Propanoic acid
C3H6O2
propanoic acid
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Identification
- CAS Number
- 79-09-4
- EC Number
- 201-176-3
- UN Number
- 1848
- Index Number
- 607-089-00-0
- PubChem CID
- 1032
Physical-chemical properties
- Molecular Formula
- C3H6O2
- Molar Mass
- 74.08 g/mol
- IUPAC Name
- propanoic acid
Chemical Identifiers
- InChI
- InChI=1S/C3H6O2/c1-2-3(4)5/h2H2,1H3,(H,4,5)
- InChI Key
- XBDQKXXYIPTUBI-UHFFFAOYSA-N
Overview
Propanoic acid (CAS 79-09-4) is a short-chain carboxylic acid with strong antimicrobial properties and characteristic pungent odor. This three-carbon saturated carboxylic acid, with molecular formula C3H6O2 and molar mass of 74.08 g/mol, represents an essential intermediate in organic chemistry and industrial applications. Propanoic acid occurs naturally as a metabolic byproduct in certain bacterial fermentation processes and is commercially produced through various synthetic routes including the oxo process and fermentation methods. The compound exhibits typical carboxylic acid behavior with a relatively low pKa value, making it a moderately strong organic acid. Its physical properties include complete miscibility with water and most organic solvents, reflecting its intermediate position between the highly water-soluble acetic acid and longer-chain fatty acids like butanoic acid. The substance demonstrates excellent thermal stability under normal storage conditions while maintaining its chemical reactivity for esterification, amidation, and other standard carboxylic acid reactions. Safety considerations are paramount when handling propanoic acid, as it carries the classification Skin Corr. 1B with danger signal word and GHS05 pictogram, indicating its corrosive nature to skin and eyes. The substance requires Class 8 transport classification under ADR regulations, necessitating appropriate containment and handling protocols in industrial settings. Primary industrial applications include its use as a preservative in animal feed due to its potent antifungal properties, as a precursor in the synthesis of propanoyl propanoate and other esters for flavoring applications, and as an intermediate in pharmaceutical manufacturing. The food industry particularly values its antimicrobial efficacy against mold and bacterial contamination. OYSI provides propanoic acid to European industrial customers with comprehensive technical support and regulatory documentation.
Safety & Classification
Skin Corr. 1B
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Causes severe skin burns and eye damage.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1848 |
| ADR Class | 8 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Propionsäure, 10 % <= Konz. < 90 % |
| Marine Pollutant | No |
Frequently Asked Questions
What is propanoic acid?
Propanoic acid is a short-chain carboxylic acid with the molecular formula C3H6O2 and CAS number 79-09-4. It has a molecular weight of 74.08 g/mol and belongs to the family of saturated fatty acids. This organic compound is characterized by its three-carbon chain structure with a carboxyl functional group, making it the third member of the carboxylic acid series after formic and acetic acid.
What are the physicochemical properties of propanoic acid?
Propanoic acid is a colorless liquid at room temperature with a sharp, pungent odor reminiscent of vinegar but more intense. It is highly miscible with water and most organic solvents due to its polar carboxyl group and relatively short carbon chain. The compound has a boiling point of approximately 141°C and demonstrates typical carboxylic acid behavior, including hydrogen bonding capabilities and acidic properties in aqueous solutions.
What is propanoic acid used for?
Propanoic acid is primarily used as a food preservative and mold inhibitor in the bakery industry, often in the form of its sodium or calcium salts. Industrial applications include its use as an intermediate in the production of herbicides, pharmaceuticals, and plastics. It also serves as a precursor for propionyl derivatives and is utilized in the manufacture of artificial fruit flavors and fragrances in the food and cosmetic industries.
How to handle propanoic acid safely?
Propanoic acid must be handled with extreme caution as it is classified as Skin Corr. 1B with the danger signal word. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work should be conducted in well-ventilated areas or under fume hoods. Emergency shower and eyewash stations must be readily accessible, and direct contact with skin, eyes, or clothing must be avoided at all times.
How to store propanoic acid correctly?
Propanoic acid should be stored in tightly sealed, corrosion-resistant containers in a cool, dry, and well-ventilated area away from direct sunlight and heat sources. Storage areas must be equipped with appropriate ventilation systems and spill containment measures. The substance should be kept away from incompatible materials such as strong bases, oxidizing agents, and metals that may corrode. Secondary containment is recommended to prevent environmental contamination in case of leaks.
What to do in case of contact with propanoic acid?
Immediate action is required in case of contact with propanoic acid due to its corrosive nature. For skin contact, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 15 minutes while holding eyelids open. Seek immediate medical attention for any exposure. If inhaled, move the person to fresh air and seek medical assistance if breathing difficulties occur.
How to dispose of propanoic acid properly?
Propanoic acid disposal must comply with local, national, and European waste regulations as it is classified as hazardous waste. The substance should never be poured down drains or disposed of with regular waste. Disposal should be carried out through licensed hazardous waste contractors who can neutralize or incinerate the material safely. Small quantities may be neutralized carefully with appropriate bases under controlled conditions before disposal, following proper safety protocols and regulatory guidelines.
How to transport propanoic acid?
Propanoic acid is classified under ADR Class 8 (corrosive substances) Group III for transport purposes. Packaging must comply with UN specification requirements for corrosive liquids, typically using appropriate containers with proper labeling including GHS05 pictogram and hazard markings. Transport vehicles must be equipped with appropriate safety equipment and emergency response information. Drivers require ADR training certification, and transport documentation must accompany all shipments according to dangerous goods regulations.
Is propanoic acid subject to specific regulations?
Propanoic acid is subject to standard chemical regulations including REACH registration requirements and CLP classification as Skin Corr. 1B with GHS05 pictogram. It is not listed as a Substance of Very High Concern (SVHC) under REACH. The substance must comply with workplace exposure limits and industrial safety regulations. Food-grade applications are subject to additional food safety regulations and purity requirements when used as a preservative in the food industry.
Where to buy propanoic acid in Europe?
Propanoic acid is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides reliable supply chains and technical support for propanoic acid procurement. As a professional chemical distributor, OYSI ensures compliance with all relevant regulations and provides appropriate safety documentation. Contact OYSI directly for specific grades, quantities, and delivery options tailored to your industrial requirements and geographic location within Europe.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.