Potassium perchlorate
ClKO4
potassium perchlorate
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Identification
- CAS Number
- 7778-74-7
- EC Number
- 231-912-9
- UN Number
- 1489
- Index Number
- 017-008-00-5
- PubChem CID
- 516900
Physical-chemical properties
- Molecular Formula
- ClKO4
- Molar Mass
- 138.55 g/mol
- IUPAC Name
- potassium perchlorate
Chemical Identifiers
- InChI
- InChI=1S/ClHO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
- InChI Key
- YLMGFJXSLBMXHK-UHFFFAOYSA-M
Overview
Potassium perchlorate (CAS 7778-74-7) is an inorganic oxidizing salt with strong oxidizing properties and high thermal stability. This white crystalline compound belongs to the perchlorate family and serves as a crucial industrial chemical in various technical applications requiring controlled oxidation processes. As a potassium salt of perchloric acid, potassium perchlorate exhibits excellent stability under normal storage conditions while maintaining its powerful oxidizing characteristics when activated. The compound's molecular structure (ClKO4) provides a balanced combination of oxidizing potential and handling safety compared to other perchlorates. Unlike sodium perchlorate, which shows higher hygroscopicity, potassium perchlorate offers superior moisture resistance, making it preferable for applications requiring long-term storage stability. The substance is classified as Oxidizing Solid Category 1 and Acute Toxicity Category 4, requiring appropriate handling protocols and safety measures. Its strong oxidizing properties demand careful storage away from combustible materials and reducing agents. The compound's thermal decomposition releases oxygen, which can intensify fires and support combustion of organic materials. Primary industrial applications include pyrotechnic compositions, where potassium perchlorate serves as an oxygen source for controlled combustion reactions. The aerospace industry utilizes this compound in solid rocket propellants, taking advantage of its stable oxygen release characteristics. Additionally, it finds use in specialized analytical chemistry applications and as an oxidizing agent in various chemical synthesis processes. The compound's consistent quality and predictable performance make it valuable for applications requiring precise stoichiometric calculations. Safety considerations include proper ventilation during handling and compatibility assessment with other chemicals in formulations. OYSI maintains reliable supply chains for potassium perchlorate, ensuring consistent availability for European industrial customers requiring this essential oxidizing agent.
Safety & Classification
Ox. Sol. 1; Acute Tox. 4 *
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1489 |
| ADR Class | 5.1 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Kaliumperchlorat, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is potassium perchlorate?
Potassium perchlorate is an inorganic chemical compound with the formula ClKO4 and CAS number 7778-74-7. This crystalline salt has a molecular weight of 138.55 g/mol and belongs to the perchlorate family. It is classified as a strong oxidizing agent (Ox. Sol. 1) and presents acute toxicity hazards (Acute Tox. 4). The compound is widely used in industrial applications requiring controlled oxidation reactions and exhibits high chemical stability under normal conditions.
What are the physicochemical properties of potassium perchlorate?
Potassium perchlorate appears as white crystalline powder or granules at room temperature. The compound is odorless and has moderate solubility in water, with solubility increasing significantly with temperature. It has a relatively high melting point and demonstrates excellent thermal stability. As a strong oxidizing agent, it can react vigorously with reducing agents, organic materials, and combustible substances. The compound is non-hygroscopic and maintains its crystalline structure under normal atmospheric conditions.
What is potassium perchlorate used for?
Potassium perchlorate serves primarily as an oxidizing agent in pyrotechnic compositions, rocket propellants, and explosive formulations. It is extensively used in the aerospace industry for solid rocket fuel applications due to its high oxygen content and controlled decomposition properties. The compound also finds applications in analytical chemistry, metal processing, and specialized industrial processes requiring strong oxidation capabilities. Its controlled release of oxygen makes it valuable in various chemical manufacturing processes.
How to handle potassium perchlorate safely?
Potassium perchlorate requires careful handling with appropriate personal protective equipment including safety goggles, gloves, and dust masks to prevent inhalation and skin contact. Work areas must be well-ventilated and free from heat sources, sparks, and incompatible materials. Avoid friction, impact, and static electricity during handling. Use non-sparking tools and equipment. Keep away from combustible materials, reducing agents, and organic compounds. Emergency shower and eyewash facilities should be readily accessible in work areas.
How to store potassium perchlorate correctly?
Potassium perchlorate must be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Use original containers or approved storage vessels, keeping them tightly sealed to prevent contamination. Store separately from combustible materials, reducing agents, metals, and organic compounds. Maintain storage temperature below 30°C and ensure adequate separation distances. Storage areas should be equipped with appropriate fire suppression systems and constructed with non-combustible materials.
What to do in case of contact with potassium perchlorate?
Potassium perchlorate exposure requires immediate first aid measures depending on the contact route. For skin contact, remove contaminated clothing and rinse thoroughly with water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes while holding eyelids open. If inhaled, move the person to fresh air and seek medical attention if breathing difficulties occur. For ingestion, rinse mouth and seek immediate medical attention. Do not induce vomiting.
How to dispose of potassium perchlorate appropriately?
Potassium perchlorate disposal must comply with local, national, and European waste regulations as it is classified as hazardous waste. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may require neutralization or dilution under controlled conditions before disposal. Never dispose of in regular waste streams, sewers, or water bodies. Maintain detailed disposal records and follow waste classification codes. Consider waste minimization strategies and recovery options where technically feasible.
How to transport potassium perchlorate?
Potassium perchlorate is classified under ADR Class 5.1 (Oxidizing substances) Packing Group II, requiring specialized transport procedures. Use approved packaging materials and labels including GHS03 and GHS07 pictograms with 'Danger' signal word. Transport vehicles must comply with ADR regulations for oxidizing substances. Drivers require appropriate hazmat training and certification. Ensure proper documentation including transport documents and emergency response information. Avoid transport during extreme weather conditions and ensure segregation from incompatible materials.
Is potassium perchlorate subject to specific regulations?
Potassium perchlorate is regulated under multiple European frameworks including REACH and CLP regulations due to its oxidizing and toxic properties. It requires safety data sheets, hazard classification, and proper labeling with GHS pictograms. The compound is not currently listed as a SVHC (Substance of Very High Concern). Industrial users must comply with occupational exposure limits and workplace safety requirements. Additional restrictions may apply for specific applications, particularly in pyrotechnics and explosive manufacturing sectors.
Where to buy potassium perchlorate in Europe?
Potassium perchlorate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides high-quality potassium perchlorate with complete regulatory documentation, safety data sheets, and technical support. As a professional chemical distributor, OYSI ensures compliance with European regulations and offers reliable supply chains for industrial applications. Contact OYSI directly for pricing, availability, and specific grade requirements for your industrial applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.