Potassium;fluoride;hydrofluoride

F2HK

potassium;fluoride;hydrofluoride

CAS7789-29-9
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7789-29-9
EC Number
232-156-2
UN Number
1811
Index Number
009-008-00-9
PubChem CID
11829350

Physical-chemical properties

Molecular Formula
F2HK
Molar Mass
78.10 g/mol
IUPAC Name
potassium;fluoride;hydrofluoride

Chemical Identifiers

InChI
InChI=1S/2FH.K/h2*1H;/q;;+1/p-1
InChI Key
VBKNTGMWIPUCRF-UHFFFAOYSA-M

Overview

Potassium fluoride hydrofluoride (CAS 7789-29-9) is an inorganic fluoride compound with strong corrosive properties and high solubility in water. This white crystalline substance, with the molecular formula F2HK and a molecular weight of 78.1031 g/mol, represents a significant chemical intermediate in various industrial processes. Also known by its EC number 232-156-2, potassium fluoride hydrofluoride exhibits exceptional chemical reactivity due to its dual fluoride structure, making it a valuable yet hazardous material requiring careful handling protocols. The compound's classification under GHS hazard categories Acute Toxicity 3 and Skin Corrosion 1B, along with its ADR Class 8 designation, underscores its dangerous nature. The associated pictograms GHS06 and GHS05 indicate both acute toxicity and corrosive properties, demanding strict safety measures during storage, handling, and transportation. Its highly corrosive characteristics can cause severe chemical burns upon contact with skin or mucous membranes, while inhalation poses serious respiratory risks. Industrial applications of potassium fluoride hydrofluoride include its use as a fluorinating agent in organic synthesis, as an etching agent for glass and silicon surfaces, and as a catalyst in various chemical reactions. The compound serves similar functions to related fluoride compounds such as sodium fluoride hydrofluoride, though with distinct reactivity profiles and application-specific advantages. Due to its hazardous nature, proper storage requires moisture-free conditions and compatibility with fluoride-resistant materials. Professional handling expertise and appropriate safety equipment are essential for all operations involving this compound. OYSI provides potassium fluoride hydrofluoride to qualified industrial customers across Europe, ensuring compliance with all relevant safety and transportation regulations.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H301

Toxic if swallowed.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1811
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameKaliumhydrogendifluorid, fest
Marine PollutantNo

Frequently Asked Questions

What is potassium fluoride hydrofluoride?

Potassium fluoride hydrofluoride is an inorganic chemical compound with the molecular formula F2HK and CAS number 7789-29-9. This substance has a molecular weight of 78.1031 g/mol and appears as a white crystalline solid. It is classified as a corrosive substance with acute toxicity properties, requiring careful handling due to its hazardous nature. The compound is widely used in various industrial applications where fluoride chemistry is essential.

What are the physicochemical properties of potassium fluoride hydrofluoride?

Potassium fluoride hydrofluoride is a white crystalline solid at room temperature with high solubility in water. The compound has a molecular weight of 78.1031 g/mol and contains both fluoride and hydrofluoride ions. It exhibits hygroscopic properties, readily absorbing moisture from air. The substance is odorless and forms acidic solutions when dissolved in water due to the presence of the hydrofluoride component.

What is potassium fluoride hydrofluoride used for?

Potassium fluoride hydrofluoride is primarily used in glass etching and metal surface treatment applications. The compound serves as a fluorinating agent in chemical synthesis and is employed in the production of specialty glasses and ceramics. It finds application in analytical chemistry as a reagent and in the electronics industry for cleaning silicon surfaces. The substance is also used in research laboratories for various fluoride-based chemical reactions.

How to handle potassium fluoride hydrofluoride safely?

Potassium fluoride hydrofluoride requires strict safety measures due to its corrosive and toxic properties. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation. Handle with plastic or PTFE tools as the compound can etch glass and metal. Never eat, drink, or smoke while handling this substance, and wash hands thoroughly after use.

How to store potassium fluoride hydrofluoride correctly?

Potassium fluoride hydrofluoride must be stored in tightly sealed, corrosion-resistant containers made of polyethylene or PTFE. Keep the substance in a cool, dry, well-ventilated area away from incompatible materials such as strong acids, metals, and glass containers. Store separately from oxidizing agents and organic materials. Ensure storage areas are equipped with appropriate spill containment measures and maintain temperatures below 25°C to prevent decomposition.

What to do in case of contact with potassium fluoride hydrofluoride?

Immediate action is required upon contact with potassium fluoride hydrofluoride due to its corrosive nature. For skin contact, rinse immediately with copious amounts of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, flush with water for at least 15 minutes and seek immediate medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek emergency medical care. Always consult a physician after any exposure.

How to dispose of potassium fluoride hydrofluoride appropriately?

Potassium fluoride hydrofluoride disposal must comply with local and national hazardous waste regulations. The substance cannot be disposed of in regular waste streams due to its toxic and corrosive properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Neutralization may be possible under controlled conditions by qualified personnel. Ensure all disposal activities are documented and follow REACH and local environmental protection requirements for fluoride-containing waste.

How to transport potassium fluoride hydrofluoride?

Potassium fluoride hydrofluoride is classified under ADR regulations as Class 8 (corrosive substances), Packing Group II. Transportation requires appropriate UN-specification packaging designed for corrosive materials. Vehicles must carry proper hazard placards and documentation including safety data sheets. Drivers need ADR training certification for dangerous goods transport. Packages must be clearly labeled with GHS pictograms GHS05 and GHS06, and the danger signal word must be displayed.

Is potassium fluoride hydrofluoride subject to particular regulations?

Potassium fluoride hydrofluoride is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification standards. The substance is classified as Acute Tox. 3 and Skin Corr. 1B under CLP regulation. It requires safety data sheets for all commercial transactions and proper labeling with danger signal words and appropriate GHS pictograms. The compound is not currently listed as an SVHC substance but remains under regulatory monitoring for fluoride content.

Where to buy potassium fluoride hydrofluoride in Europe?

Potassium fluoride hydrofluoride is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this substance to industrial customers across Europe with full regulatory compliance including proper documentation and safety data sheets. The company ensures quality standards and reliable supply chains for laboratory and industrial applications. Contact OYSI directly for availability, technical specifications, and pricing information tailored to your specific requirements and delivery location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.