Potassium fluoride

FK

potassium fluoride

CAS7789-23-3
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
Danger

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Identification

CAS Number
7789-23-3
EC Number
232-151-5
UN Number
1812
Index Number
009-005-00-2
PubChem CID
522689

Physical-chemical properties

Molecular Formula
FK
Molar Mass
58.10 g/mol
IUPAC Name
potassium fluoride

Chemical Identifiers

InChI
InChI=1S/FH.K/h1H;/q;+1/p-1
InChI Key
NROKBHXJSPEDAR-UHFFFAOYSA-M

Overview

Potassium fluoride (CAS 7789-23-3) is an inorganic salt compound with high solubility and strong fluorinating properties. This white crystalline salt represents one of the most important fluoride compounds in industrial chemistry, serving as a versatile source of fluoride ions in numerous chemical processes. As a highly hygroscopic material, potassium fluoride readily absorbs moisture from air and dissolves completely in water to form alkaline solutions. The compound exhibits excellent thermal stability and maintains its chemical properties across a wide temperature range, making it particularly valuable in demanding industrial applications. From a safety perspective, potassium fluoride requires careful handling due to its classification as Acute Tox. 3 under GHS regulations, displaying the skull and crossbones pictogram (GHS06) with the danger signal word. The material poses significant health risks through ingestion, inhalation, or skin contact, necessitating appropriate personal protective equipment and controlled storage conditions. Transport regulations classify it under ADR class 6.1, reflecting its toxic properties. Industrial applications of potassium fluoride span multiple sectors, with primary uses including organic synthesis as a fluorinating agent, glass etching processes, and as a flux in metallurgical operations. The compound also serves as an intermediate in pharmaceutical manufacturing and specialized chemical production. Unlike related compounds such as azanium fluoride, potassium fluoride offers superior stability and handling characteristics in many applications. The electrolytic properties and high ionic conductivity of potassium fluoride solutions make it valuable in electrochemical processes and battery technologies. Its role as a catalyst or co-catalyst in various organic reactions further extends its industrial utility. OYSI maintains reliable supply chains for potassium fluoride, ensuring consistent availability for European industrial customers requiring this essential chemical intermediate.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1812
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameKaliumfluorid, fest
Marine PollutantNo

Frequently Asked Questions

What is potassium fluoride?

Potassium fluoride is an inorganic chemical compound with the molecular formula KF and CAS number 7789-23-3. This ionic salt consists of potassium cations and fluoride anions, with a molecular weight of 58.0967 g/mol. It is classified as an acute toxic substance (Acute Tox. 3) and requires careful handling due to its hazardous properties. Potassium fluoride is widely used in various industrial applications where fluoride ions are needed.

What are the physicochemical properties of potassium fluoride?

Potassium fluoride is a white crystalline solid at room temperature, typically appearing as cubic crystals or powder. It is highly hygroscopic, meaning it readily absorbs moisture from air. The compound is highly soluble in water, forming a basic solution due to fluoride ion hydrolysis. It has no characteristic odor and is stable under normal conditions. Its high solubility and ionic nature make it effective for applications requiring fluoride availability.

What is potassium fluoride used for?

Potassium fluoride serves multiple industrial purposes, primarily as a fluorinating agent in organic synthesis and pharmaceutical manufacturing. It is used in the production of fluorinated compounds, as a flux in metallurgy, and in glass etching processes. The compound also finds applications in pesticide formulations, as a preservative for wood, and in analytical chemistry as a reagent. Its ability to provide fluoride ions makes it valuable in specialized chemical processes.

How to handle potassium fluoride safely?

Potassium fluoride requires strict safety protocols due to its acute toxicity classification. Personal protective equipment must include chemical-resistant gloves, safety goggles, and appropriate respiratory protection when dust exposure is possible. Work should be conducted in well-ventilated areas or under fume hoods. Avoid skin contact, inhalation, and ingestion. Keep containers tightly closed and use appropriate tools to prevent direct contact. Emergency equipment should be readily available in work areas.

How to store potassium fluoride correctly?

Potassium fluoride should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from moisture due to its hygroscopic nature. Keep away from incompatible materials such as acids and oxidizing agents. Store in original containers with proper labeling and ensure compliance with local regulations for toxic substances. Access should be restricted to trained personnel only, and storage areas should be equipped with appropriate spill containment measures.

What to do in case of contact with potassium fluoride?

Potassium fluoride exposure requires immediate action due to its acute toxicity. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately. In case of eye contact, rinse thoroughly with water for at least 15 minutes. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician after any exposure incident.

How to dispose of potassium fluoride appropriately?

Potassium fluoride disposal must comply with local and national hazardous waste regulations as it is classified as toxic waste. The substance cannot be disposed of in regular waste streams or sewers. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities may require neutralization under controlled conditions by qualified personnel. Always maintain documentation of disposal activities and follow your facility's hazardous waste management procedures.

How to transport potassium fluoride?

Potassium fluoride is classified under ADR Class 6.1 (toxic substances), Packing Group III, requiring specific transport protocols. Packages must be properly labeled with GHS06 pictograms and 'Danger' signal words. Use appropriate packaging that prevents leakage and meets UN specifications. Transport vehicles must carry proper documentation and emergency response information. Only authorized carriers familiar with hazardous materials regulations should handle the transport of this substance.

Is potassium fluoride subject to specific regulations?

Potassium fluoride is regulated under various European frameworks including CLP Regulation for classification and labeling, requiring GHS06 pictogram and 'Danger' signal word. It falls under REACH registration requirements but is not listed as a Substance of Very High Concern (SVHC). Users must comply with occupational health regulations, transport regulations (ADR), and waste disposal directives. National restrictions may apply, and safety data sheets must be provided to downstream users.

Where to buy potassium fluoride in Europe?

Potassium fluoride is available through OYSI, a European distributor specializing in technical chemical products. OYSI provides this substance with proper documentation including safety data sheets and certificates of analysis. As a regulated toxic substance, purchases are typically restricted to professional users with appropriate handling capabilities. Contact OYSI directly for availability, specifications, and regulatory compliance support for your specific application requirements across European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.