Hydrogen peroxide

H2O2

hydrogen peroxide

CAS7722-84-1
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7722-84-1
EC Number
231-765-0
UN Number
2015
Index Number
008-003-00-9
PubChem CID
784

Physical-chemical properties

Molecular Formula
H2O2
Molar Mass
34.02 g/mol
IUPAC Name
hydrogen peroxide

Chemical Identifiers

InChI
InChI=1S/H2O2/c1-2/h1-2H
InChI Key
MHAJPDPJQMAIIY-UHFFFAOYSA-N

Overview

Hydrogen peroxide (CAS 7722-84-1) is a powerful oxidizing agent with strong bleaching and disinfectant properties. This versatile chemical compound consists of two hydrogen atoms bonded to two oxygen atoms, forming one of the most important oxidizers in industrial chemistry. Hydrogen peroxide appears as a colorless liquid that decomposes readily into water and oxygen, making it an environmentally friendly alternative to many traditional chemical processes. With its molecular formula H2O2 and molar mass of 34.015 g/mol, this compound demonstrates remarkable reactivity due to the unstable oxygen-oxygen bond in its structure. The substance requires careful handling due to its classification as Oxidizing Liquid Category 1 and Skin Corrosive 1A under GHS regulations. The associated danger pictograms GHS03, GHS07, and GHS05 indicate its oxidizing nature, acute toxicity, and corrosive properties respectively. During storage and transport, hydrogen peroxide falls under ADR Class 5.1, reflecting its strong oxidizing characteristics that can intensify fires and cause combustible materials to ignite more readily. In industrial applications, hydrogen peroxide serves as a critical component in pulp and paper bleaching processes, where it provides an eco-friendly alternative to chlorine-based bleaching agents. The textile industry utilizes this compound for fabric bleaching and treatment, while water treatment facilities employ it for disinfection and organic pollutant removal. Similar to other oxidizing agents like calcium dihypochlorite, hydrogen peroxide offers powerful antimicrobial properties, though with the advantage of decomposing into harmless byproducts. OYSI maintains reliable supply chains for hydrogen peroxide across European markets, ensuring consistent availability for diverse industrial applications.

Safety & Classification

Danger
Classification:

Ox. Liq. 1; Acute Tox. 4 *; Acute Tox. 4 *; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H271

May cause fire or explosion; strong oxidiser.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2015
ADR Class5.1
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameWasserstoffperoxid, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is hydrogen peroxide?

Hydrogen peroxide is a chemical compound with the molecular formula H2O2, consisting of two hydrogen atoms and two oxygen atoms. With a molecular weight of 34.015 g/mol, it is a powerful oxidizing agent commonly used in industrial applications. It appears as a colorless liquid that is slightly more viscous than water and has a characteristic sharp odor. Hydrogen peroxide is highly reactive and decomposes readily into water and oxygen, making it both useful and potentially hazardous in various applications.

What are the physicochemical properties of hydrogen peroxide?

Hydrogen peroxide is a colorless, odorless to slightly sharp-smelling liquid at room temperature. It has a density greater than water and is completely miscible with water in all proportions. The compound is thermally unstable and decomposes exothermically into water and oxygen, especially when exposed to light, heat, or catalytic surfaces. It exhibits strong oxidizing properties and can act as both an oxidizing and reducing agent depending on the reaction conditions. Its boiling point is higher than water due to hydrogen bonding.

What is hydrogen peroxide used for?

Hydrogen peroxide serves multiple industrial and commercial purposes due to its strong oxidizing properties. It is widely used as a bleaching agent in the textile and paper industries, as a disinfectant and sterilizing agent in healthcare and food processing, and as an oxidizer in chemical synthesis. Additional applications include wastewater treatment, electronics cleaning, rocket fuel oxidizer, and as a precursor in the production of other chemicals. Its environmentally friendly decomposition into water and oxygen makes it attractive for green chemistry applications.

How to handle hydrogen peroxide safely?

Hydrogen peroxide requires careful handling due to its corrosive nature (Skin Corr. 1A) and acute toxicity. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas to avoid inhalation exposure. Avoid contact with skin, eyes, and clothing as it can cause severe burns. Keep away from heat sources, incompatible materials, and organic substances that may catalyze decomposition. Use proper handling tools and containers made of compatible materials to prevent accidental spills or reactions.

How to store hydrogen peroxide correctly?

Hydrogen peroxide must be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Use only containers made of compatible materials such as high-density polyethylene or aluminum. Keep away from organic materials, metals, and other incompatible substances that can catalyze decomposition. Store in original containers with proper labeling and ensure containers are not completely sealed to allow oxygen gas release. Maintain storage temperatures below recommended limits and implement proper segregation according to chemical compatibility guidelines.

What to do in case of contact with hydrogen peroxide?

Hydrogen peroxide contact requires immediate action due to its corrosive properties. For skin contact, immediately remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. For eye contact, rinse immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move person to fresh air and seek medical attention if breathing difficulties occur. For ingestion, do not induce vomiting and seek immediate medical attention. Always seek professional medical advice after any significant exposure incident.

How to dispose of hydrogen peroxide properly?

Hydrogen peroxide disposal must comply with local, national, and European waste regulations as it is classified as hazardous waste. Small quantities can often be diluted and neutralized under controlled conditions, allowing decomposition to water and oxygen. Larger quantities require disposal through licensed hazardous waste contractors. Never dispose of hydrogen peroxide down drains without proper treatment or mix with organic materials. Always consult local environmental authorities and follow waste classification codes. Proper documentation and waste tracking may be required depending on quantities and local regulations.

How to transport hydrogen peroxide?

Hydrogen peroxide is classified under ADR Class 5.1 (Oxidizing substances) Packing Group I, indicating high transport risk. Transportation requires UN-specification packaging designed for oxidizing liquids and proper hazard labeling with appropriate placards. Vehicles must carry emergency response information and drivers need ADR certification. Segregation rules must be followed to prevent contact with incompatible materials during transport. Professional hazardous goods carriers should handle transportation, ensuring compliance with European ADR regulations and proper documentation including dangerous goods declarations and transport certificates.

Is hydrogen peroxide subject to particular regulations?

Hydrogen peroxide is subject to multiple European regulations including REACH registration requirements and CLP classification obligations. It is classified with hazard classes Ox. Liq. 1, Acute Tox. 4, and Skin Corr. 1A, requiring specific labeling with GHS03, GHS07, and GHS05 pictograms and the signal word 'Danger'. While not currently listed as a SVHC substance, higher concentrations may face additional restrictions. Industrial users must comply with occupational exposure limits, safety data sheet requirements, and may need authorization for certain uses depending on concentration and application.

Where to buy hydrogen peroxide in Europe?

Hydrogen peroxide is available through OYSI, a European distributor of technical chemicals serving industrial customers across Europe. As a specialized chemical distributor, OYSI can provide various grades and concentrations suitable for different industrial applications. Professional buyers should contact OYSI directly to discuss specific requirements, concentrations needed, packaging options, and delivery arrangements. Given the hazardous nature of hydrogen peroxide, purchases typically require proper documentation, safety data sheets, and may be subject to quantity restrictions depending on end-use applications and local regulations.

Digital Product Passport available

EU DPP

A Digital Product Passport (DPP) compliant with EU regulations is available for this substance. The passport contains complete information on composition, safety, and sustainability.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.