2-chlorobenzaldehyde

C7H5ClO

CAS89-98-5
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
89-98-5
EC Number
201-956-3
UN Number
3265
Index Number
605-011-00-X
PubChem CID
6996

Physical-chemical properties

Molecular Formula
C7H5ClO
Molar Mass
140.56 g/mol
IUPAC Name
2-chlorobenzaldehyde

Chemical Identifiers

InChI
InChI=1S/C7H5ClO/c8-7-4-2-1-3-6(7)5-9/h1-5H
InChI Key
FPYUJUBAXZAQNL-UHFFFAOYSA-N

Overview

2-chlorobenzaldehyde (CAS 89-98-5) is an aromatic aldehyde compound with corrosive properties and distinctive chemical reactivity. This halogenated benzaldehyde derivative represents an important intermediate in organic synthesis and industrial chemistry. The compound features a benzene ring substituted with both a chlorine atom and an aldehyde functional group in the ortho position, giving it unique reactivity patterns that make it valuable for various synthetic applications. Its molecular structure (C7H5ClO) with a molecular weight of 140.56 g/mol places it among the lighter aromatic aldehydes, though its chemical behavior differs significantly from simpler compounds like butanoic acid or heptanoic acid due to its aromatic nature and halogen substitution. The presence of both electron-withdrawing groups (chlorine and aldehyde) on the benzene ring influences the compound's reactivity, making it particularly useful in nucleophilic substitution reactions and condensation processes. As a corrosive substance classified under Skin Corr. 1B with GHS05 pictogram and ADR class 8, 2-chlorobenzaldehyde requires careful handling and appropriate safety measures during storage and processing. Industrial applications include its use as a building block in pharmaceutical synthesis, agrochemical production, and specialty chemical manufacturing. The compound serves as an intermediate in the preparation of various heterocyclic compounds and can be utilized in the synthesis of dyes, fragrances, and other fine chemicals. Its aldehyde functionality makes it suitable for condensation reactions, while the chlorine substituent provides opportunities for further derivatization. OYSI supplies 2-chlorobenzaldehyde to meet the demanding requirements of European industrial customers across pharmaceutical, chemical, and research sectors.

Safety & Classification

Danger
Classification:

Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3265
ADR Class8
Packing GroupIII
Tunnel CodeE
Proper Shipping Name2-Chlorbenzaldehyd
Marine PollutantNo

Frequently Asked Questions

What is 2-chlorobenzaldehyde?

2-chlorobenzaldehyde is an aromatic aldehyde compound with the molecular formula C7H5ClO and CAS number 89-98-5. This organic chemical features a benzene ring substituted with both a chlorine atom and an aldehyde functional group in the ortho position. With a molecular weight of 140.56 g/mol, it is classified as a corrosive substance (Skin Corr. 1B) requiring careful handling due to its hazardous properties.

What are the physicochemical properties of 2-chlorobenzaldehyde?

2-chlorobenzaldehyde is typically a colorless to pale yellow liquid at room temperature with a characteristic aldehyde odor. As an aromatic compound, it has moderate polarity due to the aldehyde group and is generally soluble in organic solvents like ethanol and acetone but has limited solubility in water. The presence of the chlorine substituent influences its reactivity and physical properties compared to unsubstituted benzaldehyde.

What is 2-chlorobenzaldehyde used for?

2-chlorobenzaldehyde serves as an important intermediate in organic synthesis and pharmaceutical manufacturing. It is commonly used in the production of various chemical compounds including dyes, agrochemicals, and pharmaceutical intermediates. The compound's aldehyde functionality and chlorine substitution make it valuable for further chemical transformations in industrial processes, particularly in the synthesis of more complex aromatic compounds and specialty chemicals.

How to handle 2-chlorobenzaldehyde safely?

2-chlorobenzaldehyde requires strict safety measures due to its corrosive classification (Skin Corr. 1B). Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Handle containers carefully to avoid spills and ensure emergency shower and eyewash facilities are readily accessible.

How to store 2-chlorobenzaldehyde correctly?

2-chlorobenzaldehyde should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. As a corrosive substance, it requires storage in appropriate chemical-resistant containers and secondary containment. Keep away from oxidizing agents, strong bases, and reducing agents. Storage areas should be equipped with appropriate spill control measures and clearly labeled with hazard warnings.

What to do in case of contact with 2-chlorobenzaldehyde?

Immediate action is critical due to the corrosive nature of 2-chlorobenzaldehyde. For skin contact, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 15 minutes and seek medical attention promptly. If inhaled, move the person to fresh air immediately. Always seek medical attention for any exposure incident.

How to dispose of 2-chlorobenzaldehyde properly?

2-chlorobenzaldehyde disposal must comply with local and European waste regulations as it is classified as hazardous waste. The substance should never be poured down drains or disposed of with regular waste. Contact authorized hazardous waste disposal companies for proper collection and treatment. Small quantities may require neutralization or incineration at licensed facilities. Always consult local environmental authorities for specific disposal requirements in your region.

How to transport 2-chlorobenzaldehyde?

2-chlorobenzaldehyde is classified under ADR Class 8 (corrosive substances), Packing Group III for transportation purposes. It must be packaged in appropriate UN-specification containers and labeled with the correct hazard labels including the GHS05 pictogram. Transportation requires proper documentation including safety data sheets and transport documents. Only authorized carriers experienced in handling corrosive chemicals should transport this substance.

Is 2-chlorobenzaldehyde subject to specific regulations?

2-chlorobenzaldehyde is subject to European chemical regulations including REACH and CLP classification requirements. It is classified as Skin Corr. 1B with the signal word 'Danger' and requires appropriate hazard communication. The substance is not currently listed as a Substance of Very High Concern (SVHC). Companies handling this chemical must ensure compliance with occupational safety regulations and proper worker protection measures.

Where to buy 2-chlorobenzaldehyde in Europe?

2-chlorobenzaldehyde is available through OYSI, a leading European distributor of specialty chemicals and pharmaceutical intermediates. OYSI provides high-quality 2-chlorobenzaldehyde to industrial customers across Europe with proper documentation including certificates of analysis and safety data sheets. As an established chemical distributor, OYSI ensures compliance with European regulations and provides reliable supply chain solutions for professional users requiring this corrosive aldehyde compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.