Propanoic acid

C3H6O2

propanoic acid

CAS79-09-4
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
79-09-4
EC Number
201-176-3
UN Number
1848
Index Number
607-089-00-0
PubChem CID
1032

Physical-chemical properties

Molecular Formula
C3H6O2
Molar Mass
74.08 g/mol
IUPAC Name
propanoic acid

Chemical Identifiers

InChI
InChI=1S/C3H6O2/c1-2-3(4)5/h2H2,1H3,(H,4,5)
InChI Key
XBDQKXXYIPTUBI-UHFFFAOYSA-N

Overview

Propanoic acid (CAS 79-09-4) is a short-chain carboxylic acid with corrosive properties and antimicrobial characteristics commonly used in industrial applications. This saturated carboxylic acid, also known by its IUPAC name propanoic acid, represents a fundamental building block in organic chemistry with the molecular formula C3H6O2 and molecular weight of 74.08 g/mol. As a member of the alkanoic acid family, propanoic acid shares structural similarities with other carboxylic acids such as butanoic acid and heptanoic acid, though it exhibits distinct properties due to its three-carbon chain length. The compound presents significant safety considerations, classified under the harmonized system as Skin Corr. 1B with the danger signal word and GHS05 pictogram indicating its corrosive nature. Its ADR classification as Class 8 reflects its corrosive transport requirements, necessitating proper handling protocols and specialized storage conditions. The substance can cause severe skin burns and eye damage upon contact, requiring comprehensive personal protective equipment during handling operations. Industrially, propanoic acid serves multiple critical functions across various sectors. The food industry utilizes it extensively as a preservative and antimicrobial agent, particularly effective against mold and bacterial growth in baked goods and animal feed applications. The chemical manufacturing sector employs propanoic acid as an intermediate in the synthesis of various derivatives, including propanoyl propanoate and other ester compounds. Additionally, it finds application in the production of herbicides, pharmaceuticals, and synthetic flavoring agents. OYSI maintains reliable supply chains for propanoic acid, ensuring consistent availability of this essential industrial chemical for European markets through our established distribution network.

Safety & Classification

Danger
Classification:

Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1848
ADR Class8
Packing GroupIII
Tunnel CodeE
Proper Shipping NamePropionsäure, 10 % <= Konz. < 90 %
Marine PollutantNo

Frequently Asked Questions

What is propanoic acid?

Propanoic acid is a short-chain carboxylic acid with the molecular formula C3H6O2 and CAS number 79-09-4. It has a molecular weight of 74.08 g/mol and belongs to the family of saturated fatty acids. This organic compound is characterized by its corrosive properties and is classified as Skin Corr. 1B under GHS regulations. It appears as a colorless liquid with a pungent, rancid odor and is completely miscible with water and most organic solvents.

What are the physicochemical properties of propanoic acid?

Propanoic acid is a colorless liquid at room temperature with a sharp, pungent odor reminiscent of body odor or rancid oil. It has a boiling point of 141°C and a melting point of -20.5°C. The compound is completely miscible with water and most organic solvents including alcohols and ethers. It has a density of approximately 0.99 g/cm³ and exhibits strong acidic properties with a pKa value of 4.88, making it a moderately strong organic acid.

What is propanoic acid used for?

Propanoic acid serves primarily as a preservative in the food industry, particularly in baked goods, dairy products, and animal feed to prevent mold and bacterial growth. It is widely used in the production of propanoate salts, which are important food preservatives. Additionally, it functions as an intermediate in the synthesis of various chemicals, pharmaceuticals, and herbicides. The compound also finds applications in the production of cellulose propionate plastics and as a flavoring agent in small quantities.

How to handle propanoic acid safely?

Propanoic acid requires careful handling due to its corrosive nature (Skin Corr. 1B classification). Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work should be conducted in well-ventilated areas or under fume hoods to avoid inhalation of vapors. Handle containers carefully to prevent spills, and ensure emergency eyewash stations and safety showers are readily accessible. Never mix with strong bases or oxidizing agents without proper precautions.

How to store propanoic acid correctly?

Propanoic acid should be stored in tightly sealed containers made of compatible materials such as stainless steel, glass, or appropriate plastics in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers away from incompatible materials including strong bases, oxidizing agents, and metals that may corrode. Storage areas should have appropriate spill containment measures and be equipped with emergency equipment. Maintain storage temperatures below 25°C and ensure containers are properly labeled according to GHS requirements.

What to do in case of contact with propanoic acid?

Immediate action is crucial in case of contact with propanoic acid due to its corrosive properties. For skin contact, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. For eye contact, rinse immediately with water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. In case of ingestion, do not induce vomiting and rinse mouth with water. Seek immediate medical attention for all exposure routes.

How to dispose of propanoic acid appropriately?

Propanoic acid disposal must comply with local, national, and EU waste regulations as it is classified as hazardous waste. The substance should never be poured down drains or disposed of with regular waste. Neutralization with appropriate alkaline materials under controlled conditions may be possible for small quantities, but this should only be done by trained personnel. Large quantities require disposal through licensed hazardous waste contractors. Always consult local authorities and follow waste classification codes for proper disposal procedures.

How to transport propanoic acid?

Propanoic acid is classified under ADR regulations as Class 8 (corrosive substances), Packing Group III, indicating moderate danger during transport. It requires appropriate UN-specification packaging designed for corrosive liquids and must be properly labeled with corrosive hazard labels and UN identification numbers. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers require ADR training for dangerous goods transport. Segregation from incompatible materials during transport is mandatory, and specific loading and unloading procedures must be followed.

Is propanoic acid subject to specific regulations?

Propanoic acid is subject to various European regulations including REACH registration requirements and CLP classification as a corrosive substance (Skin Corr. 1B). It is not classified as a Substance of Very High Concern (SVHC). The compound falls under food additive regulations when used as a preservative, requiring compliance with specific purity criteria and usage limits. Transport is regulated under ADR as a Class 8 substance. Industrial users must comply with occupational health and safety regulations and may require permits depending on quantities handled.

Where to buy propanoic acid in Europe?

Propanoic acid is available through specialized chemical distributors across Europe, with OYSI being a reliable European supplier of this corrosive chemical. OYSI provides propanoic acid with proper documentation, safety data sheets, and regulatory compliance for industrial applications. Professional chemical distributors ensure appropriate packaging, labeling, and transport arrangements according to ADR regulations. When purchasing, verify supplier credentials, product specifications, and ensure proper handling capabilities are in place before delivery. Always request current safety documentation and certificates of analysis.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.