Potassium perchlorate

ClKO4

potassium perchlorate

CAS7778-74-7
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
7778-74-7
EC Number
231-912-9
UN Number
1489
Index Number
017-008-00-5
PubChem CID
516900

Physical-chemical properties

Molecular Formula
ClKO4
Molar Mass
138.55 g/mol
IUPAC Name
potassium perchlorate

Chemical Identifiers

InChI
InChI=1S/ClHO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI Key
YLMGFJXSLBMXHK-UHFFFAOYSA-M

Overview

Potassium perchlorate (CAS 7778-74-7) is an inorganic oxidizing salt with strong oxidizing properties and excellent thermal stability. This white crystalline compound represents one of the most important perchlorate salts in industrial chemistry, widely recognized for its powerful oxidizing characteristics and controlled decomposition properties. As a member of the alkali metal perchlorate family, potassium perchlorate shares similar oxidizing behavior with related compounds such as sodium perchlorate, though it offers distinct advantages in specific applications due to its unique thermal decomposition profile and solubility characteristics. The compound exhibits exceptional stability under normal storage conditions while maintaining its strong oxidizing potential when required. This dual nature makes it particularly valuable in applications where controlled energy release is essential. Its relatively low solubility in water compared to other perchlorates provides additional handling advantages in certain industrial processes. From a safety perspective, potassium perchlorate requires careful handling protocols due to its classification as an oxidizing solid. The substance can intensify fires and may cause combustible materials to ignite more readily. Proper storage away from reducing agents, organic materials, and heat sources is essential. Personal protective equipment including respiratory protection and appropriate clothing should be used during handling operations. Key industrial applications include its use as an oxidizing agent in pyrotechnic compositions, where its clean burning properties and color enhancement capabilities are highly valued. The aerospace industry utilizes potassium perchlorate in solid rocket propellants, taking advantage of its reliable performance characteristics. Additionally, it finds application in specialty chemical synthesis processes where controlled oxidation is required. OYSI provides high-quality potassium perchlorate to industrial customers across Europe, ensuring consistent supply and technical support for demanding applications.

Safety & Classification

Danger
Classification:

Ox. Sol. 1; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H271

May cause fire or explosion; strong oxidiser.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1489
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameKaliumperchlorat, fest
Marine PollutantNo

Frequently Asked Questions

What is potassium perchlorate?

Potassium perchlorate is an inorganic chemical compound with the formula ClKO4 and CAS number 7778-74-7. This white crystalline salt has a molecular weight of 138.55 g/mol and serves as a powerful oxidizing agent. It belongs to the perchlorate family of compounds and is classified as a solid oxidizer (Ox. Sol. 1) with acute toxicity properties. The compound is widely used in industrial applications requiring controlled oxidation reactions.

What are the physicochemical properties of potassium perchlorate?

Potassium perchlorate appears as white, odorless crystals or crystalline powder at room temperature. It has moderate solubility in water, increasing significantly with temperature. The compound is stable under normal conditions but decomposes when heated above 400°C, releasing oxygen. It has a relatively high density and exhibits strong oxidizing properties, making it reactive with reducing agents, organic materials, and combustible substances.

What is potassium perchlorate used for?

Potassium perchlorate is primarily used in pyrotechnics and fireworks manufacturing as an oxidizer to produce brilliant colors and effects. It serves as an oxygen source in solid rocket propellants and emergency oxygen generators. Industrial applications include analytical chemistry as a reagent, photography processing, and specialized manufacturing processes requiring controlled oxidation. It's also utilized in certain pharmaceutical preparations and as a component in safety matches and flares.

How to handle potassium perchlorate safely?

Potassium perchlorate requires careful handling due to its oxidizing properties and acute toxicity classification. Always wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and dust masks to prevent inhalation. Work in well-ventilated areas away from heat sources, flames, and combustible materials. Avoid friction, impact, and static electricity. Keep separate from reducing agents and organic compounds to prevent dangerous reactions.

How to store potassium perchlorate correctly?

Potassium perchlorate must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Use original containers or appropriate chemical-resistant packaging, keeping them tightly sealed to prevent moisture absorption. Store separately from combustible materials, reducing agents, metals, and organic compounds. Maintain storage temperatures below 30°C and ensure adequate separation distances from incompatible substances as per safety regulations.

What to do in case of contact with potassium perchlorate?

Potassium perchlorate contact requires immediate first aid measures. For skin contact, remove contaminated clothing and rinse affected areas thoroughly with water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention if breathing difficulties occur. For eye contact, flush eyes with clean water for 15 minutes. In case of ingestion, do not induce vomiting and seek immediate medical assistance.

How to dispose of potassium perchlorate appropriately?

Potassium perchlorate disposal must comply with local and European waste regulations as it's classified as hazardous waste. Never dispose of it in regular trash or pour it down drains. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities may be neutralized by authorized personnel using appropriate chemical methods. Always consult local environmental authorities for specific disposal requirements and approved disposal facilities in your region.

How to transport potassium perchlorate?

Potassium perchlorate is classified under ADR regulations as Class 5.1 (Oxidizing substances), Packing Group II, requiring specialized transportation procedures. It must be packaged in UN-approved containers with proper labeling including GHS03 and GHS07 pictograms and 'Danger' signal word. Transport vehicles must carry appropriate safety equipment and documentation. Only qualified carriers with ADR certification should handle transportation of this oxidizing substance.

Is potassium perchlorate subject to specific regulations?

Potassium perchlorate is regulated under European REACH and CLP regulations, requiring proper classification, labeling, and safety data sheets. It's not currently listed as a SVHC (Substance of Very High Concern). Users must comply with occupational exposure limits and workplace safety requirements. Some countries may have additional restrictions on its sale and use due to security concerns, particularly regarding quantities and end-use applications in pyrotechnics.

Where to buy potassium perchlorate in Europe?

Potassium perchlorate is available through OYSI, a specialized European distributor of technical chemicals. As an established chemical supplier, OYSI provides quality potassium perchlorate with proper documentation, safety data sheets, and regulatory compliance for industrial and professional applications. Contact OYSI directly to discuss your specific requirements, quantities, and delivery options across European markets while ensuring all regulatory requirements are met.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.