Hydrogen peroxide

H2O2

hydrogen peroxide

CAS7722-84-1
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7722-84-1
EC Number
231-765-0
UN Number
2015
Index Number
008-003-00-9
PubChem CID
784

Physical-chemical properties

Molecular Formula
H2O2
Molar Mass
34.02 g/mol
IUPAC Name
hydrogen peroxide

Chemical Identifiers

InChI
InChI=1S/H2O2/c1-2/h1-2H
InChI Key
MHAJPDPJQMAIIY-UHFFFAOYSA-N

Overview

Hydrogen peroxide (CAS 7722-84-1) is a powerful oxidizing agent with strong disinfectant and bleaching properties, widely used across multiple industrial applications. This versatile chemical compound consists of two hydrogen atoms bonded to two oxygen atoms, forming one of the most important peroxide compounds in industrial chemistry. With its molecular formula H2O2 and molecular weight of 34.015 g/mol, hydrogen peroxide exists as a pale blue liquid in its pure form, though it is commonly available in various aqueous concentrations for different applications. The compound's remarkable oxidizing capabilities stem from its ability to readily release oxygen, making it an essential chemical for numerous industrial processes. Hydrogen peroxide presents significant safety considerations due to its classification as an oxidizing liquid (Ox. Liq. 1) and corrosive substance (Skin Corr. 1A). The compound requires careful handling protocols, as indicated by its "Danger" signal word and associated GHS pictograms including oxidizing, health hazard, and corrosion symbols. Its ADR classification as Class 5.1 reflects its oxidizing properties and potential fire enhancement risks during transportation and storage. Key industrial applications include water treatment and disinfection processes, where hydrogen peroxide serves as an environmentally friendly alternative to chlorine-based systems. The pulp and paper industry extensively utilizes hydrogen peroxide for bleaching processes, while the chemical manufacturing sector employs it as an oxidizing agent in various synthesis reactions. Unlike other oxidizing agents such as calcium dihypochlorite, hydrogen peroxide decomposes into water and oxygen, leaving no harmful residues. OYSI provides technical-grade hydrogen peroxide solutions to meet diverse industrial requirements across European markets.

Safety & Classification

Danger
Classification:

Ox. Liq. 1; Acute Tox. 4 *; Acute Tox. 4 *; Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H271

May cause fire or explosion; strong oxidiser.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2015
ADR Class5.1
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameWasserstoffperoxid, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is hydrogen peroxide?

Hydrogen peroxide is a chemical compound with the molecular formula H2O2 and CAS number 7722-84-1. It consists of two hydrogen atoms and two oxygen atoms, with a molecular weight of 34.015 g/mol. This colorless liquid is a powerful oxidizing agent that naturally decomposes into water and oxygen. It is widely used in various industrial applications due to its strong oxidizing and bleaching properties.

What are the physicochemical properties of hydrogen peroxide?

Hydrogen peroxide is a colorless, odorless liquid at room temperature with a slightly viscous consistency. It has excellent solubility in water and can form hydrogen bonds due to its polar nature. The compound is thermodynamically unstable and decomposes spontaneously into water and oxygen gas, especially when exposed to heat, light, or catalytic surfaces. Its density is higher than water at approximately 1.45 g/cm³ for concentrated solutions.

What is hydrogen peroxide used for?

Hydrogen peroxide serves multiple industrial and commercial purposes as a versatile oxidizing agent. It is extensively used in paper and textile bleaching, water treatment processes, chemical synthesis, and as a disinfectant in healthcare facilities. The compound also finds applications in electronics manufacturing for cleaning and etching, in food processing as a sanitizer, and in environmental remediation for soil and groundwater treatment.

How to handle hydrogen peroxide safely?

Hydrogen peroxide requires careful handling due to its corrosive and oxidizing properties. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas to prevent vapor accumulation. Avoid contact with skin, eyes, and clothing as it can cause severe burns. Use non-metallic containers and tools to prevent catalytic decomposition and potential hazardous reactions.

How to store hydrogen peroxide correctly?

Hydrogen peroxide must be stored in cool, dry, well-ventilated areas away from direct sunlight and heat sources. Use only original containers or compatible materials like high-density polyethylene or glass. Keep away from combustible materials, reducing agents, and metals that can catalyze decomposition. Ensure containers are properly vented to prevent pressure buildup from oxygen release during natural decomposition.

What to do in case of contact with hydrogen peroxide?

Immediate action is required upon contact with hydrogen peroxide due to its corrosive nature. For skin contact, remove contaminated clothing immediately and rinse the affected area with plenty of water for at least 15 minutes. In case of eye contact, flush continuously with clean water and seek immediate medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and contact emergency services immediately.

How to dispose of hydrogen peroxide appropriately?

Hydrogen peroxide disposal must comply with local environmental regulations and waste management requirements. Small quantities can often be neutralized through controlled dilution and decomposition under professional guidance. Larger quantities require disposal through licensed hazardous waste contractors. Never dispose of concentrated solutions directly into sewage systems or the environment. Always consult local authorities and follow established chemical waste disposal protocols.

How to transport hydrogen peroxide?

Hydrogen peroxide is classified under ADR transport regulations as Class 5.1 (Oxidizing substances) with Packing Group I, indicating high danger level. It requires specialized packaging, proper labeling with oxidizer symbols, and compliance with dangerous goods transport regulations. Only authorized carriers with proper training and equipment should handle transportation. Vehicles must carry appropriate emergency equipment and documentation during transport.

Is hydrogen peroxide subject to specific regulations?

Hydrogen peroxide is regulated under various European legislation including REACH and CLP regulations. It is classified with hazard classes including Oxidizing Liquid 1, Acute Toxicity 4, and Skin Corrosion 1A, requiring appropriate safety data sheets and hazard communication. Industrial users must comply with workplace safety regulations and may require permits for storage and handling of larger quantities depending on concentration and local requirements.

Where to buy hydrogen peroxide in Europe?

Hydrogen peroxide is available through OYSI, a European distributor specializing in technical chemicals. As an established chemical supplier, OYSI can provide hydrogen peroxide in various concentrations and packaging sizes suitable for industrial applications. Professional customers can access technical support, proper documentation, and reliable supply chains through authorized distributors who ensure compliance with European chemical regulations and quality standards.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.