compound belongs to the perchlorate family and serves as a powerful oxidizing agent across various industrial applications. With the molecular formula ClNaO4 and a molecular weight of 122.44 g/mol, sodium perchlorate exhibits exceptional stability under normal conditions while maintaining its reactive oxidizing characteristics when required. The substance is classified as an Oxidizing Solid Category 1 and Acute Toxicity Category 4 under the CLP regulation, requiring careful handling protocols. Its GHS pictograms include GHS03 (flame over circle) and GHS07 (exclamation mark), indicating both oxidizing and health hazard properties. The "Danger" signal word reflects the need for appropriate safety measures during storage, handling, and transportation, which falls under ADR Class 5.1 for oxidizing substances. Sodium perchlorate demonstrates remarkable water solubility, making it particularly useful in aqueous systems where other perchlorates like potassium perchlorate might have limited solubility. This enhanced solubility distinguishes it from related compounds such as barium(2+);dichlorate;hydrate, which has different solubility characteristics and applications. Primary industrial applications include its use as an oxidizing agent in chemical synthesis, as a component in pyrotechnic formulations, and in analytical chemistry procedures. The compound also finds application in specialized chemical processes where controlled oxidation reactions are essential, and in certain electrochemical applications where its ionic properties are advantageous. OYSI maintains reliable supplies of sodium perchlorate to support European industrial customers' technical requirements.

Safety & Classification

Danger
Classification:

Ox. Sol. 1; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H271

May cause fire or explosion; strong oxidiser.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1502
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameNatriumperchlorat, wasserfrei, fest
Marine PollutantNo

Frequently Asked Questions

What is sodium perchlorate?

Sodium perchlorate is an inorganic chemical compound with the formula ClNaO4 and CAS number 7601-89-0. It belongs to the perchlorate family and has a molecular weight of 122.44 g/mol. This substance is classified as a strong oxidizing agent (Ox. Sol. 1) and poses acute toxicity hazards (Acute Tox. 4). It requires careful handling due to its oxidizing properties and potential health risks, making it subject to strict safety regulations and transport requirements.

What are the physicochemical properties of sodium perchlorate?

Sodium perchlorate is a white crystalline solid that is highly soluble in water and polar solvents. It appears as colorless to white crystals or powder with no characteristic odor. The compound is hygroscopic, meaning it readily absorbs moisture from the atmosphere. It has excellent thermal stability and demonstrates strong oxidizing properties, which makes it reactive with organic materials and reducing agents under certain conditions.

What is sodium perchlorate used for?

Sodium perchlorate is primarily used in analytical chemistry as a supporting electrolyte in electrochemical applications and as a drying agent due to its hygroscopic properties. It serves as an oxidizing agent in various industrial processes and is utilized in laboratory research for specific chemical reactions. The compound also finds applications in specialized industries where controlled oxidation reactions are required, though its use is regulated due to safety considerations.

How to handle sodium perchlorate safely?

Sodium perchlorate requires careful handling with appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation exposure. Avoid contact with skin, eyes, and clothing. Keep away from heat sources, sparks, and incompatible materials like organic compounds and reducing agents. Always follow proper laboratory safety protocols and ensure emergency equipment is readily available.

How to store sodium perchlorate correctly?

Sodium perchlorate must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and store separately from combustible materials, organic compounds, and reducing agents due to its strong oxidizing properties. Use appropriate secondary containment and ensure storage areas comply with local regulations for oxidizing substances. Maintain proper labeling and inventory records for regulatory compliance.

What to do in case of contact with sodium perchlorate?

Sodium perchlorate exposure requires immediate action: for skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes and remove contact lenses if present. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician after any significant exposure incident.

How to dispose of sodium perchlorate appropriately?

Sodium perchlorate disposal must comply with local, national, and EU waste regulations as it is classified as hazardous waste. Contact licensed waste disposal companies specialized in handling oxidizing substances. Never dispose of it through regular waste streams or pour down drains. Small laboratory quantities may require neutralization procedures before disposal. Maintain proper documentation of waste disposal activities and follow your organization's hazardous waste management protocols.

How to transport sodium perchlorate?

Sodium perchlorate is classified under ADR Class 5.1 (oxidizing substances) Packing Group II, requiring specialized transport procedures. It must be packaged in UN-approved containers with proper hazard labels (GHS03, GHS07) and shipping documentation. Transport vehicles must comply with ADR regulations for oxidizing substances. Only trained personnel should handle shipments, and emergency response information must accompany the cargo during transport.

Is sodium perchlorate subject to particular regulations?

Sodium perchlorate is subject to various European regulations including CLP (Classification, Labelling and Packaging) and REACH registration requirements. It is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with occupational health and safety regulations, proper labeling requirements with danger signal word and appropriate pictograms (GHS03, GHS07). Industrial users may need permits and must follow strict handling and reporting requirements.

Where to buy sodium perchlorate in Europe?

Sodium perchlorate is available through OYSI, a European distributor of technical chemicals specializing in high-quality chemical products. OYSI provides sodium perchlorate with proper documentation, safety data sheets, and regulatory compliance support across European markets. As a specialized chemical distributor, OYSI ensures product quality and regulatory compliance while offering technical support for industrial and laboratory applications requiring this oxidizing compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.